光催化的

The invention relates to a method of preparing acetophenone by ethylbenzene photocatalysis and oxidation, belonging to the technical field of organic synthesis application.

本发明涉及一种乙苯光催化氧化制备苯乙酮的方法，属于有机合成应用技术领域。

Use semiconductor to adulterate to also can improve the smooth catalysis performance of TiO_2 film well, among them with SnO_2 effect best.

采用半导体掺杂也能很好地提高TiO_2薄膜的光催化性能，其中以SnO_2效果最好。

As for photocatalytic oxidation, the dispersion , recycling and loading technology of catalyzer has not been mature so far

光催化氧化法的催化剂分散、回收及负载技术还不很成熟。

In recent years, applications to environmental cleanup have been one of the most active areas in heterogeneous photocatalysis.

近年来，应用复相光催化净化环境已成为最活跃的研究领域之一。

The photocatalytic degradation process of azo dye Congo Red was investigated in aqueous suspension of TiO 2, and the optimum reaction conditions were determined.

通过研究在间歇悬浮体系中直接偶氮染料刚果红在水中的光催化降解过程，确定了最佳降解条件。

The developing directions of combining nanometer photocatalysis technological with activated carbon fiber together to decontaminate a...

并对今后利用纳米光催化技术与活性炭纤维相结合用于净化空气的发展方向进行了展望。

These phenomenon showed that there were interactions between the frontier orbits of TiO〓 semiconductor and the heteroatom. It give a further support to the new point of view drown by us that the DOS at the lower part of CB and the upper part of VB of semiconductor nano-TiO〓 was important to the photocatalytic activity.

说明了杂原子的前线轨道能级与TiO〓半导体的前线轨道之间有相互作用，从而进一步印证了我们提出的半导体光催化剂价带顶部和导带底部的能级密度对纳米TiO〓催化剂光催化活性有较大影响的新观点。

The experiments show that TiO〓 nanowire arrays have higher photodecomposition efficiency than TiO〓 film. It is due to not only their higher surface area, but also their wider energy gap. 6. Ordered NiO nanowire arrays embedded in anodic alumina membranes have been prepared by using an electrochemical deposition method. Thermogravimetry curve shows that NiOH embedded in AAO decomposed slowly compared to thin film.

可能存在两个原因：氧化钛纳米丝具有比氧化钛纳米膜更大的比表面积；氧化钛纳米丝的光学带隙大于氧化钛纳米膜的，带宽的增加，使得价带电子电位变得更正，导带电位变得更负，这实际上增加了光生电子和空穴的氧化还原能力，提高了半导体光催化氧化有机物的活性。

Composition of suspension will chang from titanium monoxide to titanium dioxide during standstill procedure. Experimental results show that the proposed method can successfully prepare the anatase phase of titanium dioxide .In the photocatalysis experiment, the prepared titanium dioxide nanofluid absorbs the Ultraviolet when light wavelength was 360 to 380 nm. Adsorption experimental results show that the efficiency of absorbing methylene blue using TiO2 is higher than that for TiO2 (Degussa P-25) or ZnO. Depigmentation of methylene blue experimental using TiO2 can depigmentize methylene blue reach 100% in 60 min.

悬浮液所含之奈米颗粒在静置过程中，成份方面会由似一氧化钛转变为二氧化钛；在结晶组成方面，所制备之二氧化钛颗粒之结晶组成为锐钛矿结构；在光催化方面，所制备之奈米二氧化钛悬浮液在光波长360nm~380nm时产生吸收紫外光现象，在吸附实验中本制程所制备的二氧化钛颗粒的吸附效果优於商用的二氧化钛及氧化锌，在亚甲基蓝的脱色实验中本制程所制备的二氧化钛颗粒能在60分钟内达到脱色率100%。

Research result indicated that the cooperative effect between swell and precursor is main factor for the nanoparticle loaded in Nafion, and moreover, polarity of solvent and water content in Nafion also affects the load largely. To improve away the surface concentration of CdS nanocrystal on two side of membrane for general preparation, thioacetamide was first used as a precursor instead of inorganic sulfur source(H2S and Na2S) in synthesis of CdS nanocrystal. The assembly mechanism for several sulfur source had been studied, and CdS/Nafion with the character of homogeneous disperse had been prepared, which is fit for mass transmission in photocatalitic reaction. Following the investigation of several crystallizing way, simple and reliable hydrothermal-crystallizing was found. According to this way, maximal TiO2 load in Nafion achieved 43%. Activity of TiO2/Nafion or CdS/Nafion as a photocatalyst was explored initially for disintegrating liquid contamination. Maximal decompose rate achieved 86% under condition of this research.

研究结果表明：Nafion膜对纳米粒子负载量的主要影响因素是溶胀作用与前驱体协同效应，同时溶剂极性和薄膜含水量对负载量也影响相当大；本课题首次使用硫代乙酰胺代替传统无机硫源（H2S、Na2S）合成CdS纳晶，研究了各种硫源的组装机理，克服了常规技术存在的CdS纳晶趋于膜表面富集的缺点，得到了有利于光催化传质需要的体相均匀分布CdS/Nafion；研究了多种Nafion膜内纳米粒子晶化途径，找到了简单可靠的水热晶化法，TiO2纳晶最高负载量达43％；初步探索了TiO2/Nafion、CdS/Nafion作为光催化剂降解水中模拟污染物的活性，在本实验条件下最高降解率达86％。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！