光气

The key step involves reduction-amination of benzamine and -acetonide glycealdehyde 20 synthesized from cheap and available ascorbic acid . The hydrolysis product of 21 condensed with triphosgene to get 6, key intermediates of Linezolid and Eperizolid. After a series of reactions, we got Linezolid and Eperizolid in reasonable yields and purity. The spectrum and 〓 values of compounds 6 and other intermediates were identical with literature reported.

我们以国内非常便宜易得的维生素C为原料合成得到-丙酮保护的甘油醛20，20和取代苯胺经还原胺化反应制备得到二噁烷21，21水解后与三光气缩合成环得到利奈唑酮和埃皮唑酮的关键中间体6.6经一系列的反应合成得到了利奈唑酮和埃皮唑酮。6及一些中间体的〓D值与文献报道的数据相吻合。

The main products are Ultraviolet absorber of Benzotriazole,Antioxidant BHT and immediate of medicine.

威海金燕化工有限责任公司是以研制和生产精细化工产品为主的生产型企业，公司目前主要产品有苯骈三氮唑类紫外线吸收剂和酚类抗氧剂以及医药中间体三光气。

Then bis chloroformate was reacted with aromatic amines under the appropriate solvent and appropriate catalyst, after removed the solvent to obtain one kind of new amine-terminated polyether.

以聚氧化丙烯为基础原料，与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯，然后再与芳香多胺在合适的溶剂和催化剂下反应，脱除溶剂后得到一种新型的端胺基聚醚。

As a foundation raw material, propylene oxide was reacted with phosgene use the process tradition method that mean low temperature and high temperature two phosgenation sections to synthesis bis chloroformate .

以聚氧化丙烯为基础原料，与光气在合适的溶剂下经过传统的低温、高温两段法光气化反应合成氯甲酸二酯，然后再与芳香多胺在合适的溶剂和催化剂下反应，脱除溶剂后得到一种新型的端胺基聚醚。

Moreover, based on the petrochemical industrial characteristics, this specification has defined benzene piping with a hypertoxicity level of extremely harmful medium as Grade SHB piping and acrylon, carbonyl chloride, carbon disulfide sulphide and hydrogen fluoride piping with a hypertoxicity level of high harmful medium as Grade SHA piping.

此外，根据石化行业的特点，本规范将毒性程度为极度危害介质的苯管道作为 SHB 级管道处理，将毒性程度为高度危害介质的丙烯腈， 48 SH 3501-2002 光气，二硫化碳和氟化氢管道作为 SHA 级管道处理。

This project quests for a new route for synthesizing polyurethane not only with mild reaction conditions but also without environmental pollution basing on the fact that virulent phosgene used in the industrial process to produce isocyanic acid ester has badly been polluting the environment at present. And this project belongs to the research in basic application science.

本项目基于目前工业生产异氰酸酯过程中采用剧毒光气对环境造成严重污染这一事实，探索出了一种反应条件温和、无环境污染的新的聚氨酯合成路线，属于应用基础研究。

Signs of DNA laddering were observed in lung tissue of positive group.

光气染毒可造成小鼠肺水肿，引起肺Ⅱ型细胞发生DNA损伤和肺脏细胞凋亡。

Triphosgene ; carbamic acid ethyl ester ; phthalimide

三光气；胺基甲酸乙酯；邻苯二甲酰亚胺

Syntheses and characterization of transition metal complexes of Schiff base derived from adamantaneamine and salicylaldehyde

收率90%。将光气通入熔融的对硝基苯甲酸，将光气化反应物进行减压蒸馏，也可以获得对硝基苯甲酰氯。

Reduction of N-substituted-4-nitrophthalimides(1)to the corresponding amines(2)was performed in hydrochloric acid at 40 ℃ using stannous chloride as reduction agent, yielding produc...

氮气保护条件下，2与乙醇在固体光气作用下生成(2 取代 1，3 二酮 2，3 二氢 1H 异吲哚 5 )氨基甲酸乙酯(3)，3的产率为67%～92%。各化合物的结构均经1H NMR、IR、元素分析和FAB MS证实。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。