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Result of photocatalytic degradation of methyl orange showed that the TiO2 photocatalytic activity decreased with the decreasing of anatase ratio in the mixed crystallite of anatase,rutile,and brookite;and photocatalytic activity of pure rutile TiO2 was relatively bad.

光催化降解甲基橙的研究表明,所得锐钛矿、金红石和板钛矿3种混晶中,二氧化钛的光催化活性随着锐钛矿含量的降低而降低;纯金红石型二氧化钛的光催化活性较差。

In a static photocatalytic reactor,the gas-phase adsorption and photocatalytic degradation of benzene and butyraldehyde over the two photocatalysts were studied,and the intermediates and products were detected by gas chromatography.

利用溶胶-凝胶并水热处理法制备了TiO2光催化剂和TiO2/AC复合光催化剂,在静态光催化反应器中研究了苯和丁醛的气相吸附和光催化降解,利气相色谱分析确定了生成的中间体。

According to study on UV-Vis opitical property、qualitative antibacterial experiment 、quantitative antibacterial experiment of anatase nano-TiO_2 and antibacterial powder (adulterated by Ag ion and Ce ion) we turned out that antibacterial powder's diffuse reflection spectrum obviously Einstein shift which makes it can absorb more visible-light. Not only irradiated by UV-light but also irradiated by visible-light antibacterial powder both possess photocatalytic capability, which brought new functions that improve latex's quality.

通过对锐钛型纳米二氧化钛和抗菌粉等光催化纳米材料的UV-Vis光学分析、定性抗菌试验、定量抗菌试验的研究表明,复合掺杂银、铈等稀土离子的锐钛型纳米二氧化钛,其UV-Vis漫反射光谱明显红移,大大加强了它对可见光的吸收能力,因此除了在紫外光为光源的条件下具备光催化能力,在普通光源条件下也具备光催化能力。

Solar light pipe combined with photocatalysis could introduce sunlight into rooms and also has air purification function.

太阳能光催化-导光管将太阳光导入的同时兼具光催化空气净化功能。

The prepared powders were characterized by XRD, UV-Vis, FTIR, N_2 adsorption, Fluorescence spectroscopy, etc. N-doped TiO_2 evidently shows its absorbance shoulder shift into visible light region. Moreover, N-doping retards the transition of TiO_2 from anatase to rutile type as well as restrains the growth of the crystal size which leads to less decrease of surface area. These characteristics are considered to benefit the photoactivity of TiO_2; When all the samples were applied to the photodecomposition of Methylene Blue under visible light(λ>400 nm), the N-doped TiO_2 show an obvious superiority when compared to the undoped TiO_2, the active hydroxyl groups are found to play a important role in this high photoactivity; When the same experiment was performed under UV light, all the samples show the consistent sequence of photoactivity as in the visible light.

通过UV-Vis、XRD、BET、IR、FL等表征手段测试表明:掺氮不仅使TiO_2的光吸收区域拓展到可见光区,而且有利于延缓TiO_2晶相的转换,从而抑止了高温煅烧下所引起的晶粒增大以及比表面积的降低,且氮源浓度越高,此现象越明显,这些特征都有利于催化剂光催化活性的提高;在主波长大于400nm的可见光催化亚甲基蓝实验当中,掺氮TiO_2的光催化活性明显优越于未掺氮样品,亚甲基蓝在90min内达到88%的脱色率。

At present, film photocatalytic is studied mostly for treating with water pollution. Because the film will not bring the secondary pollution, and can be used again. ZnO film and TiO_2 film is mostly used as photocatalyzer, but they have some disadvantage, as they can only absorb little of the sun-light energy, the photoluminescence exciton compounds mostly, and they can be eroded easily by light. Complex semiconductor film is a good method to ravel out these problems.

目前,在光催化治理水污染方面,膜的光催化是一个研究的热点,因为膜催化不存在二次污染且便于回收和重复利用,研究较多的是ZnO薄膜和TiO_2薄膜,但是单一组分的薄膜存在光能利用率低,光激子复合率高,易发生光腐蚀等缺点,复合膜是解决该问题的有效途径,我们提出了全新的复合薄膜的制备方法—混合溶胶法。

Experiments showed that the photocatalytic reduction of inorganic oxidizing species and the photocatalytic oxidation of the organic compounds are synergically. This indicates that the COD value is proportional to the amount of the photocatalytic reduction of inorganic oxide.

实践表明,无机氧化物光催化还原和有机物的光催化氧化是协同进行的,因此我们可以由光催化还原无机氧化物量的变化来定量计算水样中的COD值。

Use SEM/EDX, TEM and XRD instrument to determine the basic characteristic of the photocatalyst, and apply the photocatalyst to decompose methyl blue solution to discuss with its performance and functions.

用铜属本身捕获二氧化钛光生电子的能及其变价特性,有效减少电子电再结合的机,因此经过属改质的二氧化钛光触媒具有佳的光催化效果,藉由SEM/EDX、TEM与XRD等仪器鉴定此光触媒之基本特性,并将其应用於分解亚甲基溶液以探讨其光催化分解性能。

Additionally, morphological structure and properties of the TiO_2 prepared by using the conventional heating and microwave dielectric heating were also compared detailedly. Acetaldehyde was chosen as a model reactant to valuate the performance of the samples.

通过自行设计的微波-光催化反应器,在功率100~170 mW、频率36 GHz 的微波和紫外光同时存在下研究了TiO_2对乙醛的光催化氧化性能,并与单纯紫外光存在下的光催化过程进行了比较。

The results show that perfect anatase nanocrystalline TiO2 can be obtained by SGRTSE method and the photocatalytic activity of TiO2 can be improved by doping and surface treatment. In the experimental system, the addings of proper salts are beneficial to the photocatalytic degradation of DBSNa. The pH value of solution, adding amount of TiO2, flow rate of air, and initial concentration are the main influence factors for the photocatalytic degradation of methyl orange, and the apparent reaction order is pseudo-first-order, which could be described by Langmuir- Hinshelwood equation.

结果表明:sol-gel法结合室温溶剂蒸发诱导可制备出晶型良好的锐钛型纳米TiO_2;过渡元素和稀土元素杂原子掺杂,贵金属掺杂和表面酸化处理是有效提高TiO_2光催化活性的途径;试验体系中,在DBSNa的降解过程中加入适量的盐,可以大大加速降解效果;光催化降解水中有机物,溶液pH值,TiO_2投加量,曝气速率,被降解物起始浓度等是影响降解效果的重要因素;对起始浓度较低的有机物光催化降解过程可利用简化的Langmuir-Hinshelwood动力学方程进行描述,反应级数为拟一级。

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