光电子的

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

In the aspects of research method, we took the method of preparing sol at first and then impregnating the wood to obtain ceramic-wood composite; this method made the wood use efficiently and increased the wood's weight gain percent. The ceramic-wood composite with performances of well decay resistance, dimensional stability, effloresce resistance and high strength was obtained by importing the cymene to the net of gel as the result of co-hydroxylation between MTES and TEOS. Making use of XPS ,we found that the apex of Si2p、O1s、C1s had evident chemical shift , which validated the existence of Si-O-C bonding.Key Words: Sol-gel, Ceramic-wood composite, Modified sol, Ecomaterials

在工艺方法上，采用先制备溶胶，然后浸注木材的工艺方法具有原料利用率高、提高增重率的优点；采用甲基三乙氧基硅烷和正硅酸乙酯共水解的方法，将甲基引入陶瓷化复合木材的凝胶内部，所制备的材料具有尺寸稳定性好、具有耐风化和耐腐朽性，强度高的特点；首次利用X射线光电子能谱，发现了Si2p、O1s和C1s谱峰发生了明显的化学位移，证实了Si－O－C键合作用的存在。

It is very difficult to eliminate these influence factors completely by conventional treatment. Surface properties and surface treatment of ultrafine red phosphorus and MMT and their interface properties with polymer matrices were studied in this thesis. The results were characterized by GC, FTIR, XRD, DTA, TG, XPS, UV, SEM, TEM and other physical and chemical methods. The main contents are as following: 1. The study of factors influencing ultrafine red phosphorus's invariability and phosphine liberation indicated red phosphorus undergone oxidation and dismutation reaction in air, and trace ion of iron, copper and nickel fastened water absorption and oxidation, in which the effect of copper ion was the most, while aluminium and zinc ion could slow down red phosphorus'oxidation, and silver ion had the best effect on red phosphorus moisture absorption. Inhibitors such as aluminium hydroxide, magnesium hydroxide, organic phenol and ferrous potassuim cyanide had a good effect on reducing red phosphorus moisture absorption and restraining phosphine liberation.

本文围绕纳微米材料的表面处理及其在高聚物基体中的应用这一主题，系统地研究了超细红磷和蒙脱土两种常见材料的表面特性、表面处理方法及其与高聚物基体的界面特性，通过气相色谱、红外光谱、X射线衍射、差热、热重、X射线光电子能谱仪、紫外光谱、扫描电镜、透射电镜等现代分析仪器以及其它物理、化学方法对实验结果进行了表征和分析，全文主要内容如下： 1、对影响超细红磷安定性的因素以及磷化氢的缓释研究表明：红磷在空气中发生缓慢氧化、歧化反应，微量的铜、铁、镍等金属离子增加了它的吸水和氧化速度，其中铜离子的作用最为明显，而铝、锌等离子减慢了红磷的氧化速度，银离子对减少红磷的吸湿性效果最好。

The performance and mechanism of corrosion inhibitions of POCA were studied bymethods such as weight-loss, electrochemistry, EDS, XPS and quantum chemistry. It isfound that POCA is cathodic corrosion inhibitor, having synergistic effect with HEDP andZn~(2+). The P and O atoms of phosphono have important electron density contribution toHOMO orbital and the electron gross orbital population is bigger than 1, so it is easy toform absorbing location between phosphono and metal resulting in good corrosioninhibition on mild steel.

通过利用失重法、电化学方法、扫描电镜、X光电子能谱、X-射线能谱和量子化学方法研究膦酰基羧酸的缓蚀性能及其机理，发现POCA是一种阴极型缓蚀剂，与HEDP、Zn~(2+)具有优良的协同增效作用；POCA分子中的膦酰基基团的P原子和O原子对HOMO轨道电荷密度贡献较大，且其轨道电子布居数均大于1，因此比较容易通过膦基与金属形成吸附位而对碳钢具有良好的缓蚀作用；对铜合金具有一定的腐蚀作用，但腐蚀作用比HEDP等有机膦药剂要小得多，同时与BTA具有优良的相容性，添加1mg／L的BTA则可以有效地防止铜合金的腐蚀。

Chapter Five: We use photoemission spectroscopy to study the interaction of the rare earth metal Cerium overlayers with GaSb (111) surface and their oxidation behavior as well.

