催化作用

The properties of the polarographic wave and the mechanism of the electrode reaction were studied with diversified electrochemical methods.

在极谱分析体系中，某些具有表面活性的有机试剂在电极表面有很强的吸附性，可以起到去极剂、催化、加速电极过程的作用。

The method comprises heating up the lactic acid solution to gasify at 150-200 degree C, mixing the obtained mixed vapour of lactic acid and water with the carrier gas, entering into gas-solid catalytic reactor to get the reaction product gas by the action of a modified Y zeolite molecular sieve catalytic agent and dewatering after heating up the mixed gas to 200-450 degree C, obtaining the propenoic acid solution through gas-liquid dissociation after cooling the reaction product gas, obtaining coarse propenoic acid products form the propenoic acid solution by gas stripping, azeotropic distillation, extraction and rectification in turns.

其特征在于将乳酸水溶液加热至150～200℃气化得到的乳酸-水混合蒸气与载气混合，将混合后的气体继续加热到200～450℃后进入气-固相催化反应器中经改性Y沸石分子筛催化剂作用脱水得反应产物气体，反应产物气体冷却后经气液分离得到丙烯酸溶液，丙烯酸溶液再依次经过气提、共沸蒸馏或萃取、精馏得到粗丙烯酸产品。

The experimental results showed that the activity of Candida rugosa lipase in the AOT microemulsions system had a typical bell-shaped dependence on the ion concentration.

结果表明，所研究的碱金属、碱土金属氯化盐对该酶反应有作用，具有类似钟形的曲线；稀土离子对该酶催化反应也存在类似影响。

A series of terpenoids, including sesqui-, di- and tri terpernoids were also observed, which was accounted for D-limonene had influence on the metabolites of marine bacteria.

从南海大亚湾的海洋微生物中筛选出3株对单萜压D-柠檬烯有显著生物催化转化作用的海洋细菌（Vibrio cholerae、Listonella damsela和Vibrio alginolyticus）。

A series of mono-, sesqui-, di- and tri-terpenoids with various structural types, which produced by bio- oxidation, hydrogenation, hydrolyzation, esterification and cyclic cleavage toward-limenone, were analyed by GC-MS.

经GC-MS分析发现该两细菌对-柠檬烯有显著的生物催化转化作用，能对底物进行不同程度的氧化、还原、水解、酯化、开环等反应，并产生丰富的系列结构不同的其它萜类化合物：包括单萜、倍半萜、二萜、以及三萜等。

Therefore, we characterized the Cyt c P71H/M80V variant protein electrochemically and spectroscopically. All the experimental results showed that the introduced histidine at position 71 did not act as a functional distal-histidine, but most likely coordinated to the heme iron, maybe due to the flexibility of theΩloop segment (resides 70-84) of Cyt c protein.

于是我们对P71H／M80V蛋白性质进行了一系列的研究，结果表明可能是由于Cyt c中Ωloop D肽段(residues 70-84)具有很强的柔韧性，使得His71并没有象HRP中的distal histidine一样起到酸碱催化功能，而是与heme发生了配位作用，无论是在氧化态还是还原态都成了heme的第六轴向配体。

A pair of FRET(frequency resonance energy transfer) donor-acceptor chromophores were simultaneously labeled on immunoglobulin G at varied ratios to prepare the spectroscopically encoded core materials,which were then housed inside a silica shell by the hydrolysis and polycondensation of tetraethoxysilane in water-in-oil microemulsion to synthesize the optically encoded silica nanomaterials.

采用两种FRET供受体荧光染料按不同的比例与载体材料人免疫球蛋白作用制备荧光编码的载体材料，以荧光编码的载体材料为内核材料，利用氨水催化硅烷化试剂在反相微乳液中水解包裹内核材料制备成一系列多色光学编码硅壳纳米材料。

Ten novel derivatives of 1-phenyl-5-[5-(substituted anilinocarbonylmethylthio)-4-phenyl-1,2,4- triazol-3-ylmethylthio]-tetrazole were synthesized rapidly in high yields by the reaction of N--2-chloryacetanilide (3) with 1-phenyl-5-(5-mercapto-4-phenyl-1,2,4-triazol-3-ylmethylthio)-tetrazo- le (2) under microwave irradiation and phase transfer catalysis conditions.

采用微波和相转移催化法通过1-苯基-5-(4-苯基-1，2，4-三唑-5-巯基-3-甲硫基)四唑(2)与2-氯乙酰芳胺(3)反应高效、快速地合成了10种尚未见文献报道的1-苯基-5-[5--4-苯基-1，2，4-三唑-3-甲硫基]四唑。其结构经IR，1HNMR，13CNMR和元素分析表征。生物活性实验结果表明，该类化合物在较低浓度下部分化合物对小麦芽有很好的促进作用

As all know, Cu-NiRs have trimeric structures, in their each monomer, there exist two types of Cu centers that play pivotal roles as the components of electron transfer pathway in the process of catalysis.

Cu-NiRs呈三聚体结构，每个单体都含有两种类型的铜原子，它们在酶催化过程中起着传递电子的重要作用。

Compared with the catalytic behaviors of the reference catalysts, CpTiCl〓 and n-CpTiCl〓, we could identify that the pendant ethereal group played an important role in this selective trimerization process.

将它们的催化性能与CpTiCl〓、n-CpTiCl〓比较，可以确定，氧对钛活性中心的配位对乙烯三聚反应起重要作用。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。