光谱的

The works in the project just done can be summarized as five respects.(1) A device was designed to fabricate the asymmetrical resonant cavities by a pendant drop. A series ARCs with variable parameters provides a valuable experimental method for investigating the characteristics of ARCs.(2) The relationship between the number of active modes and the shape parameters in an ARC was investigated. The experimental lasing threshold was compared with theoretical result, the good agreement between two shown that it was the decrease of the number of active modes in an ARC that decreased lasing threshold.(3) Dye lasing gain was used to enhance the signals of stimulated Raman scattering of the weak gain Raman modes in a circular cavity made by a pendant drop, the instantaneous SRS spectra of weak gain Raman modes in ethanol was obtained by this new method.(4) The SRS signals of minority compound in a binary chemical complex was obtained by using dye lasing gain method. The detection concentration of minority compound was reduced to an order compared with normal SRS method.(5) A cylindrical circular cavity was formed by a liquid jet, which was used to reduce the pump intensity required for laser induced plasma spectroscopy. The limit of detection of trace element in aqueous sample was greatly decreased by this new method.

我们设计并成功制作了使悬垂液滴连续变形的装置，用此装置可以方便地改变非圆对称谐振腔的几何参数，为ARCs的研究提供了一种有效的实验方法；研究了ARCs中活性模式数和变形参数间的变化规律，激光阈值的数值计算结果和激光辐射的实验结果作了比较，二者吻合的曲线说明ARCs中活性模式数量的减少是受激辐射放大阈值降低的原因；在由单元化合物构成的微型圆对称谐振腔中，首次尝试用"激光增益"增强弱增益拉曼模式的受激拉曼散射信号，获得了乙醇分子中弱增益拉曼模式的瞬态SRS光谱；在由二元混合物构成的微型圆对称谐振腔中，用染料的激光增益增强了少量化合物的SRS信号，把少量化合物的SRS信号探测浓度降低了近一个数量级，在SRS应用于瞬态过程的组份分析方面做了卓有成效的探索；用石英毛细管形成的稳定液拄构成拄形谐振腔，降低了激光诱导等离子体光谱需要的激励能量，有效地降低了水相样品的痕量元素分析极限，为LIPS应用于微量元素的化学分析开拓了一条新的技术路线。

Light output analysis tests character of spectrum radiate of pyrotechnic mixtures and analyses wave band distribute of light by comparing different static blaze spectrograms of the pyrotechnic mixtures. Screen out the better pyrotechnic mixtures according to request of pumping source. Press experiments in airtight erupt container experiment, which simulate the circumstance that pyrotechnic mixtures deflagrate in quartz pipe, realize the press influence to the quartz pipe wall and the disciplinarian of axes press variety. Apply these pyrotechnic mixtures to Nd:YAG lasers as the pumping source and compare pumping efficiency of different pyrotechnic mixtures. Pumping efficiency is an important standard which checkout if these pyrotechnic mixtures are the better pumping source. Sensitivity experiment analysis incarnate security of pyrotechnic mixtures that is the essential parameter in the process of design, manufacture and use.

通过对烟火药的热分析(爆热分析、DTA、TG)，了解备选烟火药反应过程中的能量输出特性及反应过程中的物理、化学变化规律；光输出分析实验对烟火药配方光谱辐射特征进行测试，比较其静态火焰光谱图，分析不同烟火药剂光辐射波段分布特征，根据激光泵浦源的辐射要求，进而筛选更符合激光泵浦源药剂要求的烟火药；模拟烟火药在石英管中爆燃环境的密闭爆发器压力分析实验反映了烟火药在石英管中反应时对管壁的压力影响以及管内轴向压力变化规律；将烟火药作为泵浦源应用于Nd：YAG固体激光器，比较不同烟火药的泵浦效率，作为检验烟火药是否适合作为激光泵浦源的重要标准；感度实验分析体现了各种烟火药的安全性，是烟火药设计、制造和使用的必要示性数。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题，系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性，通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析，全文主要内容如下： 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明：红磷在空气中发生缓慢氧化、歧化反应，微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度，其中铜离子的作用最为明显，而铝、锌等离子减慢了红磷的氧化速度，银离子对减少红磷的吸湿性效果最好。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

The two-photon absorption cross-sections of these styryl derivatives were determined by Z-scan technique, and the benzothiazolium derivatives exhibited the largest TPA cross-sections (10〓s·cm〓/photon) and the best power limiting ability at high operable incident intensity. The results show that the benzothiazolium derivatives are promising organic compounds as two-photon absorption optical limiting materials. 2. Several organic dyes active to 800nm femtosecond laser with D-π-A structure were designed and synthesized.

研究了它们的上转换荧光、上转换激射和光限幅行为，通过改变染料分子共轭体系的大小，首次实现了在576nm-635nm范围内的双光子上转换激光波长的调节，其中噻唑啉碘盐类二苯乙烯化合物的双光子上转换激射峰（576nm）是迄今在1064nm皮秒激光作用下能够得到的最短波长的激光；阴离子显著改变上转换激射效率，但对上转换荧光峰和激射峰的位置影响很小；增加溶液的浓度，上转换荧光光谱和激射光谱红移，并在一定的浓度范围内，能够有效的提高上转换激射效率；利用Z-扫描技术测定了染料分子的双光子吸收截面，发现苯并噻唑类染料分子的双光子吸收截面高达10〓s·cm〓／photon，而且在较大的入射光强范围内，这类染料分子具有较大的光限幅能力，是一类作为双光子吸收光限幅材料很有潜力的染料分子。

Based on the changes in the spectrum characters of guest molecules producedthrough inclusion complex formation with cyclodextrins, we have carried out two aspects of investigation:First, the mechanisms for the host-guest recognition reactions have been studied, such as the interactions between 3-CD and curcumin, the main constituent of the rhizomes of the plant Curcuma longa, the recognition of p-CD towards rubidate, the effective component of the Chinese traditional medicine madder, and the reactions of p-CD towards the antileprotic drug dapsone and the antiinflammatory drug nabumetone: The formation of supramolecular complex between P-CD and guest molecule has been discussed and verified in virtue of multitudinous means such asultraviolet-visible absorption, fluorescence emission, infrared spectrogram and so on. The influence of addition of linear alcohols on the supramolecular system has been studied and the reason why the noncovalent interactions in the three-component system could result in a decrease in the apparent association constant of the inclusion complex has been revealed.

