催化的

Methods for synthesizing of pinacol are reviewed,the difference of catalytic effects and stereoselectivity with various catalytic systems are introduced in this paper.Highlights are laid on the mechanism and stereoselectivity of new synthetic methods catalyzed by low valent Samarium, Titanium and Trimethyl chlorosilane, etc.

频哪醇合成新进展* The Recent Progress in the Synthesis of Pinacol 李有桂蒋昌盛尤田耙**(中国科学技术大学化学系合肥 230026)本文综述了合成频哪醇的方法，介绍了不同催化体系的催化效果和立体选择性的差异，着重介绍了低价钐、低价钛、三甲基氯硅烷等新的合成频哪醇反应的机理和立体选择性。

The maximal reaction rate of pyrotechnical reagent with potassium nitrate added with CuO by mixing method is 7.38 min-1, which is 1.30 times of that without catalyst. The time to maximal rate is 53.55 min, which is lower than that without catalyst by 66.3%.

氧化铜对含硝酸钾的烟火药剂具有催化作用，混合法添加的催化效果最佳；此药剂最大反应速率为7.38 min-1，是不含催化剂药剂的1.30倍；到达最大反应速率时间为53.55 min，比不含催化剂的药剂降低了66.3%。

The maximal reaction rate of pyrotechnical reagent with potassium perchlorate added with Fe2O3 by crystallization method is 8.10 min-1, which is 4.09 times of that without catalyst. The time to maximal rate is 8.52 min, which is lower than that without catalyst by 92.8%. It was also found that CuO can catalyze pyrotechnical reagent with potassium nitrate, and the addition is better with mixing method.

结果表明，氧化铁对含高氯酸钾的烟火药剂具有催化作用，以结晶添加法催化效果最佳；此药剂的最大反应速率为8.10 min-1，是不含催化剂药剂的4.09倍；到达最大反应速率时间为8.52 min，比不含催化剂的药剂降低了92.8%。

The catalytic cracking of NNJ 150 over USHY, HZSM 5 and SAPO 34 catalysts presented as that the selectivity of light olefins over USHY was the lightest among the three calalysts with a quicker deactivation, while HZSM 5 showed a longer catalyst life and lower selectivity of light olefins, for SAPO 34, both the conversion and the selectivity of light olefins were the lowest.

实现吸热型碳氢燃料这种功能的关键之一是选择适当的化学反应。由于碳氢燃料的裂化是吸热反应，而催化裂化与热裂化相比，能降低反应的温度，因此催化裂化是实现吸热型碳氢燃料功能较好的途径之一。由热力学可知，燃料裂化生成乙烯、丙

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性，发现丁烷到异丁烯的一步转化无法在这一反应体系十有效实现。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性，发现丁烷到异丁烯的一步转化无法在这一反应体系中有效实现。

Contrasted with the activity of the same reaction in oil-water double phased system, the hydrolyzing behavior of Camlicla Lipolytica Lipase in reversed micellar systems is much like that in oil-water double phased system. The stability and catalyzing activity are both enhanced and give rise to "superactivity". except in reverse micelles composed of cationic surfactant.

实验表明，脂肪酶CLL在反胶束体系中催化水解反应的行为与油-水双相体系中的行为大体相似，在阴离子和非离子型表面活性剂构建的反胶束中，酶的稳定性和催化活性都有所增加，呈现&超活性&。

The Limit Oxygen Index also can be raised from 16.5 to 22 and 23 respectively.The Octaphenyl POSS is synthesized via the hydrolysis and condensation of phenyltrichlorosilane (PhSiCl_3) and the subsequent rearrangement reaction catalyzed by tetramethylammonium hydroxide. Poly are easily synthesized from Ph-POSS via bromination with Br_2/Fe system.

以苯基三氯硅烷为起始原料，通过水解缩合、催化重排的办法制备了八聚苯基笼型倍半硅氧烷，在Fe粉催化条件下将溴元素引入Ph-POSS的苯环得到Br-POSS；使用该种Br-POSS和Sb_2O_3的混合物(3∶1，质量比)作为聚苯乙烯树脂的添加剂，采用熔融共混法制备(Br-POSS+Sb_2O_3)／PS复合材料。

Alkylation reactions of thiophenic compounds with olefin contained in FCC naphtha on USY zeolite catalyst were investigated.

以USY分子筛催化FCC汽油中噻吩类硫化物与烯烃的烷基化反应，采用DL-2B-EE微库仑仪测定反应前后硫分布的变化，考察了USY分子筛的制备条件和烷基化反应温度对其催化性能的影响。

Molybdophopsphoric Acid Catalysis in the Oxidative Cleavage of Olefins by the Hydrogen Peroxide Oxidative cleavage of the double bond could be catalyzed by H_3PMo_(12)O_(40) using H_2O_2 as oxidant, various trisubstituted olefins were oxidized to aldehydes or ketones in high yields. The system was not satisfied for electron-deficient olefins such as trans-(2-nitrovinyl) benzol or chalcone. The reaction of aliphatic olefins did not occur under the same conditions.

二、磷钼酸催化过氧化氢对烯烃的氧化断裂反应用过氧化氢(30％)作为氧化剂，磷钼酸可以催化氧化碳碳双键的断裂反应，三取代的烯烃被氧化生成醛或酮，产率较高；此体系对于缺电子烯烃如查尔酮，不饱和硝基化合物的断裂反应效果较差，脂肪族烯烃在此体系下的氧化并不发生。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！