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催化作用

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Study on spectrophotometric determination of ferrum with phenylfluorone in thepresence of β-CD and OP ;2. A new method for the determination of trace Crwas studied,which was based on surfactant OP enhancement.

在HAc-NaAc缓冲溶液介质中,在乳化剂 OP 存在下,痕量铬对过氧化氢氧化中性红的褪色反应有很强的催化作用,据此建立了测定微量铬的催化动力学光度法。

Metal-containing molecular sieves were very stable during oxidation reaction, which was carried out heterogeneously.

孔径较小的MeAPSO-34分子筛的催化氧化活性来自于外表面上过渡金属的催化作用

A new catalytic spectrophotometry was established for the determination of trace silver based on the catalytic effect of Ag on the oxidational discoloration reaction of methyl violet with potassium persulfate in buffer medium of HAc-NaAc including phenothroline as activator.

在醋酸-醋酸钠缓冲介质中,有活化剂邻二氮菲存在时,Ag对过硫酸钾氧化甲基紫褪色反应有催化作用,建立了测定痕量银的新催化光度法。

The maximal reaction rate of pyrotechnical reagent with potassium nitrate added with CuO by mixing method is 7.38 min-1, which is 1.30 times of that without catalyst. The time to maximal rate is 53.55 min, which is lower than that without catalyst by 66.3%.

氧化铜对含硝酸钾的烟火药剂具有催化作用,混合法添加的催化效果最佳;此药剂最大反应速率为7.38 min-1,是不含催化剂药剂的1.30倍;到达最大反应速率时间为53.55 min,比不含催化剂的药剂降低了66.3%。

The maximal reaction rate of pyrotechnical reagent with potassium perchlorate added with Fe2O3 by crystallization method is 8.10 min-1, which is 4.09 times of that without catalyst. The time to maximal rate is 8.52 min, which is lower than that without catalyst by 92.8%. It was also found that CuO can catalyze pyrotechnical reagent with potassium nitrate, and the addition is better with mixing method.

结果表明,氧化铁对含高氯酸钾的烟火药剂具有催化作用,以结晶添加法催化效果最佳;此药剂的最大反应速率为8.10 min-1,是不含催化剂药剂的4.09倍;到达最大反应速率时间为8.52 min,比不含催化剂的药剂降低了92.8%。

Hydrothermal reactions makes water a Bronsted base-acid and act as an effective catalyst and the metal ions represent Lewis base character. The conversion process occurs in a very complex network of parallel, consecutive and equilibrium reactions, and the last step being the catalyzed Cannizzaro-type reaction of pyruvaldehyde to lactic acid.

nsted酸碱并具有一定的催化作用,金属离子在水热催化降解丙酮醛生成乳酸中表现出Lewis碱的特性,能与丙酮醛生成金属复合物,最终生成乳酸,此反应过程符合Cannizzaro反应特性。

According to this, a series of new methods to determine trace cobalt, copper, antimony, cadmium, aluminum and iron was established by taking advantage of the characteristic of metal ions with intense catalysis effect on hydrogen peroxide oxygenating rhodanine.

基于此,利用痕量金属离子对过氧化氢氧化若丹宁具有强烈催化作用的性质,建立了一系列利用新型含羧酸基偶氮若丹宁衍生物催化荧光法测定痕量钴、铜、锑、镉、铝和铁的新方法。

This paper describes the experiment of hydrolysis of cellulose under acid and enzyme catalyzing.

探讨纤维素在酸催化及酶催化作用下的降解方法。

Reactive Red 195(RR 195) and C.I. Acid Black 234(AB 234) in the presence of H2O2. The catalytic function of Fe-AO-PAN on dye degradation was investigated with respect to decoloration percentage in this work.

活性红195(RR 195)和C.I。酸性黑234(AB 234)的光催化氧化降解反应中,考察了其对降解反应的催化作用

Ferric nitrate and cupric nitrate can catalyze carbonization process. It is discovered that the catalyst dispersion on alkaline surface is poor through catalyst adsorption study.

对单元催化炭化过程的研究发现,铁、铜的硝酸盐对炭化过程有催化作用,能够减缓炭化过程中挥发份的最大析出速度,有利于各向同性炭前驱体的形成。

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