催化的

The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of Sodium tetraphenylborate (NaBPh4) with carboxylic anhydrides catalyzed by Pd(PPh3)2Cl2 in THF was first reported.

第二章：微波辐射下Pd配合物催化NaBPh_4与羧酸酐的偶联反应研究本章中我们在微波辐射条件下，研究了PdCl_2(PPh_3)_2催化NaBPh_4与羧酸酐偶联反应，合成出了十种不对称芳酮，并分别考察了微波辐射功率、辐射时间、溶剂和原料配比等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

Research progresses in the asymmetric addition of organozinc reagent s to imines in the recent decade are reviewed according to the kinds of chiral ligands.

亚胺的催化不对称加成反应是近年来不对称催化反应中的热点研究领域，从手性配体类型的角度总结了近10余年来有机锌试剂在亚胺不对称加成反应中的应用进展。

Nano titanium dioxide is of favorable biological and chemical inertness, strong oxidizability, low cost and long-term stability against photocorrosion and chemical corrosion. Nano TiO_2 and TiO_2/SiO_2 thin films are used photocatalysis degradation materials and self-cleaing materials, and can kill bacteria and virus.At present it is the hot spot in the research of photocatalysis, and it is of great value in the practical applications.

由于纳米TiO_2具有良好的生物和化学惰性、较强的氧化性能、低成本、以及对光腐蚀和化学腐蚀的稳定性等，故其薄膜不仅能用作光催化降解和自洁净材料，还能杀死细菌及病毒，是目前光催化材料的研究重点，具有广阔的应用前景。

In order to improve the electro-catalytic activity of platinum based catalyst to methanol oxidation, in this thesis, firstly prepare heteropoly acid modified Pt/GC electrode with different concentration by cyclic voltammetry method, and then test the cyclic voltammetry curves individually in vitriolic and methanol solution. The study shows the best concentration for both phosphomolybdic acid and phosphotungstic acid is 1×10~(-3)mol/L. And find the more heteropoly acid modified on electrode, the lower peak-up potential towards methanol because of the existence of oxygenous species.

为了改善铂基催化剂氧化甲醇的催化活性，本论文首先通过循环伏安扫描法制备了不同浓度磷钼酸和磷钨酸修饰的Pt/GC电极，通过研究Pt/GC电极在修饰前后在硫酸溶液中及含甲醇的硫酸溶液中的循环伏安行为发现，磷钼酸和磷钨酸均能在PtRu/C电极上发生氧化还原反应，而且杂多酸修饰浓度对Pt/GC电极氧化甲醇的催化活性有很大影响。

The aim of this thesis is to prepare rutile TiO2 nanorods under the hydrothermal condition and to investigate the correlation between the preparation parameters and the photocatalytic activity of as-prepared TiO2 samples. The initial sols for TiO2 were prepared by the hydrolysis and condensation of Ti precursor, titanium n-butoxide 〔Ti4, TNB〕 in DI-water with hydrogen chloride as a peptizer.

中文摘要本研究的主要目的是制备以水热法制备金红石相二氧化钛奈米棒并探讨其制备条件与光催化活性的相关性，以四丁基氧化钛为前驱物，在盐酸的催化下，经由水热处理来合成金红石相的二氧化钛奈米粒，并藉由XRD鉴定其结晶相，TEM来观察其外观形貌及其颗粒大小，氮气吸附法来分析其比表面积。

Goodcatalytic activities of the phosphine palladium complexes were observed incarbonylation of benzyl chloride with atmospheric CO. In some reactions the yieldof phenylacetic acid was 91% and the catalyst could be reused repeatedly in severaltimes.

这些钯配合物催化苄基氯的常压羰基化反应有较好的催化活性，有些反应中苯乙酸的产率可达91％，可重复使用，是一类环境友好的新型绿色催化剂。

Morphological structures of TiO2 such as crystal structure, particle size, surface area and surface state properties which influence photoactivity of the catalyst have been discussed.

本文介绍了TiO2多相光催化剂的作用机理及其结构特性对光催化活性的影响，并对TiO2的晶相组成、晶粒尺寸、比表面积、表面形态与光催化活性的关系作了综述。

TiO2 photocatalyzer supported on glass were prepared with sol-gel method. The photocatalytic degradation of methylene blue was studied including the effect of the factors such as reaction time, the initial concentration and pH value on the photocatalytic degradation.

采用溶胶－凝胶法制备了玻璃负载的TiO2薄膜光催化剂，研究了该催化剂对亚甲基蓝溶液的光催化降解，考察了反应时间、水样的初始浓度、溶液的pH等对光催化降解效果的影响。

New methods for asymmetric synthesis of pinacol are reviewed, the catalytic effects and stereo- selectivity with various catalytic systems are discussed in this paper.

综述了近年来不同催化体系的不对称合成呐醇的方法，并总结了不同的催化效率和对映选择性的差异

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！