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The experimental results indicate that the catalytic decompose efficiency of anthracene reduced linearly with reaction temperature and the concentration of anthracene increased.

实验结果表明:随着催化反应温度的升高,蒽的催化分解效率呈下降趋势,而且呈大致的线性变化规律;蒽的催化分解率随蒽的浓度呈线性递减规律;蒽在V_2O_(5~-)WO_3/TiO_2催化剂上具有良好的空速特性。

The effects of the composition of catalyst (the structure and amount of bident ligand and strong acid, the cocatalytic activity of Cu〓, the roles of methanol and phenol etc.) and the copolymerization condition (the reaction time, temperature, amount of ST and CO, the structure and amount of solvent etc.) on catalytic activity were studied. The principle of the copolymerization was investigated.

研究了催化体系组成(含氮双齿配体的结构与用量、强酸的结构与用量、铜盐的助催化作用、甲醇和酚类化合物作用等)和共聚反应条件(共聚反应的温度与时间、溶剂种类与用量、苯乙烯与一氧化碳量等)对溶液共聚反应的催化活性的影响,探索溶液聚合反应规律。

After tiny amount of platinum was deposited onto the NPG substrate,not only the structure stability of NPG was greatly improved,but also the Pt-Au bimetallic catalysts displayed the better catalytic activity and the stronger poison resistance towards the electrooxidation of small or...

如在NPG基体再沉积微量的铂,不仅明显改善了NPG的结构稳定性,而且由于Pt、Au两组分之间的协同效应而使该催化剂对有机小分子的电催化氧化具有比纯铂更高的催化活性和更强的抗催化毒物能力。

Results Same conservative sites and key catalytic sites existed among SjLDH and LDHs from other species. Similarity of SjLDH compared to CsLDH, TvLDH and HsLDH was 75%, 17%, 58%-60% respectively. Phylogenetic analysis demonstrated that the evolution relation between SjLDH and DmLDH was closer than the relation between SjLDH and CeLDH, the relationship between SjLDH and HsLDH-B,-C was closer than HsLDH-A. Three trans-membrane regions were found, the region of 98aa-106aa in three hydrophilia regions located outside of membrane was inferred as the major antigen epitope. This antigen epitope had significant difference with LDHs from protozoon ( Pf ., Tg ., Tv .) and had 1-3 amino acid residue difference with MmLDH, HsLDH-A,-B,-C, and was the same with CsLDH. One of the key catalytic residues and substrate binding loop were located in this region. Tertiary structure demonstrated that 98aa-106aa was on the surface of the protein and formed a substrate binding loop, other two key catalytic sites were at the position near the loop.

结果 SjLDH与其他物种的同源序列含相同的保守位点及催化活性位点,与华支睾吸虫LDH同源性最高为75%,与阴道毛滴虫LDH同源性最低为17%,与人LDH(HsLDH-A,-B,-C)的同源性为58%~60%; SjLDH与果蝇的进化距离较秀丽隐杆线虫为近,3种人LDH中与HsLDH-B、-C的进化距离较HsLDH-A为近;该蛋白具有3个跨膜区域,3个高亲水性区域,主要的线性表位98aa~106aa位于膜外,与原虫LDH相同区域差异显著,而与其他LDH有1~3个氨基酸的差异,关键催化位点之一及底物丙酮酸结合区域位于该区域,蛋白质同源模建分析表明该区域位于蛋白表面形成环状结构,3个关键催化位点位于该区域或在其附近。

Reaction trends of catalytic desulfurization of thiophene were determined based on the reaction energy needed, which was obtained with the AM1 calculation results of thiophene and possible carbonium ions on transition state.

采用半经验AM1计算方法,利用静态理论对噻吩在分子筛催化剂上的催化裂化脱硫机理进行了量子化学计算研究,通过对噻吩分子和可能产生的中间正碳离子的量子化学计算,得到各中间反应所需的能量,从而判断噻吩催化裂化脱硫反应的趋势,证实了氢转移反应在催化裂化脱硫中所起的作用。

The results show that the thermal degradation process of polystyrene initiates from chain end scission, and styrene dimer is the residual of degradation of polystyrene; Different catalysts have different catalytic activity on the degradation process of polystyrene, among which barium oxide is the best.

作者利用热重质谱法对聚苯乙烯热降解和催化降解过程进行了研究,得出以下结论,聚苯乙烯的热降解过程主要由链端断链反应引发,苯乙烯二聚体可能是聚苯乙烯降解结束阶段的剩余物;不同催化剂在聚苯乙烯降解过程中具有不同的催化活性,其中氧化钡的催化活性最高。

The flow-field around a hemisphere and a flat-nosed cylinder in the shock tube is simulated numerically by using non-equilibrium Navier-Stokes equations with an air chemical model of 5 species 17 reactions, and the catalytic rate constant of surface materials such as Pt, SIC:, Ni and a flight vehicle materials is determined by using the heat transfer rate of testing in the shock tube and the distribution of heat transfer rate along with the catalytic rate constants.

用5组分17个化学反应Durm-Kang空气化学模型和轴对称热化学非平衡Navier-Stokes方程,对激波管中球头和平头圆柱模型绕流流场进行了数值模拟,给出了驻点热流随催化速率常数变化的分布,并根据激波管实验测量的热流值确定了表面材料Pt、SiO2、Ni和某种飞船材料的催化速率常数,建立了数值分析高焓流动边界层催化特性的软件。

NiRs are divided into two different types based on their prosthetic groups, namely heme-containing nitrite reductases (cd1-NiRs) and Copper-containing nitrite reductases.

Cu-NiRs呈三聚体结构,每个单体都含有两种类型的铜原子,它们在酶催化过程中起着传递电子的重要作用。在催化过程中,Cu-NiRs中部分残基的结构变化有利于催化反应的进行。

Different from many other researches the Henkel-Esterification process was studied here which starts from 1,8-naphthalenedicarboanhydride. In the Henkel reaction of 1,8-naphthalenedicarboanhydride to 2,6-naphthalenedicarboxylic acid (abbreviated as 2,6-NDA) non-cadmium catalytic system was used. In atmosphere of carbon dioxide 1,8-naphthalenedicarboanhydride can be effectively converted to 2,6-NDA in the temperature range of 300~340℃ with zinc carbonate as catalyst and the yield of 2,6-NDA can reach more over 62%.

和国内外绝大多数研究不同的是,论文结合公司自身的原料资源优势和长远规划,提出了从工业苊深加工产品—1,8-萘二甲酸酐出发,经过非镉系催化剂催化转位,然后再进行非酸催化酯化合成2,6-萘二甲酸二甲酯的工艺路线,并对工艺过程中涉及的成盐过程、催化转位反应、酯化反应等进行工艺参数的重点考察,对合成产物进行分析确证。

Additionally, morphological structure and properties of the TiO_2 prepared by using the conventional heating and microwave dielectric heating were also compared detailedly. Acetaldehyde was chosen as a model reactant to valuate the performance of the samples.

通过自行设计的微波-光催化反应器,在功率100~170 mW、频率36 GHz 的微波和紫外光同时存在下研究了TiO_2对乙醛的光催化氧化性能,并与单纯紫外光存在下的光催化过程进行了比较。

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