光谱的

Raman spectra of polythiophene and poly（para-phenylene） films electrochemically deposited on stainless steel electrodes by direct oxidation of thiophene and benzene in boron trifluoride diethyl etherate solution have been investigated by excitations with 633 and 785 nm laser beams, respectively.

聚噻吩和聚苯的薄膜通过在噻吩和苯的三氟化硼乙醚溶液中电化学氧化得到，它们分别使用633 nm和785 nm的激光进行拉曼实验，新制的聚噻吩薄膜的拉曼光谱和薄膜的厚度密切相关，同样的，新制的聚苯薄膜的拉曼光谱和薄膜的厚度密切相关。

After the tested N gas components are led into the spectrograph via sampling probe and pipeline, the spectrograph obtains the transmittivity data in the scanned wave number or wavelength range and transmits the data to the computer, the computer extracts the effective characteristic quantities as the input to the parallel supporting vector machine algorithm module, and the supporting vector machine outputs the multiple component gas concentration values.

被测的N个多组分气体经气体采样探头与连接管路导入光谱仪，由光谱仪获得扫描波数或波长范围内各波数或波长对应的透射率关系给出光谱数据经数据传输线进入计算机。进入计算机内的光谱数据由软件的数据预处理模块提取有效的特征量，作为支持向量机并行算法模块的输入，支持向量机并行算法模块的输出为N个多组分气体浓度。

In the light of field features in desertification areas, the data quality and band combination of different bands are assessed, the indicators, principles and methods for data assessment and band option are put forward to, and optional band combination for desertification monitoring is determined primarily. The data pre-treatment model for desertification monitoring is developed after studying the pre-treatment algorithm of restoration and rebuilding of hyperspectral resolution data. The spectral features and variation rules of different objects in experimental areas are understood and analyzed. The different classified methods are given and discussed on the basis of characteristics of desertification region. The remote sensing quantitative retrieval model for the appraisable factors of desertification monitoring are founded.

针对荒漠化地区的地物特征，对高光谱数据不同波段的数据质量、波段组合进行定性和定量的评价，提出用于数据评价、波段选择的指标、原则和方法；初步确定一个适用于荒漠化监测的优化波段组合，建立适合于荒漠化监测的数据预处理模式；初步分析、掌握研究区内各类地物的光谱特性及变异规律；针对荒漠化地区特点对多种分类方法进行探讨分析；建立荒漠化监测主要评价因子的定量反演模型。

The results have indicated that the introduction of electron-donating methoxy or electron-withdrawing cyano-group at the 7-position of 3-phenylcoumarins caused a bathochromic shift for both absorption and fluorescence spectra. The phenyl group at the 4-position derivative has a hypsochromic shift for both absorption and fluorescence spectra.

结果发现，在3-苯基香豆素的7-位引入给电子基团甲氧基或吸电子基团氰基均使它们的吸收光谱和荧光光谱产生红移，4-苯基香豆素的衍生物的吸收光谱和荧光光谱均产生蓝移。3-苯基香豆素衍生物与4-苯基香豆素的衍生物的基态和激发态的电子转移方向相反。

The emission of N_2 in discharge gap is detected using optical emission spectrophy. The discharge reactor was put in lightproof box to avoid the disturbance from outside lights. A small hole was drilled in one sidewall of the box, and the fibre was mounted coupling to the inlet (1mm) into the hole. A tube with the inner diameter of 1.1mm was set in the front of the hole. In this way, only the light from a certain direction emitted from the discharge reactor could transfer into the inlet through the tube. The reactor could be moved in the vertical direction of the fibre, and the spectrometry can collect the total emission along the fibre inlet in single-shot measurement.

利用光学发射光谱仪对多针对板电晕放电中放电间隙内的N_2发射光谱进行测量，放电反应器置于暗箱中以避免外界对光谱测量的影响，将光谱仪的光纤耦合入口固定在暗箱侧壁的小孔内，小孔孔径为光纤耦合入口直径，在小孔前方安装孔径为1.1mm的细直管，只采集与光纤耦合入口在同一直线上的发光，避免放电区其它区域的发光被同时接收。

Oil film thickness along the piston skirt in motored engine was measured, and the comparison with theory result was given.

