光催化的

Selective doping has been proved to be a semiconductor oxide improve the photocatalytic activity of the most effective ways The introduction of certain metal ions can greatly improve the photocatalytic oxidation efficiency, Recently, a lot on the adoption of the doping to improve the photocatalytic oxidation performance reports, doped semiconductor photocatalysis material because of its physical and optical properties change, thereby improving the photocatalytic properties.

有选择性的进行掺杂已被证明是一种提高半导体氧化物光催化活性的极其有效的方法，掺入一定的金属阳离子能极大的提高TiO2的光催化效率，最近有大量的关于通过掺杂来提高TiO2的光催化性能的报道，掺杂的半导体光催化材料由于其物理和光学性质的改变，通过扩展光响应范围和提高光生电荷的分，从而提高了光催化性能。

The development and manufacture of photocatalytic reactors were also carried out in the scale of model and practical engineering application.

光催化研究的核心内容就是研发出性能优良的光催化体系；其次是高效低能耗光催化反应器的设计，这两个方面内容是二氧化钛光催化技术实际应用的前提与基础。

The TiO2 synthesized by normal and reverse micelles as templated were applied for phot ocatalytic of Rhodamine B and organic toxic small molecule 2.4-dichlorophenol under ultraviolet irradiation. Oxidation species and photodegradation products in the photoreaction process were detected for studying their photocatalyst properties. The results showed that: the R-TiO2 had a better photocatalysis property under UV irradiation when photodegradation of RhB and DCP compared to the N-TiO2. After 160min, the mineralized rate of RhB can be 95%. And the oxidative species was mainly referred to OH radical.

利用正相和反相胶束介质模板制备的纳米TiO2为光催化剂，在紫外光照射下，对染料罗丹明B和有机有毒无色小分子2，4-二氯苯酚进行光催化降解，研究了其光催化性能，并对光催化过程中氧化物种及降解产物进行了跟踪测定，结果表明，反相胶束模板体系制备的纳米TiO2与正相胶束介质制备的纳米TiO2比较，在紫外照射下对RhB及DCP的降解有较好的光催化性能，对RhB在160min尤催化矿化率可达95%，光催化反应主要的氧化物种涉及在基自由基。

Generally, the main point of this thesis rests with exploring novel hydrothermal methods to synthesize functional stannate composite oxides nano-materials, and studying the formation and morphology controlled mechanism of the composite oxides nano-materials under hydrothermal conditions. The main research achievements are summed up as follows:(1)According to the testing needs of photocatalytic hydrogen-generation, we have designed and set up a suit of photocatalytic H2-generation equipments with external light irradiation.

本文正是在这一背景条件下，重点研究以水热法合成锡酸盐纳米光催化材料，并对合成出的样品进行了细致的表征分析，初步研究纳米材料的光催化活性，探索纳米催化剂的颗粒尺寸、形貌和晶体结构对催化性能的影响规律，其内容主要包括以下几个方面：(1)根据光催化制氢的需要，设计并组建了一套外置光源照射的光催化制氢装置。

The photocatalytic oxidation performance and kinetics of the simulated organic wastewater in a circulating slurry photocatalytic reactor was investigated.The effects of operation conditions, such as dosage of photocatalyst, illumination time, initial benzamide concentration, pH value, anions and cations in wastewater, on the photocatalytic oxidation performance were discussed.

采用循环式浆态光催化反应器对苯甲酰胺模拟废水光催化氧化特性和动力学进行了研究，系统地考察了操作条件对模拟污染物光催化降解的影响，并与搅拌式和鼓泡床式浆态光催化反应器中苯甲酰胺的降解效果进行对比。

