光催化的

Having experimented and studied of photocatalyses by ultraviolet rays and titanium dioxide which in millicron state,then,we applied photocatalysis technology of millimicron material to relevant luminaire.

本文通过紫外线与纳米级TiO2 材料进行光催化的试验研究，然后将该项技术应用到相应的灯具上，使常用的照明灯具在室内起到了空气净化的作用，改善了生活环境和工作环

The experiment in vitro of killing cervical cancer cells was carried out by using TiO 2 photocatalytic method.

应用二氧化钛光催化的方法在体外对宫颈癌细胞进行了杀灭试验，结果显示，二氧化钛在光照下对宫颈癌细胞有明显的杀灭作用。

The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.

研究结果表明：SO〓〓与TiO〓表面的结合为螯合式双配位结构；TiO〓光催化剂表面经H〓SO〓浸渍处理后，提高了表面酸性，改善了催化剂结构和光催化性能，当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时，可制得SO〓〓/TiO〓超强酸催化剂(H〓＜-12.14)，其结构和光催化活性得到明显改善，与TiO〓相比，SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移，具有优异的光催化氧化活性、稳定性及抗湿性能，光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级，是一种有实际应用前景的高效光催化剂；由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型，认为在SO〓〓/TiO〓超强酸催化剂表面，由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心，其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移，具有可逆吸附水的性能，是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。

The aim of this dissertation was to investigate the effects of SPE technique on electrochemically assisted photocatalytic system.

通过对SPE法电助光催化的影响因素的研究，找出合适的光催化最佳条件。

The results showed that (1) The grain size of nanometer YiO_2 was40～80nm.The wavelength corresponding to the maximum absorbency values were observedin the 200～320nm range.The crystal structure of carbon doped TiO_2 photocatalyst is primarilyanatase(22.43% rutile), and the content of carbon is about 4.6%.(2) The relative humidityvaring from 8% to 80%, the photocatalytic degradation degree of benzene increased withincreasing relative humidity; and to toluene, degradation rate was hanced by relative humidityup to 60%, and more or less inhibited above 60%.(3) Scheme and results of orthogonal testswere used by evaluating the photocatalytic performance of the gas phase methanol, acetoneand 1-heptane.The results revealed that their degradation degree reached 84.5%, 93.39% and93.45%, respectively.(4) The 254nm UV lamp showed higher photocatalytic degradation rate.For methanol, acetone and 1-heptane, it was found that photocatalytic degradation reactionoccurs with the light strength of daylight lamp.(5) Under the the same conditions, 15%degradation degree has been obtained for benzene, whilst about 10% degradation degree wasattained by Degussa P25; During the initial phases, the toluene revealed higher photocatalyticactivity, comparing with Degussa P25, the degradation degree of methanol, acetone and1-heptane were slightly lower.

结果表明：(1)CVD法制备的纳米TiO_2光催化剂，颗粒球形度好、粒径在40～80nm之间；最大吸光度值所对应的波长为200～320nm；含碳量约为4.6％；晶型组成主要为锐钛矿型，金红石的含量约为22.43％；(2)在相对湿度为8％～80％范围内，苯的光催化降解率随着相对湿度的增大而增大；甲苯在相对湿度为60％时达到最好降解效果，当相对湿度增大到80％时光催化效果降低；(3)将正交实验设计及实验方案应用于气相甲醇、丙酮和正庚烷光催化降解研究，实验结果表明：三者最高降解率分别为84.5％、93.39％和93.45％；(4)有254nm紫外灯参与的光催化实验可以大大提高有机气体的光催化降解率；在日光灯的照射下，掺碳纳米TiO_2对气相甲醇、丙酮和正庚烷具有一定的光催化氧化能力；(5)较P25粉，在相同的光催化操作条件下：气相苯的平均降解率达15％，高于P25粉10％的降解率；气相甲苯在初始阶段具有较高的反应速率；气相甲醇、丙酮和正庚烷的降解率略低于P25粉。

The photodegradation of methylic orange under UV light irradiation in aforementioned photocatalyst were studied.