本论文基于环糊精对被包结客体光谱性质的改变，开展了两大方面的研究：β-环糊精对姜黄属植物根茎主要成分—姜黄素、中药茜草有效成分—茜草双酯、抗麻风药物氨苯砜及抗炎药物萘丁美酮的主-客体识别反应机制研究：借助超分子包合物的紫外吸收光谱、荧光光谱或红外吸收光谱等手段，通过多种方法探讨并验证了超分子包合物的形成；研究了直链醇的加入对超分子体系的影响，揭示了三元体系中非共价相互作用导致超分子包合物表观结合常数降低的原因：对超分子包结反应进行了热动力学研究，探讨了各热动力学参数的变化趋势并从熵焓互补的角度考察了超分子包结过程；通过荧光猝灭实验进一步揭示了水相中β-环糊精增敏客体荧光的本质原因，从而为超分子化学提供新的理论和研究方法。

POMs and deys are still maintained integrallty.AFM exhibits the films is even.The thickness of each layer is about 1.25nm. The AFM images reflect that there are some protuberances on the outer surface layer of the film, which due to the aggregates of spherical structure PMo12. Cyclic Voltammograms reflects the redox potentials of dye in multilayer shifts towards more positive values than pure dye multiplayer which may be explained by charge transfer from dye to POM. Fluorescence spectra show that polyoxometalates caused the fluorescence decay of dyes, which maybe used as fluorescence sensors.

UV-VIS说明复合膜均匀生长； IR 光谱、XPS能谱研究结果表明，紫外光照前后，膜中多酸/染料分子间没有发生显著的光化学反应，各组分的结构仍然保持；原子力显微镜显示，膜的外表面是均匀的，每一个双层厚度大约是1.25nm，膜表面的隆起，可能是多酸阴离子簇堆积所引起；循环伏安测定结果表明，由于多酸阴离子的影响，有机染料的氧化还电位发生了正的偏移，反映出复合膜中染料分子与多酸阴离子间发生了荷移相互作用，导致染料分子失去部分电子而使氧化性略强；荧光光谱研究结果表明，多酸阴离子可以有效地引发荧光染料的荧光淬灭，这为多酸在荧光传感器方面的应用提供了有价值的信息。

Adding a small quantity of three functional group of polyvalent can improve the water resistance and decoration of copolymer emulsion after film forming. The structure form of interpenetrating networks has a greater destroy degree to the micro crystal of polyurethane film forming substance than the effect of the prepolymer capping graft copolymer.IV, This article studies on the heat stability of acrylate modified polyurethane dispersion, researches the changes of the structure of acrylate modified polyurethane dispersion afterheating, and analyses by the heat analysis, infrared ray and heat analysis, and mass spectrometery.

利用拉曼光谱和扫描电镜、红外光谱等测试技术，分析了丙烯酸酷及丙烯酸酷一有机硅等改性聚氨酷水分散体的成膜过程—利用预聚体封端技术合成的丙烯酸酷改性聚醚聚氨酷的成膜过程包括乳液颗粒的挤压成膜与分子硬段的微区结晶，有机硅氧烷的引入将同时出现硅氧烷的水解缩合；具有互穿网络结构的丙烯酸酷改性聚氨酷水分散体因丙烯酸酷的互穿而限制了聚氨酷硬段在成膜过程中的结晶，聚合物成膜以挤压成膜为主，有机硅的复合改性同样出现硅氧烷水解缩合现象。8。

There are, however, no wide-accepted molecular parameters taken as a reference and no precise γ and A_D obtained simultaneously so far.

本论文报道我们获得的自然丰度下N~(16)O的中红外LMR光谱，并采用最新的联系各同位素分子参数的标度函数将所有已发表的光谱数据和我们测量的实验数据实现统一的标识分析，通过对所有数据的完整一体的最小二乘拟合，得到了迄今为止最完备、最精确的~mN~nO(m=14，15；n=16，17，18)系列分子的结构参数，这些参数的精度与文献结果相比提高了1-2个量级，其中许多参数都是首次获得的。

Fluorescence emission spectra and UV absorb spectra analysis have been undertaken to test the influence of solvent polarity on the lowest excited singlet state of the tertiary amines. The absorption maxima were red-shafted slightly, and the emission maxima were red-shafted strongly, which showed all of the three compounds were found to be essentiallyππ* in character, which makes for the formation of triplet-exciplex state and the subsequent reactions,?known as photo-reduction and hydrogen-abstraction.

本文借助光谱检测的手段测试了新合成的增感剂的光物理化学性能，利用荧光发射光谱和紫外吸收光谱测试了溶剂极性对叔胺的最低激发单重态的影响，实验结果表明叔胺的紫外最大吸收波长随溶剂极性的增强产生轻微的红移，荧光最大发射波长随溶剂极性的增强产生明显的红移，表明三种叔胺的最低激发单重态具有ππ*跃迁的特性，这对于激态复合物的生成以及其后的光致还原反应和提氢反应的发生都非常有利。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。