光谱的

The completely diagonalized Hamiltonian matrices of 3d2/3d8 ion configuration in the trigonal symmetry have been established by irreducible representation method. Taken into account the influence of the spin-spin coupling interactions omitted in previous publications, the spectra and the constants of crystal structure and zero-field splitting parameters of CsNiCl3 crystal and CsNiCl3: Mg2+ crystal are calculated and the influence of the doping to the spectra, the constants of crystal structure, zero-field splitting parameters and Jahn-Teller effect are studied. The results show that doping can change the structure of crystal which brings about the changes in the spectra and zero-field splitting parameters as well as Jahn-Teller effect.

应用不可约张量理论构造了三角对称晶场中3d2/3d8态离子的45阶可完全对角化的微扰哈密顿矩阵，在考虑了以前工作中被忽略的自旋-自旋耦合作用的基础上计算了CsNiCl3晶体和CsNiCl3：Mg2+晶体的基态能级、晶体结构、零场分裂参量和Jahn-Teller效应，研究了掺入Mg2+对CsNiCl3晶体的光谱、零场分裂参量及Jahn-Teller效应的影响和自旋单重态对基态能级的贡献，发现掺杂使得晶体结构产生畸变，从而改变晶体光谱的精细结构和零场分裂参量，不改变Jahn-Teller效应的分裂规律但改变分裂的大小。

BSpatial characterization of laser induced Cu plasma in air with different laser focusing distancesThe plasma spectra induced by pulsed laser ablation of copper target are measured. By adjusting the distance of the len-sample, the spectrum of air spark plasma、 Cu plasma and the reciprocity of both plasmas are analysed. From the result, it has been shown that the focusing of the laser beam has an important infunence to analyse the properties of the sample.

b 不同的激光焦点位置产生的等离子体光谱的空间特性研究激光烧蚀置于空气中的Cu靶产生等离子体，通过调节透镜与Cu靶的距离，本文观测了激光烧蚀空气产生的空气火花等离子体、激光直接烧蚀铜靶产生Cu等离子体以及空气火花等离子体与Cu等离子体相互作用等不同情况下的激光诱导击穿发射光谱，激光束焦点的位置在分析材料性质的过程中有着重要的影响。

The mechanism of the reaction was studiedin detail,in which excited state avaliable to carryout the excited state intramolecular proton transferreaction was recognized.The INDO/S-CI semiempiricalMO method was used to calculate transition energiesand oscillator strength,and assign spectra theore-tically,the calculated spectra values were basicallyconsistent with the experimental values.Themolecular orbital properties for the adjacent HOMO-LUMO of various kinds of conformersand anion species,thetransition properties and symmetry for thetransition from ground state to lower excited stateswere analysed,especially,no much study on theanion species all of the world.

位能曲线的求法满足反应坐标是反应过程中能量最小途径的定义，较详细地研究了各类反应的质子转移历程，认定在哪个激发态有利于发生激发态分子内质子转移反应，用INDO/S-CI半经验MO方法进行跃迁能和振子强度计算及光谱的理论指认，计算的光谱值和实验值基本吻合，并分析了各种异构体和阴离子的HOMO-LUMO附近的轨道性质，各跃迁态的跃迁性质和对称性，尤其是对阴离子的研究国内外尚不多见。

Four non-ionic europium complexes,〓-phen(11),〓·bipy(12),〓·dia(13) and 〓(14)(TTA=2-thenoyltrifluoroacetone, DBM=dibenzoylmethane, phen=phenanthroline, bipy=2,2'-bipyridine, dia=4,5- diazafluoren-9-one, dmbp=4,4'-dimethyl-2,2,-bipyridine), were synthesised and the triboluminescent phenomena of 12, 13 and 14 were firstly observed. Structure determinations of 11,12 and 14 were carried out. The triboluminescence maxima of 12 and 13 are similar to those of their photoluminescence. X-Ray structure analyses show that Eu atoms all exhibit eight-coordinate tetragonal antiprismatic geometries and complexes 11, 12 and 14 are all centrosymmetric.

二、合成了四个非离子型的铕的配合物：〓、〓、和〓(14)[HTTA=2-噻吩三氟甲酰丙酮，DBM=二苯甲酰基甲烷，phen=邻菲罗啉， bipy=2，2'-联吡啶，dia=4，5-二氮杂芴-9-酮，dmbp=4，4'-二甲基-2，2'-联吡啶]，首次报道了12、13及14的摩擦发光性质，测定了11、12及14的晶体结构，并系统地讨论了晶体结构和摩擦发光活性之间的关系。12及13的摩擦发光光谱的极大值均类似与其相应的光致发光光谱，表明它们有相同的激发态。

It is found that,in a first-order differential Raman spectrum,almost all noise peaks are confined within a narrow horizontal band-like region with the base line going through its middle,whereas thesignal peaks shoot up and down much far beyond the region.Based onthis property,a new peak searching method with the aid of first-order differentiation is suggested.In this paper,a R_spectrumpeak labelling program for SPEX 1403 laser spectrometer with DMIBcomputer is reported.The result of peak labelling sho...

