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In addition, ioding was found to be an efficient catalyst for the imino Diels-Alder reaction of N-arylimine and enol ethers and the reaction provided tertrahydroqinolines in good yields. One pot synthesis of tetrahydroqinolines from aldehyde, aniline and enol ethers was also achieved using iodine as the catalyst. The chemical yield of the"one pot"reaction was comparable with that obtained using preformed N-arylimine.

此外我们也发现碘能够有效地催化N-芳基亚胺与烯醇醚的Diels-Alder反应,以很高的化学收率得到了四氢喹啉衍生物,并且发现碘也能够直接催化芳香醛、苯胺、烯醇醚的三组分"一锅"反应,获得的化学产率与使用预制的N-芳基亚胺相当。

It has many potential applications such as producing and upgrading heavy water, removing tritium from light water or heavy water, and recovery tritium for fusion reactor.

本论文的主要研究内容分为四部分:憎水催化剂的设计和制备,憎水催化剂的性能评价,氢-水液相催化交换工艺研究以及电解结合催化交换工艺流程的理论计算。

By improving the chemical reaction between Potassium Iodide and Hydrogen Peroxide, using initial velocity and activation energy calculation, this paper proposes and discusses the reaction mechanism in the reaction.

通过改进碘化钾与过氧化氢的反应实验,用初速度的方法,通过活化能的计算,讨论提出的反应机理,确定反应级数和催化反应与非催化反应的速度常数。

Naphthylamine is the intermediate of various dye products and the major raw materials of various rubber aging inhibitors,ɑ-naphthol produced with ɑ-naphthylamine is the major intermediate of pesticide carbaryl; KT-02 nickel catalyst is used to prepare naphthylamine by nitro-naphthalene catalytic hydrogenation, the product has high purity and high yield, and it's currently one of the best technological conditions, and the catalytic activity of the catalyst does not deteriorate after multiple times of recycle.

萘胺是多种染料产品的中间体,也是多种橡胶防老剂的主要原料,由ɑ-萘胺生产的ɑ-萘酚是农药西维因的重要中间体,KT-02型镍催化剂用于硝基萘催化加氢制备萘胺,产物纯度好、收率高,是目前最佳的工艺条件之一,且催化剂多次套用催化活性不减。

The catalytic kinetics of oxidoreductase can illuminate its catalytic characteristics,substantial properties,and response to environmental changes.

其催化反应的动力学研究常用来阐明其催化过程的特性、酶的本质属性及其对环境变化的响应等。

The acid property of zirconium oxychloride was characterized by means of DTA and FT-IR spectra of pyridine absorbed on the surface.

采用DTA和吸附吡啶的FT-IR表征氯氧化锆的表面酸性,用Hamm ett指示剂测定其酸强度,以催化合成环己酮2,3-丁二醇缩酮为探针反应优化缩酮反应条件,并考察它对其他缩酮反应的催化活性,比较了不同催化剂对缩酮活性的影响。

The experimental results indicated that these metal oxide catalysts had better catalytic activities to the methylene chloride gas at low concentration, and the catalytic activities increased with the increase of temperature,but decreased with the increase of inlet gas concentration. The CrO3/potsherd catalytic activity was better than V2O5/potsherd, and the CrO3/potsherd catalyst displayed higher activity at the relative low temperature. When the reaction temperature was 320 ℃, the conversion rate could reach 99%, and the result of 100h catalyst stability experiment show that the catalytic activities have good stability.

实验结果表明此类金属氧化物催化剂对低浓度CH2Cl2气体有较好的催化活性,催化剂的活性随温度升高而升高,随入口废气浓度增大而降低,其中CrO3/陶瓷片催化剂的催化活性比V2O5/陶瓷片催化剂的活性好,CrO3/陶瓷片催化剂在较低温度下就表现出较高反应活性,在反应温度320℃时,转化率即达到99%,同时催化剂100h稳定性实验结果表明催化剂活性有很好稳定性,为进一步工业化应用提供理论和实践依据。

With the characterization of NMR and IR, combining with the synthesis of active species and studies of their structures, it is suggested that the hydride [RuHCl(PPh3)3], being favorably formed in the acid media, exhibited higher activity in the reduction of the C=C bond, while the hydride [RuH4(PPh3)3], being preponderantly formed in the basic media, showed activity and higher selectivity towards the C=O reduction.

通过核磁、红外等表征手段,并结合可能催化活性配合物的合成和结构研究,推测了在非水介质中对C=C和C=O双键起到活化作用的催化剂活性物种和可能的选择加氢反应机理,即,催化剂[RuCl2(PPh3)3]在酸性环境下倾向于生成[RuHCl(PPh3)3]物种,该Ru-H物种对C=C双键加氢反应表现出较高的活性;而碱性环境下则易于生成[RuH4(PPh3)3]物种,该Ru-H物种对C=O双键加氢具有较高的催化活性。

A key feature of this methodology is the use of metal catalysts for the in situ racemization of enzymatically unreactive enantiomers in the enzymatic resolution of racemic substrates.

酶和金属配合物的结合扩展了这个方法的使用范围,该方法的主要特征是用酶催化拆分和金属催化原位外消旋化未反应的底物,克服了经典动力学拆分最高产率只有50%的缺陷。

The experimental results showed that the product distribution and selectivity of the deasphalted oil from vacuum residuum was better than that from gasoline while the deasphalted oil from FCC slurry oil was worse than gasoline.

研究发现,减压渣油和掺兑催化油浆的减压渣油的丙烷脱沥青油具有较好的产物分布和选择性;而催化油浆的脱沥青油的裂化性能较差。

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Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气,收缩臀部肌肉;拱起身体,尽量抬起头来,右腿伸直朝向天花板(膝微屈,以避免肌肉紧张)。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化,但却比去年同期高8%。

However, to get a true quote, you will need to provide detailed personal and financial information.

然而,要让一个真正的引用,你需要提供详细的个人和财务信息。