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In addition, there was an activity evaluation on TiOa thin film using HA as handle objects. The results showed that TiO2 thin film had a good effect on degradation of HA, and the degradation rate could attain to 52.9% in three hours which was 18.2% higher than that of direct photolysis, but when compared to the TiO2 aqueous suspensions, the degradation rate of TiOa thin film was a little lower.

并以腐殖酸为处理对象,对TiO_2膜进行了活性评价,发现该固定TiO_2膜光催化体系对降解腐殖酸有良好的效果,反应3h,腐殖酸的降解率达52.9%,比直接光解法降解腐殖酸的效率提高了18.2%,但与悬浮态TiO_2光催化氧化系统相比,其降解效率略有降低。

The results of photocatalytic degradation to methyl orange show that the mixed crystallite of anatase and brookite has the best photocatalytic activity.

光催化降解甲基橙活性结果表明锐钛矿和板钛矿混晶具有最好的光催化活性。

Then, the mechanism and rate constant of the photocatalytic degradation of the methylene blue solution were investigated.

结果显示,反相微乳液法制备的纳米TIO:具有较高的光催化活性,但负载型光催化剂MCM一TIOZ显示更好的光催化活性。

Therefore, it is necessary to determine the intermediates and mineralization products and obtain photocatalytic degradation mechanism finally.

因此,有必要研究光催化降解反应的矿化产物、中间产物进而得到其光催化降解机理。

The investigation of catalyze indicated that the Bi2O3 could oxidate sodium nitrite under the light, which deserved further research.

Bi_2O_3光催化亚硝酸钠研究表明:Bi_2O_3对亚硝酸钠有良好的光催化氧化能力,值得进一步研究。

In this thesis, semiconductor photocatalysis materials, especially the development and application of nanosize TiO2 are reviewed comprehensively.

本文全面综述了半导体光催化材料,尤其是纳米TiO_2光催化材料的发展及应用现状。

A new technology of plasma-photocatalysis combination was proposed to remove stenchful gas from sewage pump station.It was showed that this combination technology had a quite notable synergistic effect.And the synergistic effect could be enchanced by adjusting the distance between plasma unit and photocatalysis unit and setting some nets between them to eliminate the influence of negative charges produced by plasma unit.

尝试用一种等离子体光催化复合技术净化污水处理泵站臭气,研究表明,该种复合技术具有较显著的协同促进效应,通过改变等离子体发生单元与光催化单元的距离以及在两者之间放置去静电网,可消除等离子体单元产生的负电荷对光催化单元的不利影响,进一步提高其复合效应。

By water contact angle meter, photocatalytic ability of several kinds or crystal form of TiO2 has been compared. In addition, OH and OH~ have been proved to be in existence on coating surface by FTIR.

通过接触角仪比较了不同晶型和不同型号的纳米TiO_2以及颜料级TiO_2光催化能力的差别,并利用红外光谱证实在纳米级光催化涂料的表面产生了具有很强光催化作用的氢氧自由基。

The efficacy of photocatalytic oxidation was relative to the number of dip-coated plate, which 2 and above plates was superior to one plate, and also vertical plane to the light source was more efficient than parallel plane. The reaction rate constant showed the color removal decreased as initial MB concentration was raised. As for efficiency of catalyst durability, it was found that TiO2 dip-coated stainless steel plate performed 95% color removal at 5ppm MB even after 4 times repeated usage, which showed favorable durability. However, when the concentration up to 10 ppm, the color removal decreased as the used counts was raised.

脱色率和钢网片数有关,钢网片数超过2片以上时,其光催化效能优於单片者;光催化效能与钢网摆放方式或光源入射的角度有关,与光源垂直摆放的脱色率优於与光源平行摆放者;由反应速率常数得知,反应物之脱色率随著反应物初始浓度的提升而递减:在耐用性方面,亚甲基蓝5ppm在重覆使用四次后,其六个小时脱色率皆维持95%,显示自制光触媒钢网之耐用性颇佳,若将反应物浓度提升至100ppm,其脱色率随著使用次数之增加而递减。

The problem in using titanium dioxide as a photocatalyst is recombination of electron and hole. One strategy for inhibiting theirs recombination is to add other electron accepters to the reaction. It can reduce the electron/hole recombination and then produce more ·OH on the surface of titanium dioxide, from which increased the degradation rate of the pesticide.

二氧化钛作为光催化剂进行光催化降解的问题在于电子—空穴对的重新复合,抑制其重新复合的一种办法是加入其他的电子接受体,减少电子—空穴对的复合,从而使光催化剂TiO2表面产生更多的·OH自由基,加强农药的光催化降解。

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