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It indicated that the vibratile radicle decreased and new radicle appeared. The activity was the most when treated by acid in pH=1. The degradation rate was 62.96%, when treated with 98% H2SO4 and reacted for 2h.

酸处理的样品在pH=1时催化活性最好,其中98%的H2SO4处理的样品2h的降解率达到62.96%,该降解反应为二氧化钛的光催化反应。

Esterification process of a reversible step wereresolved as two irreversible steps,then chemical decomposition of wood components weredecreased in liquid acid catalyst.Experiments showed that crosslinking catalysts took catalysisrole on two process in the esterification,(1)five cyclic anhydrides formed by dehydration ofpolycarboxylic acids,(2)esters occurred by substitution between five cyclic anhydrides andwood.

实验中的反应过程使一般的酯化一步可逆反应,分解为两步不可逆反应,减少了液相酸催化过程的木材组分化学降解;交联反应催化剂对于多元羧酸类化合物与木材组分的酯化反应具有两个过程的催化作用:(1)多元羧酸脱水形成五元环酸酐中间体;(2)木材与五元酸酐中间体亲核取代反应形成酯。

Transformation into active enzymes occurs as one or more peptide bonds in the zymogen are cleaved.

活化作用即是打断原分子内的一个或多个键。这作用受不同的催化或受的活化型本身的催化。

In this chapter, the MPV reactions catalyzed by alkoxy dysprosium is used to the reduction of prochiral ketones. The chiral alkoxy catalyst was prepared by chiral binaphthol and Dy 〓.

最后还将烷氧基镝催化下的MPV还原反应应用于潜手性酮的不对称还原,利用光学活性的联萘酚制备了手性烷氧基催化剂,结果表明该催化剂可有效地催化潜手性酮的不对称MPV还原。

The catalytic reaction rate constant for amidopyrine in different conditions are also determined, and the rate constants agreed closely with the mechanism presented by us.

讨论了影响其催化反应速度的因素及条件;并对不同条件下氨基比林对亚铁氰化钾的催化反应速率常数进行了测定,所得结果很好的符合提出的反应机理。

Some new results are obtained from the studies: 1 a novel thermokinetic research method, the characteristic reduced parameter method, has been proposed, and the kinetics of oxidation of benzoquinone by hydrogen peroxide has also been investigated with this method; 2 the kinetic mathematical models that the metallomicelles made from the mono-nuclear or dinuclear complexes and surfactants catalyze the phenolic derivant oxidation have been established respectively; 3 the feasibility and mechanism that the metallomicelle, a mimetic model of peroxidase, catalyzes the phenolic derivant oxidation has been discussed.

研究得到如下新的结果:(1)提出了一种新的热动力学研究法——特征对比参量法,用该法研究了过氧化氢氧化苯醌反应动力学;(2)分别建立了由单核和双核金属配合物与表面活性剂形成的金属胶束催化酚类氧化反应的动力学数学模型;(3)探讨了金属胶束模拟过氧化物酶催化酚类氧化反应的可行性及其机理。

In this thesis, investigations focused on heteropoly acids-catalyzed C-C and C-N bond formation reactions and the synthesis of xanthenediones and acridinediones under thermal conditions are described.1.12-Phosphotungstic acid has been used as an efficient,eco-friendly,and air- and moisture-stable catalyst to promote the direct dehydrative substitution of the hydroxy group of benzylic and allylic alcohols with variousβ-dicarbonyl compounds.

本篇论文主要描述了杂多酸催化下的C-C和C-N键的生成,以及无溶剂直接加热下合成十氢氧杂蒽二酮和9-芳基十氢吖啶二酮。主要内容如下:1。在磷钨酸催化下,1,3-二羰基化合物与醇能够顺利偶合,脱除一分子的水,生成烷基化的1,3-二羰基化合物。反应在甲苯中进行时,二芳基甲醇能与各类1,3-二羰基化合物反应,成率很高;但对于1-苯乙醇,只能得到很低的产率。

The catalytic cracking of PS thermal product is assumed to proceed via carbonium ion species during which the oligomers appear to be more active.

通过PS在小型固定床反应器中热解及热解-催化结果的对比研究,就二者的产物分布差异探讨了PS热解-催化过程的正碳离子反应机理,对主要反应产物的生成途径作了推断。

This paper reviews the development of synthetic technology of carbon nanotube by catalytic py-rolysis of carbonous compound and compares the advantages and disadvantages of moving support method and floating catalysis method.

介绍了催化热分解含碳化合物合成碳纳米管的技术,比较了基板法和流动催化法的优缺点以及它们的发展前景,并简单地介绍了碳纳米管的应用领域。

In this thesis, several novel reaction-controlled chiral phase-transfer catalysts were designed and synthesized from readily available materials, and were used in the asymmetric epoxidation of unfunctionalized olefins and chalcone.

本文以有机合成方法学为目标,从廉价的原料出发,合成出几个新的反应控制的手性相转移催化剂,并且检验了他们在催化烯烃的不对称环氧化中的催化效果。

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她婉言拒绝了,但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

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