催化的

The isomerization reaction of propylene oxide to produce allyl alcohol catalyzed by basic lithium phosphate was studied.

研究了环氧丙烷在碱性磷酸锂催化作用下异构化生成烯丙醇反应过程，考察催化剂的制备条件，异构化温度对催化性能的影响，以及催化反应机理和动力学特性。

It is demonstrated that the chiral quaternary ammonium salts catalysts exhibit promising catalytic properties for the substrate. Part III: The synthesis and the characterizing of the macroporous aminomethyl resin-supported cinchona alkaloid complexes and the study on its catalytic properties The part consists of two subsections. the macroporous aminomethyl resin -supported cinchona alkaloid complexes were synthesized by the stuff (cinchonine, quinine and macroporous aminomethyl resin). Their structures were characterized by means of elemental analysis, XPS, TG/DTA; the chiral polymer-supported complexes were first used as catalysts for the reduction of ketones. Their catalytic properties for the reduction processes were investigated. The comparison of the products e.e., the conversion of the substrate among different reduction processes was employed with determined by HPLC. The effects of the time, the temperature, the ratio of catalyst to substrate, reaction solvent as well as the recycle times were also discussed.

第三章聚-4-氨甲基苯乙烯负载金鸡纳碱金属络合物的合成与表征及其不对称催化性能研究本章分为两节，以辛可宁和奎宁及聚-4-氨甲基苯乙烯为原料，合成了4种聚-4-氨甲基苯乙烯负载金鸡纳碱络合物催化剂，并对它们的结构用元素分析、X-射线光电子能谱、TG/DTA等几种测试手段进行了表征；首次将所合成的手性高分子负载的金属络合物用于催化芳香酮不对称还原反应，详细研究了所得的手性高分子负载的金属络合物对不同底物的催化性能，用HPLC等分析手段定量检测了还原过程的底物转化率及其产物对映异构体选择性，并考察了反应时间、反应温度、催化剂和底物投料比、反应溶剂和循环次数对催化性能的影响。

We study the relation between the BET and the efficiency. Then, the reasons of the deactivation are introduced.

文章首先研究了我国催化转化器的构成以及作用机理，分析了催化器比表面积对催化性能的影响。

To meet the need of developing the simulator of the whole flow sheet of the mathematical Plant, mathematical model and simulation software of the plant is developed.

本论文根据催化压缩机仿真的需要，建立了催化装置压缩机数学模型，开发出催化压缩机的仿真软件。

The transition metal carbides were a new class of catalysts which had good catalytic activity and selectivity and were widely used in hydrogenolysis,dehydrogenation,desulfidation,denitrification,reforming,and other hydrocarbon conversion reactions.

过渡金属碳化物作为一种催化新材料得到了人们广泛的关注，在催化加氢、脱氢、脱硫、脱氮和重整等方面，表现出优良的催化活性和选择性。

For efficient utilization of phosphorus—rich rhodochrosite and complicated sulfides, we have carried out some studies on enrichment of manganese, dephosphorization and bio-catalytical oxidation of sulfides supported by NSFC (No. 59374150, 59774010), the main contents include: properties of Huayuan Manganese ore; microorganisms preparation of dealing with manganese ore; physiological and biochemical properties of microbes used; the mechanism of microbes function to manganese ore; the separation, tameness of Thiobacillus ferrooxidans and its nutriment; bio—catalytical oxidation mechanism of sulfides; extraction of gold by bio—catalytical oxidation—cyanidation.

为解决我国储量丰富的高磷贫碳酸锰矿石和复杂硫化矿有效利用中存在的问题，我们在国家自然科学基金委员会的资助下（No.59374150，No.59774010），以花垣锰矿石和黄铜矿、黄铁矿等为研究对象，进行了高磷贫碳酸锰矿石的微生物富锰降磷和生物催化氧化硫化矿等的研讨工作，内容包括：花垣锰矿石的性质研究；富锰降磷微生物的筛选；试验用微生物的生理生化特性及富锰降磷机理探讨；催化氧化硫化矿细菌的分离、驯化及营养条件确定；生物催化氧化硫化矿的机制；金的生物催化氧化—氰化提取。

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中，2-甲基吡啶配位的钌卡宾配合物62的催化活性最高，在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1)；催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

Moreover, high TONs (turnover numbers, TONs up to 1 000 000 for the reaction of iodobenzene with phenylboronic acid) for the palladium-catalyzed Suzuki-Miyaura cross-couplings were observed

同时，这种催化体系还可以达到很高的催化效率(碘苯和苯硼酸的催化效率甚至可以达到1000000)。

The catalysing technology is preferentially considered as a research field in this century .

催化过程，包括各种形式的化学催化和生物催化，是实现高原子经济反应的重要途径。

The method solves the problems better through adopting the following technical proposal that: the method takes the solid super acid consisting of the VIB group elements or the VIB group elements and the IVB group elements in the periodic table of elements and loaded on a symbiosis molecular sieve as catalyst, and naphtha with the component being C4-C10 as a raw material so as to carry out catalytic cracking reaction at a temperature of between 550 and 700 DEG C, under a pressure of between 0.01 and 0.5 MPa, at a reaction weight space velocity of between 0.1 and 4 hours and with the weight ratio between water and naphtha of between 0.5:1 and 4:1, thereby generating ethylene and propylene.

本发明涉及一种催化裂解制乙烯丙烯的方法，主要解决现有催化裂解制乙烯丙烯催化剂的使用温度高，活性低，乙烯丙烯选择性差的问题，本发明通过使用在共生分子筛上负载由元素周期表VIB族元素或VIB族元素和IVB族元素组成的固体超强酸作为催化剂，以组份为C 4 ～C 10 的石脑油为原料，在反应温度为550～700℃，反应压力为0.01～0.5MPa，反应重量空速为0.1～4小时-1 ，水/石脑油重量比为0.5～4∶1的条件下，进行催化裂解反应生成乙烯丙烯的技术方案，较好地解决了该问题，可用于催化裂解制乙烯丙烯的工业生产中。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！