第五章 利用超高真空中的光电子能谱的测量，就稀土金属Ce对半导体GaSb(111)表面的催化氧化特性进行了研究，并且研究了Ce的厚膜本身的氧化，探讨了Ce在催化氧化中所起的作用。

Inorganic salts produced in combustion of pyrotechnically generating aerosol fire extinguishing agent are strongly hygroscopic and potentially corrosive to metal surfaces in humid circumstances.

针对固体微粒气溶胶灭火剂对金属材料表面产生腐蚀性的问题，在气溶胶发生装置的释放通路中，通过汽化的十八胺对气溶胶固体颗粒进行原位表面包覆，采用扫描电镜和光电子能谱表征了包覆效果，对包覆前后气溶胶粒子的吸湿性和腐蚀性进行测试，结果表明有机包覆层的存在有效抑制了气溶胶颗粒的吸湿，达到了降低灭火气溶胶对铜片腐蚀性的目的

Therefore, zinc oxide and Eu~(2+)-activated strontium aluminate green phosphors were synthesized for the fluorescence conversion of near ultraviolet light-emitting diode, and their properties were examined by means of photoluminescent spectra, thermoluminescent spectrum, X-ray photoelectron spectroscopy and X-ray diffraction.

本研究针对近紫外LED荧光转换材料的要求，采用荧光光谱，热释光谱，X射线光电子能谱，X射线衍射等分析手段，重点研究ZnO绿色荧光粉和Eu~(2+)激活铝酸锶绿色长余辉荧光材料的合成，或提高发光效率和稳定性的新方法及其相关机制。并在以下几方面取得了一些进展： [1]将ZnS与一定量的卤化物MX(X=F，Cl，Br，I；M=Na，K，NH_4，Zn，ZrO)一起煅烧合成出发光性能优良的、具有六方纤维锌矿结构的ZnO绿色荧光粉。

The results indicate that the relative atom content of Nd islow contrasted to that of Fe, which results from the weak competitive reaction ofNdCl〓 because of the strong bulk effects. The results of x ray photoelectronspectroscopy reveal that other valence of Fe could be in NdCl〓-FeCl〓-GIC.It is considered as the result of the charge shift between FeCl〓,〓 and graphitein intercalating process. Structural model of RECGIC was supplemented after thinking of the chargeshift between the intercalates and graphite. The characteristic layer distance, I〓, ofstage-1 RECGIC were calculated by the model.

利用能谱分析测定了NdCl〓-FeCl〓-GIC中插入剂的含量，结果表明， Nd的相对含量低于Fe的相对含量，这是因为NdCl〓的空间效应较大，而致使其竞争插入反应处于劣势的缘故。X光电子能谱研究表明，Fe可能有其它价态存在，这是由于在插入反应过程中，FeCl〓、NdCl〓以及石墨间发生电荷转移等作用的结果。

Properties of sulfur passivated GaAs (100) surfaces are studied by using photoelectron spectroscopy and photoluminescence measurem...

本文通过光电子能谱的手段和光荧光谱的方法分析了硫钝化GaAs(100)的性质并在此基础之上对硫钝化的实际应用进行了初步的尝试取得了较好的效果。

Properties of sulfur passivated GaAs (100) surfaces are studied by using photoelectron spectroscopy and photoluminescence measurements. Some practical applications of the sulfurizing technique are carried out and very promisingt results are obtained.

本文通过光电子能谱的手段和光荧光谱的方法分析了硫钝化GaAs(100)的性质并在此基础之上对硫钝化的实际应用进行了初步的尝试取得了较好的效果。

Finally, according to market conditions and market products this article paper analyzes the trends in the development of camera technology, and designs a color night vision camera.

最后根据市场情况和市面上产品的情况分析了摄像机技术的发展趋势，并设计了一款彩色夜视摄像机。

Only person height weeds and the fierce looks stone idles were there.

只有半人深的荒草和龇牙咧嘴的神像。