催化的

After this research work, we know that: HMCM-22 is a better catalyst of selecting naphthalene alkylation; Surface modification of zeolite Y is effective, but the effect of zeolite 3 is not evident and surface modification doesn"t suits mordenite; Surface modification doesn"t affect the frameworks and inner environments of zeolites, but only reduces diameter of orifice and overlays surface acidities; t-butanol is not suitable for alkylating agent of the reaction using modified zeolites as catalyst; Solvents with smaller molecular size are advantageous for naphthalene alkylation reaction using modified zeolites as catalyst, such as cyclohexane is better than decalin.

通过本论文的研究，我们知道：HMCM-22是萘择形烷基化反应较好的沸石之一；Y沸石的外表面改性效果较好，β沸石则效果不明显，而丝光沸石则不适于外表面改性；外表面改性不改变沸石的骨架结构和孔道内部环境，仅减小孔口直径和覆盖外表面酸性位；叔丁醇不适于作外表面改性沸石催化的反应的烷基化试剂，其反应活性很低，且选择性无明显提升；分子较小的溶剂更适于外表面改性沸石催化的反应，环己烷就明显好于十氢萘。

Subsequently,enol methylation of P in basic condition completed the synthesis of malyngamide O.Applied this route to the synthesis of malyngamides Q and R,the chiral unsaturated acid was connected with the vinyl chloride part by amidation,then the resulting product was converted into the corresponding aldehyde,followed by aldol condensation of the aldehyde with the chlorotitanium enolate of pyrrolidone to complete the skeleton of malyngamides Q and R,then the synthesis of them was completed via enol methylation in acid condition.

该合成路线拓展应用到malyngamides Q和R的合成时，首先用酰胺键将手性不饱和脂肪酸和烯氯片段连接，再转化成相应的醛，与乙酰基吡咯酮进行TiCl_4催化的aldol反应即得到malyngamides Q和R的骨架结构，再经过酸催化的烯醇甲基化反应完成了Q和R的全合成。

The research result also showed that aminoalkylferrocene and new ferric alkyldithiocarbamate were effective initiators of the two kinds of biodegradation of the PE film; and new nickelous alkyldithiocarbamate could effectively control the initial process of its biodegradation; and PE film with them had better environmental degradability.

其中聚 酯、聚酰胺和聚氨酯等聚合物是通过H'或 OH_催化的水解降解引发过程，而聚乙烯、聚丙烯和聚苯乙烯等聚烯烃主要是通过光、热、氧和过渡金属离子催化的光一氧降解引发过程。但它们的最终可被生物吸收的产物都是低分子量的羧酸。

For very long time, many research groups focus on using more than a stoichiometric amount of a chiral auxiliaries to obtain high enantioselectivity. There were mainly two sorts of processes reported on highly catalytic asymmetric addition of Grignard reagents to aldehydes. The former case was to transform Grignard reagent RMgX into other organometal reagents such as R_2Zn and R-Ti derivatives via complicated procedures at extremely low temperature. The later case was to link a chiral ligand to Mg in the form of organomagnesium amides or use chiral amine ligand catalyzing the alkylation of aldehydes.

格氏试剂对醛的不对称加成的报道大多需要大量的手性助剂以获得高的光学活性，而高度催化的格氏试剂对醛的不对称加成主要通过两种途径进行：一种是把格氏试剂转化成其他的有机金属试剂如R_2Zn和R-Ti化合物再对醛进行加成，反应通常在低温下进行；另一种是利用手性镁胺作为中间体或直接用手性胺催化来完成此反应。

A series of α-(fluoro-substituted phenyl)pyridines have been synthesized by means of a palladium-catalyzed cross-coupling reaction between fluoro-substituted phenylboronic acid and 2-bromopyridine or its derivatives. The reactivities of the phenylboronic acids containing di- and tri-fluoro substituents with α-pyridyl bromide were investigated in different catalyst systems.

利用钯催化的SUZUKI偶联反应，以氟取代的苯硼酸与2-溴吡啶为原料合成了系列新的邻吡啶芳香化合物，研究了二及三氟取代的苯硼酸与溴代吡啶在不同催化体系中的反应性质。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应，高度非对映选择性地一步控制了含有季碳的三个相邻立体中心，有效地构建了&2-季碳1，3-二醇&结构单元，首次实现了此类重排—还原过程的催化循环，其中对于两个C1位的差向异构体底物，此反应具有明显的非对映选择性放大特点。

The effect of dose rate on the radiation chemical yield ofhydroxyterephthalate in the radiolysis of aerated terephthalate aqueoussolution has been investigated,and the generation of OH by copper ion catalyzedFenton reaction has been evaluated with the help of TA.

首先研究了剂量率对对苯二甲酸剂量计的影响，然后将对苯二甲酸用于测定铜催化的类Fenton产生的羟自由基的速率，并观察了MT存在对铜催化Fenton反应产生OH自由基的影响。

With high efficiency, high selectivity, security and environmental friendship, the biocatalysis possesses significant advantages over chemical catalysis in organic synthesis, especially in the asymmetric synthesis of the enantiomerically pure compounds and in the resolution of racemates.

生物催化的高效性、选择性、安全性以及环境友好等优点，使其在一些化学合成领域，特别是在对映体纯的手性化合物的合成和消旋体拆分等方面，具有化学催化不可比拟的优势。

In our study, the synthesis of spice and the resolution of racemates menthol,(R, 5-4-hydroxy-3-methyl-2-(2-propenyl)-2-cyclopenten-1-one (R, S-HMPC were achieved in ionic liquids by three lipase that are usually used in biocatalysis. Meanwhile, some problems associated with enzyme catalysis in ionic liquids were also addressed.

本论文以三种常用于生物催化的脂肪酶作催化用酶，在&绿色&反应介质—离子液体中实现了香料的合成和手性对映体的拆分，同时也对酶在离子液体中催化所存在的问题进行了一些探讨。

To meet the initial study of high efficiency photoreactor, we dedicate to the synthesis of TiO_2 film with optical fiber by Liquid Phase Deposition and wish to obtain well-combined, stable films which can deal with both organic and some inorganic contaminations.

鉴于近年来高效催化的光纤反应器的初步研究，本课题主要致力于薄膜与光纤载体结合性的研究，通过液相沉积法制得具有一定的牢固度，稳定性好，能够用于处理气态、液态的有机物及部分无机物的纳米TiO_2光纤薄膜，为设计高效光催化反应器奠定良好的基础。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。