催化剂

Influence of active components in the catalyst and acetonitrile hydrogenation condition on behaviors of the catalyst and stability of the catalyst were investigated.

研究了催化剂活性组分和乙腈催化加氢工艺条件对催化剂性能的影响，并考察了该催化剂的稳定性。

The homogeneous hydrogen transfer of acrolein to allyl alcohol was carried out with aluminium isopropoxide as catalyst.

采用异丙醇铝为催化剂，丙烯醛与异丙醇进行均相氢转移反应合成烯丙醇，对催化剂的再利用及催化剂的失活原因进行了研究。

The catalyst includes: supported Ziegler-Natta catalyst of titanium halide compound and organic electron donor compound supported with MgCl2 alcoholate carrier; aluminoxane prepared with trialkyl aluminum and water; and one kind of organic electron donor, such as organosilicon compound R2Si(OCH3)2, where R is phenyl, isopropyl, isobutyl or cyclopentyl.

该催化剂包括，a一种负载型的Ziegler-Natta催化剂，即将卤钛化合物和有机给电子体化合物负载在氯化镁醇合物载体上得到的固体催化剂，b一种通过三烷基铝与水反应而制备得到的铝氧烷和c一种有机电子给体，如有机硅化合物R 2 Si(OCH 3 ) 2 ，其中R为苯基、异丙基、异丁基或环戊基。

The catalysts used in the preparation of di acetone alcohol by the Aldol condensation were studied in detail, and a new kind of catalyst Ca 2/Al 2O 3 is developed.

对丙酮经Aldol缩合制二丙酮醇的催化剂进行了研究，研制出新型催化剂Ca 2 /Al2 O3，这种催化剂对丙酮的缩合反应具有较理想的活性及选择性。

The effect of alkaline metal, alkaline-earth metal or rare-earth metal oxides doping to Pd/γ-Al〓O〓 on the properties of supported palladium catalysts were investigated.

研究含氧条件下单Pd催化剂上进行丙烯选择催化还原NO的反应，考察浸渍法制备的Pd/γ-Al〓O〓催化剂中加入碱或稀土金属氧化物助剂对NO转化率的影响，并对催化剂进行了XRD表征及在氧化气氛中饱和吸附NO后的TPD研究。

The degree of hydrogenation of methyl benzoate might be controled by adding the promoters and changing the nano-size of ZnO. For hydrogenation of methyl benzoate to benzaldehyde, the active-structure of a catalyst should be modified to decrease the absorption of benzaldehyde on the surface of it, because benzaldehyde absorbed is hydrogenated easily. Using 30-40％ZnO/γ-Al〓O〓 or Li-30％ZnO/γ-Al〓O〓, a higher selectivity to benzaldehyde is obtained. Hydrogenolysis of methyl benzoate to toluene or benzene is carried out effectively using a catalyst modified. For instance, 45.3％ selectivity to benzene and 100％ conversion of methyl benzoate at 420℃ was obtained over 10％ZnO/MCM-41 with the nano-size particles of ZnO (2.4nm).

也可以通过助催化剂的添加和活性组分的纳米化，并根据苯甲酸甲酯多步加氢反应的特点实行加氢深度的调控：苯甲酸甲酯选择性加氢制苯甲醛中，由于苯甲醛容易进一步加氢，需要对活性结构进行调变，以减弱苯甲醛的吸附，使用30-40％ZnO/γ-Al〓O〓催化剂或Li调变的Li-30％ZnO/γ-Al〓O〓催化剂，可获得较高的苯甲酸甲酯加氢制苯甲醛的活性；采用同样的方式，苯甲酸甲酯选择性氢解为甲苯或苯也获得了较好的结果，如使用ZnO纳米化的10％ZnO/MCM-41催化剂，在420℃，可获得45.3％的苯选择性，苯甲酸甲酯完全转化。

Performance of different noble metal catalysts and catalyst supports were studied.

比较了不同贵金属催化剂及催化剂载体对加氢反应的影响，结果表明Pd／C催化剂对CFC-12的转化率和HFC-32的选择性都要优于其它的催化剂。

The test results for the commercially scaled-up catalyst showed that its preparation technique was well-proven with good repeatability; catalytic properties of the catalyst attained those of laboratory-prepared catalyst.

FC-28型单段高中油型加氢裂化催化剂工业放大结果表明，该催化剂制备工艺成熟可靠，重复性好，FC-28型放大催化剂的反应性能完全达到了实验室定型催化剂的水平。

The results indicated that a dependable kinetic model could be obtained by modifying the Temkin equation by considering the H2 and NH3 adsorption factors. Activation energy for the ammonia synthesis reaction was obtained as 90.2 kJmol^(-1) after linear fitting the kinetic and thermodynamic parameters k, K(subscript H2) and K(subscript NH3) with the Arrhenius and Van't Hoff equation, which was much lower than that over iron-based catalyst, which indicated that the activation energy barrier of N2 dissociative adsorption on Ru was far lower than that on either the conventional magnetite-based catalyst or wustite-based catalyst; the hydrogen adsorption heat was 76.2 kJ mol^(-1), indicating that the adsorption of hydrogen on the Ba-Ru-K/AC catalyst was so strong that it inhibitied the dissociative adsorption of nitrogen.

结果表明，在Temkin方程中加入H2和NH3的吸附项能够获得可靠的动力学模型，用Arrhenius和Van't Hoff方程对动力学和热力学参数k、K(下标 H2)和K(下标 NH3)进行线性拟合，得到氨合成反应的活化能为90.2 kJmol^(-1)，远低于铁基催化剂，说明Ru上N2的解离吸附活化能垒远低于传统磁铁矿基催化剂和维氏体基催化剂。H2的吸附热为76.2 kJmol^(-1)，证明Ba-Ru-K/AC催化剂上H2的吸附较强烈，对N2的吸附有强烈的抑制作用。

Points of knowledge: To know the definition, performance, category and preparation of solid catalyst; characteristic of solid catalyst, basic course of gas-solid catalytic reaction, physical construction of catalyst; to understand the derivation of intrinsic kinetics of gas-solid catalytic reaction by using the Langmuir 's adsorption isothermal line.

知识要点：了解并掌握固体催化剂的定义、性能要求、种类和催化剂的制法；固体催化剂的特性，气-固相催化反应进行的基本过程，催化剂的物理结构；掌握朗哥缪尔吸附等温线推导气固相催化反应本征动力学的方法。

The absorption and distribution of chromium were studied in ryeusing nutrient culture technique and pot experiment.

采用不同浓度K2CrO4(0，0.4，0.8和1.2 mmol/L)的Hoagland营养液处理黑麦幼苗，测定铬在黑麦体内的亚细胞分布、铬化学形态及不同部位的积累。

By analyzing theory foundation of mathematical morphology in the digital image processing, researching morphology arithmetic of the binary Image, discussing two basic forms for the least structure element: dilation and erosion.

通过分析数学形态学在图像中的理论基础，研究二值图像的形态分析算法，探讨最小结构元素的两种基本形态：膨胀和腐蚀；分析了数学形态学复杂算法的基本原理，把数学形态学的部分并行处理理念引入到家实际应用中。