作者提出了用一阶导数谱辅助求 Raman 光谱峰值的新方法，较好地解决了谱峰与噪音的识别问题；编制了 SPEX_(1403)激光 Raman 光谱的标峰程序，具有10种不同大小尺寸的绘图功能、9种不同的字号供标峰选用，操作分为自动、半自动和手动三种方式，具有用于图注、实验条件说明的打字，存、取及复制标峰谱图等功能，克服了一般标峰过程中常见的弊病，标峰效果满意。

Spectra of I_2 in benzene solution shows that Raman scatting light intensity is increased gradually as scattering distance is increased, in the scattering process it is accumulated and it is getting stronger and stronger.

苯溶液的I_2拉曼光谱，表明在液芯光纤内产生的拉曼散射光谱的强度是随着激发光束在介质中作用距离的增加而增强的，拉曼散射光在光纤的传播中不断累积得以增强。

The fluorescent emission mechanism, and the some factors that affect the energy and the intensities of the fluorescent peaks were studied. The strong powder second harmonic generation efficiencies for complexes (1),(2),(3) and (4) were found. The determination of variable-temperature magnetic susceptibility for complex (3) and complex (5) was performed. The magnetic data were analyzed with their structure properties, and the further information about the magnetic coupling capacity of Carbamyldicyanomethanide as bridging ligand was obtained.

测试了配合物(1)，(2)，(3)，(4)的荧光光谱，从配体的结构特点等方面研究了该荧光光谱的产生机理，研究了影响荧光谱峰能量及强度的因素；发现了配合物(1)，(2)，(3)，(4)显示有强的二阶非线性倍频效应；测试了配合物(3)和(5)的变温磁化率，对所得磁数据进行了结构性质分析，进一步获得了甲氨酰二氰基甲基阴离子作为桥联配体的磁耦合信息。

Shape of fluorescence spectrum of diphenylanthracene in multilayer film is almost the same as that in solution, and the position of emission peak does not show apparent shift, which is related to the fact that fluorophore are surrounded by highly branched dendrons. These results provide a new route for design and assembly of luminescent materials.

溶液中的荧光光谱和多层膜的荧光光谱的形状和峰位都非常接近，这和发色团处在树状分子的三维支化结构的中心是直接相关的，这一研究对发光材料的分子设计具有重要的指导意义。

Its basic principle, classification, applications, and new developments are introduced and described in detail. 2 A new optimum method named simulated annealing algorithm is introduced and applied in the analysis of the ellipsometric spectra. 3 Some new ferroelectric materials have been studied by the method mentioned above, and some new results achieved as follows. First, Ca-modified lead titanate ferroelectric thin films have been prepared by solgel processing. The optical constants spectra of the 〓(x=0.0-0.4, 0.24) films have been obtained, the structure properties of the thin films have been studied by XRD and AFM.

回顾了椭偏光谱近一个世纪的产生发展的历程，系统介绍了椭偏光谱的基本原理、物理模型，以及广泛应用与发展状况。2）介绍模拟退火算法这一新型的优化方法，并将其结合Forouhi-Bloomer模型和Sellmeier模型应用到椭偏光谱分析中。3）用上述方法分析几种新型铁电材料的光学性质，并获得以下结果：首先，第一次获得钛酸铅钙系列、钙原子含量分别为0％、10％、20％、24％、30％、40％的铁电薄膜的光学常数谱，并结合XRD和SEM分析其结构，发现随钙含量的增加，薄膜晶相发生变化。

The hyperfine effects emerging in all spectra of atomic Rydberg states are due to the nuclear effects including hyperfine structure and isotope shifts. The autoionizing Rydberg states converging to 6p〓 and 4f〓 5d6s 〓 [3/2] 〓 limits were investigated by three photon excitation. In the study of the spectra for those converging to 6p〓 limit, the ICE (Isolated-core excitation) model has been proved to be suitable for describing the excitation of the autoionizing Rydberg states with a lowly excited core.

论文对实验中得到的收敛于6p〓及4f〓5d6s〓[3/2]〓的Yb原子自电离Rydberg态及其激发光谱进行了分析，特别是通过对收敛于6p〓的Yb原子自电离Rydberg态光谱的研究，论证了孤立实激发模型在低核实激发的自电离Rydberg态研究中的适用性。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。