催化剂

Here we applied many types of cinchona alkaloid derivatives and otherβ-aminoalchohol compounds in IFB reactions and investigated the effects of solvent, temperature and catalyst amount on the enantioselectivities in order to find the proper catalyst and optimize reaction condition.

本文考察了多种金鸡纳生物碱衍生物及其它一些β-氨基醇类化合物在IFB反应中的应用，并研究了催化剂的结构、溶剂效应、温度、催化剂用量及反应底物类型对立体选择性的影响，以筛选适合的催化剂和优化反应条件。

Reductive conversion of geraniol to citronellol is adopted as a model reaction, and several factors in the reaction are discussed using gas chromatography method. The influence of n-hexane and butyl acetate, as organic solvents, on biocompatibility was studied; the influence of methanol, ethanol, glycol, n-butanol and 1-hexanol, as energy substance, on the transformation efficiency was compared, respectively; the catalysis capabilities of Baker's yeast, XST-KO yeast, LP yeast, alcohol yeast, dry yeast, Saccharomyces cerevisiae, Angel yeast and Meishan yeast were discussed. It has been proved that biocompatibility of n-hexane are much better than that of butyl acetate, and the hexane has been demonstrated the most effective in terms of the influence on biotransformation, Baker's yeast has shown the highest tranformation efficiency among the eight yeast strains.

以香叶醇转化为香茅醇作为模型反应，通过气相色谱法进行定性和定量分析研究了影响该有机相生物转化反应的几个基本因素，考察了两种有机溶剂正己烷和乙酸丁酯对生物相容性的影响，选用甲醇、乙醇、乙二醇、正丁醇和l-己醇分别作为能量物质进行实验，比较其对转化的影响并探讨了Baker's酵母、XST-KO酵母、LP酵母、酒精酵母、假丝酵母、干酵母、安琪酵母和梅山酵母八种不同酵母作为生物催化剂对模型反应的催化能力，结果表明，正己烷作为有机溶剂，其生物相容性明显好于乙酸丁酯，更加有利于该生物转化反应进行；乙二醇作为能量物质，该模型反应转化率最高；而 Baker's酵母作为生物催化剂，对该模型反应的催化能力最强，最适合作为该模型反应的催化剂。

4The obtained solid alkali catalyst was applied to biodiesel preparation with colza oil and used oil as materials respectively and the technics was optimized by sigle-factor and orthogoral experiments with esterification rate as the index. The optimal technique conditions using colza oil were: the amount of solid catalyst 12%, the mol ratio of methanol to oil 9:1, reaction temperature 65℃, reaction time 3h, under which the esterification rate reached to 94.48%.

4以菜籽油和煎炸废油为原料，利用固体碱催化剂催化制备生物柴油，以转化率为考察指标，采用单因素和正交试验对工艺进行优化，得到以菜籽油为原料时制备的最佳工艺参数为固体催化剂投入量2.5％，醇油摩尔比9∶1，反应温度65℃，反应时间3h，转化率达到93.9％；以煎炸废油为原料时最佳工艺参数为反应温度65℃，反应时间3h，固体催化剂投入量4％，醇油摩尔比6∶1，转化率达到91.2％。

The byproducts using a HZSM-5 supported multi-metal catalyst are polymer of MXDA condensation detected by MS, which is different from the byproducts using the carbon supported metal catalyst.

反应副产物用MS定性分析表明：分子筛负载的多金属加氢催化剂与活性炭负载的多金属催化剂不同。分子筛负载的多金属加氢催化剂产生的副反应主要为MXDA的分子间脱氨缩合反应。

A process for preparing cycloolefin features that in the presence of catalyst slurry containing metal Ru catalyst, water and metallic sulfate, the mononuclear aromatics is partially hydrogenated by hydrogen, and includes a step to control the activity of catalyst.

一种生产环烯烃的方法，该方法是在含有金属钌催化剂、水和金属硫酸盐的催化剂浆液存在下用氢部分加氢单环芳烃进行该方法，其中包括控制催化剂活性的步骤。

The results of the hydrogenation indicate that there are the dispersion capacities of metals on the surface of carrier.

表现在Ni为主催化剂，Co的引入提高了催化剂的选择性，Cu的引入提高了催化剂的活性。

It was discovered that when ethyl nitrite was introduced to the surface of catalyst, Pd ethoxyl compound was formed and simultaneously the active site Pd was transferred to the surface of catalysts with the change from Pd〓 to Pd〓. Then lined-adsorbed CO inserted into Pd alkoxyl compound to form the carboethoxypalladium complex.

研究结果表明，在CO偶联反应过程中，亚硝酸乙酯在催化剂上吸附，生成钯乙氧基络合物，同时将催化剂表面上的活性中心氧化，由Pd〓→Pd〓，并向催化剂表面上迁移。

The catalysts for the combustion of ethyl acetat ewer eprepared using Fe,Co,Cu,Cr,and Mn metal oxides as active components supported on Al2O3-Ce0.5Zr0.5O2 mixed oxides and characterized by X-ray diffraction,temperature programmed reduction,oxygen storage capacity measurement,BET surface area,XPS measurement,and activity test.

制备了Fe，Co，Cu，Cr和Mn金属氧化物催化剂，所用载体为Al2O3-Ce0.5Zr0.5O2复合氧化物。利用X射线衍射，程序升温还原，储氧量测试，BET比表面测试和光电子能谱表征了催化剂。并利用活性测试表征了各种催化剂对乙酸乙酯催化燃烧能力。

The influence of CO2 on the reaction is less significant than that of other traditional ferrochrome shift catalysts, which, very possibly, results from the diffusion or the behavior of Cu in this catalyst.

从动力学方程可以得出该高温变换催化剂内扩散影响严重；该催化剂上CO2组分对反应速率的影响与其它铁系变换催化剂相比变小。

The effects of fluorination ratio、 specific surface area and pore volume of the catalysts on their activities were demonstrated.

研究了催化剂前驱体的热行为，催化剂的晶相以及催化剂的氟化度，比表面积，孔容对催化活性的影响。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。