最后在实验研究中，本文国内首次在活塞裙部油膜厚度中采用了激光荧光诱导的测试方法，主要工作是：分析了激光荧光诱导法的基本原理，建立了测膜厚的基本定量关系模型，通过实验分析了膜厚测试的各种影响因素，通过实验对不同香豆素荧光光谱和激发光谱特性进行了分析，通过实验确定了选取香豆素的种类和溶液浓度的基本原则，自主开发了以光纤为光学光路的测试系统并对系统进行了标定，对内燃机冷拖动状态的活塞裙部进行了实测，并与理论测试结果进行了对比。

Here we introduced oxadiazole moiety to theside-chain of Ph-PPV to enhance the electron transport properties. The luminescenceefficiency and luminescence brightness (1.33cd/A, 9400 cd/m~2) of the Ph-PPV withside oxadiazole moiety are much higher than non-oxadiazole Ph-PPV (0.70 cd/A,2300 cd/m~2), and these polymers emitted green light which unaffected by theintroduction of oxadiazole moiety. Anthracene has a rigidity and planar structure which shows high photoluminescenceand thermo-stability.

结果表明，以十烷氧基作为间隔基使噁二唑单元键接在苯基取代PPV的侧链，所得材料制备的电致发光器件的效率和亮度(1.33cd／A，9400 cd／m~2)明显高于不含噁二唑单元的苯基取代PPV(0.70 cd／A，2300 cd／m~2)，噁二唑单元的引入并不影响材料的发光光色，膜状态下的荧光发射光谱和电致发光光谱均呈绿光发射。

To facilitate the applications of biologically functional protein in drug design, it is necessary to have a thorough understanding of their conformations and their interactions with the receptors. NMR spectroscopy has the unique ability to retrieve information about 3D structures of proteins and their interactions with the target proteins in solution. Many NMR techniques have been used to study a number of pharmaceutically important proteins and characterize their interactions with the targets. In this review, we will introduce these NMR methods and show how to utilize them for protein drug design.

为了设计具有生物功能性的蛋白质来当作药物，我们必须对其蛋白质结构与其受体在结合时的作用有完整清楚的了解，而核磁共振光谱具有独特的能力，可以获得溶液状态下蛋白质结构以及蛋白质与标的蛋白质交互作用间的资讯，目前已有许多核磁共振光谱技术运用到蛋白质药物的研究，并确认它们与其标的蛋白质间的作用模式，笔者将在本文中介绍这些技术，以及如何运用它们来获取重要资讯，俾设计蛋白质药物。

As to the high polarity, high boiling point resultant—trimesic acid, the analysis methods of infrared spetrum, gas chromatography-mass spectroscopy, vapour-phase chromatography, acid number titration and so on are seperately used to characterize its property. Infrared spetrum and gas chromatography-mass spectroscopy are used to have a qualitative analysis on the resultant and are compared with the stand diagram. Sulfuric acid-methanol esterification and rapid esterification are used to prepare the trimesic acid trimethyl-ester and have a FID quantitative analysis. So that we make sure the purity of trimesic acid in the resultant and also we have an acid alkali titration on the resultant to get its acid number, in order to verify the purity of trimesic acid in the resultant.

对于高极性、高沸点的固体产物均苯三甲酸，分别采用红外光谱、气质联用、气相色谱、酸值滴定等分析手段进行了表征：利用红外光谱、气质联用的方法进行产物的定性分析，并与在同一仪器、同一条件下做出的标准谱图进行比对；采用硫酸-甲醇酯化法和快速酯化法制备出均苯三甲酸三甲酯，对其进行气相色谱FID定量分析，进而确定固体产物中均苯三甲酸的纯度；用酸碱滴定法确定固体产物的酸值，以对固体产物中均苯三甲酸的纯度进行验证。

According to Johnson's Rule and IR spectra, their possible structures are suggested. The bonding parameters of those complexes are calculated by ESR parameters. And the crystal field parameters are calculated by using electronic spectral data. It can be seen that the vanadyl complexes in the solution are ionic complexes and that the α〓 values of those complexes decrease following the increasing of the N donor replacing the O donor of water on the equatorial plane in those complexes. This means that the covalent bonding between vanadium and ligand increases as Ser, Phen or Bipy replace water ligands. The results show the competitive coordinate law that the coordination reactivity of Phen and Bipy is much stronger than that of Ser. The simulation program of ESR is compiled by the theory of ESR in the present work.

测定了VO-丝氨酸二元体系、VO-丝氨酸-邻菲咯啉三元体系和VO-丝氨酸联吡啶三元体系在不同酸度下（pH=1.0～14.0）的乙二醇／水（V／V=1：1）溶液低温ESR谱，发现不同pH下，溶液中具有不同组成的配合物，根据不同pH下ESR谱的变化，利用Johnson的加合规则并结合红外光谱，推测了它们在溶液中的可能结构；利用波谱参数计算了配合物键参数；利用电子光谱数据计算了配合物的晶体场参数，讨沦了它们的成配特性，结果表明：VO配合物属离子型配合物，随取代水分子的配体（Ser、Phen或Bipy）数目增加，键参数减小，配合物共价性增强，同时得出这些体系中，生物配体竞争配位规律：Phen和Bipy与VO的配位能力比Ser强。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。