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催化作用

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The wall of the burning chamber was pitted at the beginning then gradually burnt through.By means of the Bunsen burner,tubular furnace and XRD,SEM,EDS,this special type of high-temperabure destruction was studied.It was found that the phenomenon is resulted from the combined action of CO and lower hydrocarbon on Ni-Cr alloy.Firstly,Ni-Cr alloy is carbonized and selectively oxidized by CO to produce Cr2C,Cr3C2 and Ni-Cr2O3,while the capillary cracks in the surface layer are formed simultaneously.

作者利用几种现代手段和试验方法,对这一燃烧破坏现象进行了系统地模拟研究,发现这是CO和低分子烃在高温下对合金共同作用的结果:第一步CO作用使合金表层发生氧化和碳化,造成裂隙;第二步低分子烃扩散进裂隙并在Ni-Cr2O3微粒的催化下,裂解生在石墨炭并包复在Ni-Cr2O3微粒周围,体积增大。

In the asymmetric hydrogenation of ethyl pyruvate catalyzed by 0 5% Rh/PVP TiO 2, the chiral modifier cinchonidine not only induces the enantioselectivity, but also accelerates the reaction rate greatly.

研究了辛可尼定作手性修饰剂修饰的负载型纳米铑簇合物催化剂(0 5 %Rh/PVP TiO2 )催化丙酮酸乙酯不对称氢化反应,在该反应中手性修饰剂辛可尼定不仅具有对产物生成的手性诱导作用,而且对反应具有明显加速作用;在优化反应条件后,反应的TOF和对映选择性分别可以达到 5 8 0min-1和

From the view of conservation of organic matter, the water body in evaporates basin takes on the character of density stratification; the niederschlag below mascon has high oxidation-reduction potential, which contribute to the conservation of organic matter. From the view of generation of hydrocarbon, bacteria, algae and lithology on the bottom of salt-water basin play important role in generation of hydrocarbon; furthermore, clunch from the redbeds acting as catalyzer, alkali metals making the hydrocarbon mobile.

从油气生成条件看,细菌、藻类及咸水盆地底层的岩性对油气的生成具有重要作用,此外红层中的粘土对烃类的生成起到催化的作用,碱金属可使生成的烃类发生流动;从有机质的保存条件看,蒸发岩盆地水体中具有密度分层的特点,在高密度层以下的沉积物具有强的氧化还原电位,从而使有机质保存下来。

The author also changes theproportion of Fe~(3+)、Cu~(2+) in total ions to study the complementariness of Fe~(3+)、Cu~(2+) in thesystem and proves that the replacement of the single catalytic ions with the complicatedSystem Fe~(3+)/Cu~(2+)/H_2O_2 has a good ability of the ability of counter assault against thechanges of pH value.

通过改变Fe~(3+)、Cu~(2+)在总离子中的不同比例,研究了Fe~(3+)、Cu~(2+)在体系中的相互补充、相互促进的作用,证明了用Fe~(3+)/Cu~(3+)/H_2O_2复合体系代替单一的催化离子能有效的对pH的变化起到很好的抗冲击的作用。

The matrix composites for diamond tools were tested with such modern testing instruments and equipments as DTA-7 differential thermal analyzer, JCXA-733 electronic probe and scanning electron microscope, JEM 2000 FX Ⅱ transmission electron microscope, eXL energy spectrometer, and humidity test instrument. The analysis, comparison, and induction of the testing results prove the enhancing effects of the rare earth on the matrix composites: degeneration, micro-alloying, purification, and catalytic activation. The comprehensive function of these effects leads to the decrease in the porosity of the matrix composites and to the increase in such actual indexes as the flexural strength, hardness, and impact ductility of the whole rare earth Fe-based diamond tool materials.

由DTA-7型差热分析仪、JCXA-733型电子探针及扫描电镜、JEM2000FXⅡ型透射电镜、eXL能谱仪以及莱茨2AP高温显微镜材料润湿性测试仪等现代测试仪器设备对金刚石工具材料进行了测试实验,对测试实验的结果进行了分析、比较和归纳,证实了稀土对胎体材料具有变性、微合金化、纯化和催化活化等四大强化作用机理,这些机理的综合作用导致了胎体材料孔隙率的降低和整个稀土Fe基金刚石工具材料抗弯强度、硬度及冲击韧性等实际使用性能的上升。

The result indicates that copper plays an important role in catalyzing the O_2~- dismutation, zinc not only stabilizes the whole structure but also promotes organization of the active site structure.

结果表明,金属铜对于催化歧化超氧阴离子O_2~-具有至关重要的作用,而金属锌起到稳定结构和促成构建活性中心的作用。

Glucokinase, also called hexokinase Ⅳ, which catalyses glucose phosphorylation in hepatocytes and pancreatic β cells, is a key component of the glucose sensing machinery in mammals and plays a fundamental role in glucose homeostasis.

葡萄糖激酶(Glucokinase,GK)即Ⅳ型己糖激酶(Hexokinase,HK),主要作用是催化肝细胞和胰岛β细胞内的葡萄糖磷酸化为6磷酸葡萄糖,该步反应是细胞内葡萄糖代谢的初始反应,也是限速步骤之一,因此葡萄糖激酶又称为细胞的葡萄糖感受机制,在维持血糖稳定方面起着关键的作用。

Calculations indicate that Ni-Ni interaction in Ni81B19 alloy is stronger than metallic bond in pure Ni. However, the Ni-Ni interaction in pure Ni is stronger than that in Ni80P20 alloy. Direct B-B contact in Ni81B19 alloys appears in our simulation, however no direct P-P contact in Ni80P20 alloys is found.

其次,在Ni的d电子和B的p电子之间存在着强烈的相互作用,形成Ni原子和B原子间的强共价作用。B和P的加入后使催化反应中的活性位Ni的活性d电子数增加,在合金中起修饰作用。

The synergism of photochemical catalysis and ozonize to treat light polluted water is studied as well as single effects.

研究了利用光催化-臭氧协同处理微污染水体,分别考察了单一作用和协同作用、不同降解时间、pH值以及不同负载方式下的去除率。

The characters, types, valid parameters, examinable methods and influence factors are summa-rized for π-π interaction. In addition, some introduction is made for evolution of π-π interaction in the field of self-assembly, asymmetric catalysis, organic semiconductor, and so on.

本文对π-π作用的特征、形式、有效参数和表征方法等作了比较全面的综述,同时小结了影响π-π作用的一些重要因素,最后还概述了近年来π-π作用在超分子组装、不对称催化、有机半导体材料等领域的研究进展。

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