催化的

2D transient model for rapid laser remelt;2. A two-dimensional symmetrical transient model applicable to cold-start emission applications was integrated, which was solved by the finite volume method.

描述了三效催化器的流动、传热传质和异相催化过程，分析了催化器的径向热导率的修正方法，比较了尾气分别作为双组分和多组分混合物时对其组分扩散系数的影响，集成了可用于模拟三效催化器的冷起动性能和暖机性能的二维轴对称瞬态模型，模型采用有限容积法求解。

The kinetic behaviors of ethylene homo- olymerization and ethylene / l-hexene co-polymerization , catalyzed by the metallocene catalyst PS-DVB-MC in an 0.5 L stainless steel reactor , were studied. The effects of polymerization conditions on ethylene polymerization , such as concentration of catalyst , temperature of polymerization , pressure of ethylene , molar ratio of AI / Z r , etc ., were also investigated . Some leading results were as follows : the activity of the catalyst PS–DVB- MC for ethylene homo-polymerization was high ( 1.053 x 107 gPE / mol Zr·h ), but the molar ratio of AI / Zr was low ( 350:1 ); the catalytic ability for ethyleneα-olefin ( such as l hexene etc .) co-olymerization was great , and the corresponding activity come up to a maximum of 1.753 x 107 gPE / mol Zr·h while concenlration of l-hexene was 0.080 mol / L ; the molecular weight of polyethylene was about 180,000 , meanwhile the molecular weight distribution was narrow ( 2.19 ); the bulk density of polyethylene and ethylene / l-hexene co -polymer were 0.25 and 0.34 respectively .

采用0.5L高压不锈钢反应釜，对催化剂PS–DVB-MC催化乙烯均聚和乙烯/ l-己烯共聚合的动力学行为进行了研究，详细考察了催化剂浓度、反应温度、压力、Al/ Zr比、1-己烯浓度等因素对乙烯聚合反应的影响，得到如下主要结论：催化剂PS-DVB-MC具有催化乙烯均聚的高活性(1.053×107g PE / mo1 zr.hr)，低Al / Zr比( 350：1 )；具有良好的催化乙烯与α-烯烃(如1-己烯等)共聚的能力，在1-己烯浓度为0.080 mol / L时，催化活性达到最大(1.783×107 g PE / molZr.hr)；乙烯均聚产物的分子量在18万左右，分子量分布窄( 2.19 )。

The results show that the optimal parameters of esterification are as follows: 4% of SO42-/ZrO2, molar ratio of methanol to litsea cubeba kernel oil 101, 68 ℃ of reaction temperature and 4 h of reaction time, the acid value decreases to 2.52 mg/g. Compared with the traditional acidic-catalyzed method, this method has the advantages of no acid proof equipment, easy to recycle catalyst and no acidic waste water emission. The optimal parameters of transesterification are as follows: 25 ℃ of reaction temperature, 0.5% of hexadecyl-trimethyl-ammonium bromide, 1% of NaOH, molar ratio of methanol to the oil 61 and 15 min of reaction time. The ester exchanging rate is 97.6%. This method adopts phase transfer catalyst and produces industry prospect, which has many advantages such as energy-saving and time-saving under room temperature.

研究结果表明，固体酸SO42-/ZrO2催化酯化反应的最佳条件为：油重4%的SO42-/ZrO2，醇油摩尔比为101，温度为68 ℃，反应时间为4 h，原油酸值降到2.52 mg/g；该法相对浓硫酸催化酯化法具有不需耐酸设备、催化剂易回收、无废水排放等优点；相转移催化酯交换反应的最佳条件为：温度为 25 ℃，0.5%的十六烷基三甲基溴化铵，油重1%的NaOH，醇油摩尔比为61，反应15 min，原油酯交换率达到97.6%；采用相转移催化技术，反应在常温下进行，大大减少了能耗，缩短了反应时间，具有的产业化前景。

The influences of composition and structure of catalysts and cracking conditions on catalytic activity are also discussed. Further key study areas in catalytic cracking of tars are presented.

分析了不同催化剂的优缺点及催化机理，讨论了催化剂的组成、结构以及催化裂解条件对催化效果的影响，展望了未来焦油催化裂解的研究重点。

The catalytic activity of the mono- and bi-nuclear complexes, and unsymetric complex 〓〓 MeNTB =tris ( N-methylbenzimidazol-2-ylmethyl amine and tetranuclear complex 〓L = N, N, N', N'-tetrakis (N-methylbenzimidazol-2-ylmethyl-1,4-diaminobutane for oxidation of hexane was examined. Thedi-iron complexes with one exchangeable monodentate ligand and unsym-metric(μ-carboxylato) diiron complex exhibit high catalytic ac-tivity, while mononuclear Fe complex are inactive.

