催化作用

In this paper, the effects of different catalyst combinations on the synthesis of α-chloro-dodecanoic acid were investigated, in which a series of acyl chlorides such as 4-toluene sulfonyl chloride, dodecanoyl chloride, chlorosulphonic acid , etc.

本文从烯酮式反应机理出发，以α-氯代十二酸的合成为模型，对酰氯化试剂(对甲苯磺酰氯、十二酰氯、氯磺酸等)和质子酸催化剂(如H型离子交换树脂、氯磺酸、对甲苯磺酸、醋酸等)进行组合和选择，并与文献报道的特殊添加剂乙酐比较，研究不同催化体系在酸催化合成α-氯代脂肪酸时的催化作用。

Homogeneous catalytic oxidations of organic substrates such as alkane and alkene catalyzed by m-oxo-bismetalloporphyrins and flexible alkoxyl oxygen linked-bismetalloporphyrins were introduced,and the catalytic mechanism of these two bismetalloporphyrins,along with the possible synergetic catalysis mechanism of binuclear central metal were discussed.

主要介绍了μ-氧代双核金属卟啉和以柔韧烷氧链相连的双核金属卟啉作为仿酶催化剂在均相催化烷烃、烯烃等有机底物氧化方面的研究进展，并对这两类双核金属卟啉的催化机理、金属双核的协同催化作用机理作了论述，最后展望了双核金属卟啉仿酶催化剂的研究前景。

Based on the problem of various types of catalyst and according to the features of carbonylation catalysts reactions, our team has been designed a series of new metal complexes of benimidazoles, which can be used for carbonylation catalyst of industry. Seven new benzimidazole derivatives were prepared by the o-phenylenediamine、oxalic acid、glycolic acid、monomethyl monopotassium malonate、ethyl cyanoacetate、succinic anhydride. The structures of them were confirmed by IR、Elemental analsis. The crystal structures of d and e were determined by X-ray single crystal diffraction of Germanic Bruker Smart APEX II CCD. The catalysis of them was tested by carbonylation reactions.

本文设计以邻苯二胺和草酸、羟基乙酸、丙二酸单甲酯、氰基乙酸乙酯、丁二酸单甲酯为原料采用PPA催化和无机酸催化法，合成了4种苯并咪唑-2-羧酸衍生物并进行了表征；培养了2个化合物d、e的晶体并测定和讨论了晶体结构；制备了3种未见报道的苯并咪唑金属配合物，对配合物在羰基化法制醋酐-醋酸反应的催化作用进行了初步试验。

Compared with conventional combustion, catalytic combustion is fameless, in which VOC is pre-mixed with air, then passes homogenously catalyst bed and burned efficiently. More significantly,because catalytic combustion may be performed under lower temperature, N2 in air is free of being oxidized into NOX, which is responsible for the formation of acidic rain ,at the same time when catalytic combustion happens.

与普通燃烧方式相比，催化燃烧是无焰燃烧，VOC与空气进行预混合后，均匀通过催化剂床层，在活性粒子的催化作用下实现燃烧，具有很高的燃烧效率，而且催化燃烧能显著降低燃烧温度，避免了其燃烧时将空气中氮气同时氧化，形成氮氧化物，从而避免了酸雨的产生。

The results illustrate the facts that:(1) The best catalyst among them is manganous sulfate,(2) compound catalyst consisting of a mixture of metal sulfates in proper proportion is better than any one of them used alone.

本文研究的第二种脱硫新工艺是采用MnSO〓等催化剂使SO〓经过液相催化成SO〓进而形成稀硫酸，实验发现MnSO〓相对于ZnSO〓和〓有较好的催化作用，三者按一定比例组成的复合催化剂的催化能力优于单组分的催化能力。

According to studying the factors of using a series of rhodanine ramifications to determine metal ions by catalytic fluorescence method and by utilizing the strong catalysis of metal ions to potassium periodate oxygenating rhodanine, a catalytic fluorescence method of using the new type rhodanine ramifications to determine trace tin, antimony and cobalt was established.

首次研究了系列若丹宁衍生物在催化荧光法测定金属离子中的各影响因素，利用痕量金属离子对高碘酸钾氧化若丹宁具有强烈催化作用的性质，建立了新型若丹宁物质催化荧光法测定痕量锡、锑、钴的新方法。

Utilizing the intense catalysis of metal ions to peroxide oxygenating rhodanine, a catalytic fluorescence method of using the new type rhodanine to determine trace iron, cobalt, copper, tin and antimony was established.

利用痕量金属离子对过氧化氢氧化若丹宁具有强烈催化作用的性质，建立了一系列利用新型若丹宁物质催化荧光法测定痕量铁、钴、铜、锡和锑的新方法；较系统研究了系列若丹宁衍生物在催化荧光法测定金属离子的各影响因素，确定了反应的最佳条件，计算了动力学参数。

Based on a brief review of semiconductor photocatalytic mechanism and researches in the past 30 years on TiO2 heterogeneous photocatalysis, this paper emphasizes that the natural vanadiferous rutile and its modified products, which have not been investigated by either Chinese or foreign research groups, degrade halogenated organic contaminants. By means of grinding, heating in situ, heating, quenching and electron irradiation, the natural rutile could be modified.

在简述半导体光催化理论及TiO2多相光催化作用近30年研究现状的基础上，重点对国内外一直处於空白状态的天然含钒金红石光催化性能进行研究。

In this study, a new idea that RDF is made with catalysis of alkali,alkali earth or transition metal salts. The addition of the catalysts is to low ignition and burn off temperature temperature.

本课题提出在制备RDF过程中引入催化助燃剂的新思路，这些催化助燃剂包括了许多碱或碱土金属的化合物，同时也考虑一些过渡金属的催化作用。

By water contact angle meter, photocatalytic ability of several kinds or crystal form of TiO2 has been compared. In addition, OH and OH~ have been proved to be in existence on coating surface by FTIR.

通过接触角仪比较了不同晶型和不同型号的纳米TiO_2以及颜料级TiO_2光催化能力的差别，并利用红外光谱证实在纳米级光催化涂料的表面产生了具有很强光催化作用的氢氧自由基。

In the United States, chronic alcoholism and hepatitis C are the most common ones.

在美国，慢性酒精中毒，肝炎是最常见的。

If you have any questions, you can contact me anytime.

如果有任何问题，你可以随时联系我。