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The catalytic effect of different modified molecular si eves were studied for synthesis amyl acetate, the results indicate that SO 2- 4 /FeZSM have go od catalysis activity to esterification .The effect of the ratio of reactants, the amoun t of the catalyst and the reaction time were also investigated.

考察不同改性分子筛催化合成乙酸戊酯的催化活性,结果表明:改性SO2 - 4/FeZSM对合成酯的催化作用较好,并讨论了以该催化剂催化酯化时原料配比、催化剂用量、反应时间等因素与酯化反应的关系。

The 20S catalytic core of the 26S proteasome has the shape of a barrel made of four rings which are composed of seven differentαsubunitsα_1-α_7 at two outer rings and seven differentβsubunitsβ_1-β_7 at two inner rings at which the catalytic sites locate. Three of theβsubunits contain proteolyses sites, which are sequestered in the hollow interior of the 20S particle. Substrates enter the 20S through a narrow channel formed by theβsubunits, whose N-termini, depending on their conformation, can either obstruct or allow substrate entry and thus function as a gate. This entry channel is narrow and only permits passage of unfolded, linearized polypeptides.

哺乳动物26S蛋白酶体是由一个20S催化颗粒(catalytic particle,CP)和两个19S调节颗粒(regulatory particle,RP)组成的ATP(adenosine-triphosphate,ATP)依赖性蛋白水解酶复合体。20S CP是26S蛋白酶体的催化核心,它是由4个圆环堆叠形成的桶状复合物,其中两侧外环每个环是由α_1-α_7亚基组成,两个内环每个环是由β_1-β_7亚基组成,4个环的中央形成一个狭窄的内腔。2个β内环形成了20S CP的催化中心空腔,其内壁为催化活性位点所在地;外侧α环中心的孔道是底物到达催化中心空腔的通道,一般被α亚基上的N末端所封闭,阻止胞内非目的靶蛋白进入20S CP内被降解破坏。

After nearly two years intensively preparing work, the scientific agreement of "Laboratoire Franco-Chinois de Catalyse" had been signed finally at GIF, Paris, on March 20,2000, by president of CAS Lu Yongxiang and Director of CNRS Catherine Brechignac.At the same time, the "Statuts du Laboratoire Franco Chinois de Catalyse" has been signed by Prof. Can Li, the Director the State Key Laboratory of Catalysis of DICP and Prof. Bernard Bigot, the Director of Institut de Recherche sur la Catalyse, France.

经过近两年的筹备,2000年3月20日,中科院院长路甬祥与法国科研中心布希尼亚克总主任,在法国GIF城堡签署了建立中法催化联合实验室的科技合作协议,同时我所催化基础国家重点实验室主任李灿研究员与法国里昂催化研究所所长比葛教授也签署了中法催化联合实验室的章程协议。

Because of specificity and high efficiency, the catalytic efficiency of cellulase is high(more 103~1013 times than general catalysts), the condition of catalytic reaction is mild and the catalytic activation can be adjusted and controlled, which can improve remarkably semblance and handle of fabrics during finishing fabrics by biological catalyzing, moreover cellulase can replace some chemical materials such as acid, cocain, chlorine and phosphorus etc, so as to decrease pollution, make no waste-water and protect environment.

由于酶具有专一性和高效性,采用生物催化,其催化效率高比一般催化剂高10~3~10~(13倍,催化反应条件温和,催化活性可调节控制,应用在纺织品处理上,能显著改善织物的外观和手感,并能取代一部分酸、碱、氯、磷化合物等化工原料,从而减少污染,不产生污水,有利于环保和生态。而且酶本身又无毒,容易生物降解,不会引起环境污染,所以酶处理已被公认为是一种符合环保要求的绿色印染加工方法。本文选用了市场上常用的纤维素酶R-10和纤维素酶ECS2610两种生物酶。

Selective doping has been proved to be a semiconductor oxide improve the photocatalytic activity of the most effective ways The introduction of certain metal ions can greatly improve the photocatalytic oxidation efficiency, Recently, a lot on the adoption of the doping to improve the photocatalytic oxidation performance reports, doped semiconductor photocatalysis material because of its physical and optical properties change, thereby improving the photocatalytic properties.

有选择性的进行掺杂已被证明是一种提高半导体氧化物光催化活性的极其有效的方法,掺入一定的金属阳离子能极大的提高TiO2的光催化效率,最近有大量的关于通过掺杂来提高TiO2的光催化性能的报道,掺杂的半导体光催化材料由于其物理和光学性质的改变,通过扩展光响应范围和提高光生电荷的分,从而提高了光催化性能。

The catalyst, palladium supported with chitosan condensated with salicylaldehyde, was studied in hydrogenation ofα-octene, nitrobenzene, 4-nitrophenol and m-dinitrobenzene, it was active and good selectivity forα-octene and nitrobenzene, when the activation time is 90 min, the catalyst showed the best hydrogenation active.

壳聚糖缩水杨醛负载不同比例PdCl_2的催化剂对α-辛烯、硝基苯、4-硝基酚和间二硝基苯的催化性能进行了研究,结果表明该催化剂活化90 min时加氢催化活性最好,对α-辛烯,硝基苯的催化选择性在催化5 h时达到了100%。

The molecular weight and molecular weight distribution of polyethylene were determined by GPC and Viscometry.

对GPC曲线的高斯函数拟合分峰,计算在双组分茂金属催化体系中每种催化剂得到的聚乙烯的重量之比;根据各催化剂的催化活性和按所加的催化剂的摩尔比例假定进行独立反应时,可以计算在双组分催化体系中每种催化剂得到的聚乙烯的重量之比;根据两种重量之比的比较结果和对双组分茂金属催化体系得到的聚乙烯的平均分子量和平均分子量分布的分析结果,可以推测在催化体系CatZr〓/CatZr〓中两种催化剂基本上不存在相互作用;而在CatZr〓/CatZr〓体系中两种催化剂之间可能有相互作用存在。

In this paper,we compared the photodegradation efficiency of nano-titania films by using dichloroacetic acid,rhodamine B and methyl orange as the photocatalytic referents and the ultraviolet lamp as the source light to generate the photocatalytic reaction.

针对纳米氧化钛光催化性能研究中缺乏统一有效表征标准的现状,比较了二氯乙酸、罗丹明B和甲基橙三种光催化活性评价物的热稳定性和对紫外光的稳定性,并以氧化钛纳米薄膜为光催化剂,研究了三种评价物的光催化降解效率表征,以及酸碱度、通氧条件等因素对评价物在光催化活性表征中的影响及其机理,归纳了三种评价物对于纳米氧化钛光催化活性表征的优缺点。

In the absence of organic solvent and phase-transfer catalyst, the catalytic oxidation of cyclohexene to adipic acid with aqueous 30% hydrogen peroxide by weight can be efficiently catalyzed by tungstenic acid/inorganic acidic ligand.

以钨酸/无机酸性配体为催化体系,在无有机溶剂和相转移剂的情况下,催化过氧化氢(质量分数30%)氧化环己烯合成己二酸。结果表明,以钨酸/磷酸催化氧化环己烯的催化效果最优。

Methods:Vanadium was determined by dual-wavelength catalytic spectrophotometric method which was based on the vanadium catalyzing oxidation of acridine orange and acid chrome blue K by potassium bromate in 0.010 mol/L H2SO4 medium.

在硫酸介质中,利用钒催化溴酸钾氧化吖啶橙和酸性铬蓝K褪色反应,分别在476 nm和556 nm处测量催化体系和非催化体系的吸光度的变化,用双波长催化光度法测定痕量钒。

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