这些单核、双核化合物、不对称化合物〓-三氨和四核化合物〓四-1，4-丁二胺催化氧化环己烷的催化活性被测试，结果表明含有可交换配体氧桥联双核Fe化合物和不对称双核Fe化合物表现很高的催化活性，而单核的Fe化合物是非催化活性的。

Some products such as: diisobutyl phthalate, cyclohexylmethyl tridecyl oxalate and 2-isopropylcyclohexanol that have not been reported in the directly oxidation of alkane by traditional method have been obtained, and all the products are used in fuel, leather, textiles, cosmetics and so on.(3) Metal-promoted superacids SO_4~(2-)/SnO_2-M_XO_Y (M= Ce, Co, V, Mo, Ti), which were highly active for this reactions, were investigated in order to improve its acid sites activity, selectivity and stability.

这一在常温常压下以锡系超强酸为催化剂催化氧化碳氢化合(来源：ABCca8cca论文网www.abclunwen.com)物的反应还未见报道：(3)金属改性锡系固体超强酸SO_4~(2-)／SnO_2-M_XO_Y(M=Ce，Co，V，Mo，Ti)在催化氧化反应中表现出很好的催化活性，通过研究表明金属改性剂的加入提高了催化剂酸性，选择性和稳定性；(4)具有光催化活性金属Ti的引入极大的提高了催化剂SO_4~(2-)／SnO_2的比表面积。

Catalytic techniques for deep desulfurization, denitrogenation and dearomatization in production of clean gasoline and diesel fuels were reviewed, especially those for producing low-sulfur and extra-low-sulfur gasoline and diesel oil, among which technologies arousing most attention are sulfur-reducing FCC catalyst and additives, selective hydrogenation catalysts and technology, adsorptive desul-f urization of gasoline and diesel oil, biologically catalytic desulf urization of diesel oil, and selective oxid...

为面对新世纪清洁燃料生产的新机遇和新挑战，各种生产清洁燃料的催化技术正在竞相开发之中，尤其是生产低硫、超低硫汽油与柴油技术。其中，催化裂化降硫催化剂和助剂、选择性加氢处理新催化剂及工艺、汽柴油吸附脱硫、柴油生物催化脱硫和选择性氧化脱硫等新技术尤其引人注目。我国应加快清洁燃料生产催化新技术的开发研究，为生产更清洁的汽油和柴油燃料提供技术储备。

The results indicated that the effect that light catalysis oxidation treated leach was related to the kinds of catalyst, and the result of treatment using autanse-TiO2 is better than rutile. Catalysis capability is improved obviously after autanse-TiO2 was calcined at 600℃, and the way of calcine had large actions for catalysis.Photo-catalytic degradation of organic compound in leaches was carried out with TiO2,-Fe2O3 and ZnO,the following conclusion can be attained.

研究结果表明半导体光催化剂TiO2对垃圾渗滤液的光催化效果和TiO2的晶型有很大的相关性，锐钛型TiO2的光催化效果明显优于金红石型TiO2；高温处理锐钛型TiO2改变其晶型和表面结构，600℃煅烧TiO2的光催化活性有较大提高；光催化剂的活化方式亦影响光催化效果。

The technological condition of preparation of mesh TiO〓/Ti catalyst was optimized by means of XRD and SEM with the analysis of effects of dyes photoelectrocatalytic degradation. The diameter of TiO〓/Ti catalyst particle was nanometer level The effects of bias voltage and light intensity on the process of photoelectrocatalytic oxidation, the adsorption property of electrode surface, the extent of mineralization of rhodamine B and rose bengal were investigated using mesh TiO〓/Ti as catalyst of photoelectrocatalytic oxidation system.

利用拉曼光谱和XRD等测定手段并结合染料的光电催化降解效果的分析，优化了丝网TiO〓／Ti催化剂制备的工艺条件，研制出高效丝网纳米级TiO〓／Ti催化剂，并将该催化剂用于光电催化氧化体系，研究了氧化体系中外加偏压、光强等因素对光电催化氧化过程的影响以及催化剂的表面吸附性能、染料若丹明B和虎红在光电催化氧化过程中的矿化程度。

The computational results indicate that surface catalytic combustion restrains gas phase combustion. Inlet velocity and tube diameters have important influence on catalytic combustion of hydrogen. For smaller inlet velocities,reaction is dominated by gas phase combustion. As the inlet velocity increases,there exist both surface catalytic combustion and gas phase combustion. For bigger inlet velocities,reaction is dominated by surface catalytic combustion. The temperature of flame core decreases with the decrease of tube diameter.

计算结果表明，表面催化反应对空间气相反应有抑制作用；入口速度和管径对氢气的催化燃烧过程有重要的影响，在入口速度较小时，燃烧主要是空间气相化学反应，随着入口速度的增大，燃烧过程同时存在着表面催化反应和空间气相反应两种控制因素，在入口速度较大时，燃烧主要是表面催化燃烧过程；随着管径的减小，微型管道内反应的最高温度降低。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！