SO〓〓/M〓O〓 solid superacid was applied to the photocatalytic oxidation of organic pollutants for the first time. Porous SO〓〓/TiO〓 solid superacid catalysts with high specific surface area were prepared by sol-gel method. The photocatalytic degradation of bromomethane was used as model reaction. The influence of impregnation with H〓SO〓 solution on the structure of catalysts and their photocatalytic performance was systematically studied by using X-ray diffraction, X-ray photoelectron spectroscopy, N〓 sorption analysis applying BET method, UV-Vis diffuse reflectance spectroscopy, FTIR spectroscopy, O〓-TPD and photocatalytic activity measurement. The acidity of TiO〓-based catalysts was investigated by Hammett indicator method, NH〓-TPD and IR spectra of pyridine adsorbtion. The mechanism of superacidifing effects on photocatalytic performances such as the photocatalytic degradation rate of bromomethane, apparent kinetic constant and apparent quantum efficiency was discussed.The results indicated that SO〓〓 is combined with metal ions of TiO〓 in a chelating bidentate mode.

本文首次将SO〓〓/MxOy型固体超强酸催化剂用于光催化氧化有机污染物研究，采用溶胶-凝胶法制备了具有多孔性和大比表面结构的二氧化钛基固体超强酸光催化剂SO〓〓/TiO〓，以光催化降解溴代甲烷为模型反应，系统地研究了H〓SO〓浸渍处理对催化剂表面酸性及其气相光催化性能的影响，结合XRD、BET、XPS、FTIR、Hammett指示剂法、吡啶吸附红外光谱、NH〓-TPD、O〓-TPD、紫外可见漫反射光谱等多种表征手段，深入地讨论了超强酸化对TiO〓的改性机理，阐明了引起SO〓〓/TiO〓超强酸催化剂光催化降解溴代甲烷的转化率、表观反应速率常数和表观量子效率变化的本质原因。

In this paper,we compared the photodegradation efficiency of nano-titania films by using dichloroacetic acid,rhodamine B and methyl orange as the photocatalytic referents and the ultraviolet lamp as the source light to generate the photocatalytic reaction.

针对纳米氧化钛光催化性能研究中缺乏统一有效表征标准的现状，比较了二氯乙酸、罗丹明B和甲基橙三种光催化活性评价物的热稳定性和对紫外光的稳定性，并以氧化钛纳米薄膜为光催化剂，研究了三种评价物的光催化降解效率表征，以及酸碱度、通氧条件等因素对评价物在光催化活性表征中的影响及其机理，归纳了三种评价物对于纳米氧化钛光催化活性表征的优缺点。

The anatase crystals of the TiO2 films connected together to form netlike structure after calcined, and th

在自制的光催化反应装置中以10mg/L甲基橙为降解对象，考察了TiO2薄膜的光催化性能，在4h内直接干燥的TiO2薄膜脱色率达到95%，经热处理后薄膜的光催化性能有一定提高，这说明采用AS溶胶前驱体制备的TiO2薄膜光催化性能良好。

While in photoreduction of Cr , the titania-modified MCM-41 photocatalysts were more photoactive than the titania-silica composite (25％ TiO〓).

在光催化降解苯酚中氧化钛修饰MCM-41的光催化活性虽然不及结晶的锐钛矿相纳米氧化钛，但是仍具有较高的催化活性；在光催化还原Cr到Cr反应中氧化钛修饰MCM-41的光催化还原性明显高于部分结晶的TiO〓-SiO〓（25wt％TiO〓）复合氧化物。

The results indicated that the effect that light catalysis oxidation treated leach was related to the kinds of catalyst, and the result of treatment using autanse-TiO2 is better than rutile. Catalysis capability is improved obviously after autanse-TiO2 was calcined at 600℃, and the way of calcine had large actions for catalysis.Photo-catalytic degradation of organic compound in leaches was carried out with TiO2,-Fe2O3 and ZnO,the following conclusion can be attained.

研究结果表明半导体光催化剂TiO2对垃圾渗滤液的光催化效果和TiO2的晶型有很大的相关性，锐钛型TiO2的光催化效果明显优于金红石型TiO2；高温处理锐钛型TiO2改变其晶型和表面结构，600℃煅烧TiO2的光催化活性有较大提高；光催化剂的活化方式亦影响光催化效果。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

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如果有任何问题，你可以随时联系我。