通过对甲基橙光催化的研究表明：在同样条件下，TiO2-PEG400颗粒的甲基橙光降解效果明显优于其他颗粒，甲基橙光降解率最高达到97。

On this basis, chosing 15w germicidal lamp with radiation centred at 253. 7nm or 15w blacklight fluorescent lamp with radiation centred at 365nm as the light source respectively, the destruction effects of trace impurities in water by photocatalytic oxidation method using TiO〓 as an immobile phase have been investigated, and the effects are contrasted with photolysis. The investigation is mounted into Phenol aqueous solution, Hydroquinone and Humic Acid aqueous solutions、three representative halohydrocarbons coexisting in main water、the comprehensive index removal of varied trace organic pollutants in main water、the removal of residual chlorine and the disinfecting action, etc..

在此基础上，选择主波长253.7nm的紫外线杀茵灯或主波长365nm的蓝黑管紫外线荧光灯作为光源，研究了TiO〓膜固定相光催化氧化法去除水中微污染物的效果，包括苯酚水溶液、对苯二酚水溶液和腐植酸水溶液的光催化氧化以及自来水中共存的三种典型的氯代烃水溶液三氯甲烷、四氯化碳和四氯乙烯的混合光催化氧化、自来水中有机物总体去除效果以及光催化去除自来水中余氯的作用和光催化的消毒作用等，并进行了光解对比实验。

In this study, the degradation of dyes (methylene blue, methyl orange, and indigo) in water by means of photocatalytic oxidation was studied.

故本研究探讨以光催化的方法将水中的染料－亚甲基蓝、甲基橙及靛青等予以破坏、降解。

The following main results are obtained: The TiO_2 photocatalyst with small crystallite size, high surface area, narrow and uniform pore size distribution, and microporous frameworks could be prepared out by applying MW radiation in the preparation process. The microwave-induced fluorescence technique verified for the first time that microwave enhanced the formation rate of hydroxyl radical, leading to the increase in the photocatalytic efficiency. Compared with the conventional catalyst, TiO_2 prepared by MW dielectric heating owns a higher UV absorption ability, and its optical absorption edge and photovoltaic response are shifted toward the short wavelength region, resulting in increase of photooxidation efficiency. The photocatalytic conversion and the mineralization ratio of acetaldehyde are increased respectively by 30% and 40% over the TiO2 prepared by MW radiation when compared to the TiO2 prepared by the conventional heating. For the MW-assisted photocatalytic reaction over the MW-prepared TiO2, production of hydroxyl radicals is enhanced by 22.5%, and the photocatalytic conversion is accordingly increased by 20%. Similarlly, applying MW also increased the photocatalytic conversion and the mineralization ratio of acetaldehyde over TiO2/Al2O3 sample.

论文得到如下主要结果和结论：(1)微波介电加热TiO_2 溶胶可得到晶粒度小、光催化活性高、比表面积大和孔径分布窄而均一，且微孔发达的TiO_2光催化剂；在溶胶干燥处理过程中微波可使催化剂表面缺陷增加，进而导致光催化反应过程有更多的活性羟基自由基产生；(2)微波制备能显著增强TiO_2 样品的紫外光吸收率，并使其光吸收和光伏响应阈值发生蓝移，从而提高TiO_2的氧化还原能力；(3)与常规加热法所制TiO_2比较，微波法制备的TiO_2对乙醛的光催化降解转化率提高30%，CO_2生成率提高40%以上；(4)与未加微波辐射时相比，发现在光催化反应过程中施加微波，TiO_2 的羟基自由基生成速率提高了22.5%，相应CH_3CHO 光催化降解转化率提高了20%；对Al_2O_3/TiO_2催化剂，CH_3CHO 光催化降解转化率甚至提高了33%，同时CO_2 的生成率也都大幅度提高；(5)微波辐射可改变光催化降解乙醛的产物分布，推断施加微波时乙醛光催化降解按照羟基自由基引发的链式反应机理进行，微波&非热效应&起主要作用。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。