催化作用

Chapter Five: We use photoemission spectroscopy to study the interaction of the rare earth metal Cerium overlayers with GaSb (111) surface and their oxidation behavior as well.

第五章 利用超高真空中的光电子能谱的测量，就稀土金属Ce对半导体GaSb(111)表面的催化氧化特性进行了研究，并且研究了Ce的厚膜本身的氧化，探讨了Ce在催化氧化中所起的作用。

With the characterization of NMR and IR, combining with the synthesis of active species and studies of their structures, it is suggested that the hydride [RuHCl(PPh3)3], being favorably formed in the acid media, exhibited higher activity in the reduction of the C=C bond, while the hydride [RuH4(PPh3)3], being preponderantly formed in the basic media, showed activity and higher selectivity towards the C=O reduction.

通过核磁、红外等表征手段，并结合可能催化活性配合物的合成和结构研究，推测了在非水介质中对C=C和C=O双键起到活化作用的催化剂活性物种和可能的选择加氢反应机理，即，催化剂[RuCl2(PPh3)3]在酸性环境下倾向于生成[RuHCl(PPh3)3]物种，该Ru-H物种对C=C双键加氢反应表现出较高的活性；而碱性环境下则易于生成[RuH4(PPh3)3]物种，该Ru-H物种对C=O双键加氢具有较高的催化活性。

A summary is given on the FCC technology development at home and abroad in recent years, including the process capacity, unit scale, new process technology and new catalyst as well as the role FCC process in residuum processing.

对近年来国内外催化裂化工艺在加工能力、装置规模、新工艺新催化剂开发，催化裂化工艺在重油加工中的作用等进行了综述。

Such as lactate dehydrogenase, xanthine oxidase and so on fall into this category.

其中氧化酶催化底物被分子氧所氧化，而脱氢酶则催化从底物分子上脱去氢的作用。

The reason may be that complex formed by rhodium and halide was difficult to produce the catalytic active species. Therefore halide ion was the poison for the rhodium catalyst in hydroformylation of olefins in ionic liquid. The effect of double long chain cationic surfactant (DCMAB, dicetyl dimethylammonium bromide) on selective hydrogenation of cinnmaldehyde catalyzed with RuCl3·x H2O/TPPTS was studied.

进一步的研究表明在使用有良好反应活性的两种催化剂HRh3 、Rh_2进行催化反应时，向体系中加入含有卤离子的化合物时将使反应活性大大降低，而且随着卤化物加入量的增加，催化剂的活性迅速下降，这是卤离子可能和金属铑作用使它难于生成催化活性物种，进一步证明卤素离子是引起催化剂活性下降的极其重要的因素。

This dissertation is mainly focused on the reactivity of methylenecyclopropanes and comprises six parts. 1 The reactions of methylenecyclopropanes with phenylsulfenyl chloride, phenylselenyl chloride and diphenyl diselenide; 2 The coupling reactions of the ring-opening products derivated from methylenecyclopropanes; 3 The palladium-catalyzed ring-enlargement of mono-aryl group substituted methylenecyclopropanes to cyclobutenes. 4 The gold-catalyzed domino ring-opening and ring-closing hydroamination of methylenecyclopropanes with sulfonamides; 5 The Lewis acid-catalyzed reactions of mono-aryl group substituted methylenecyclopropanes with diethyl ketomalonate in the presence of water; 6 The iodobenzene diacetate mediated novel 1,3-dipolar cycloaddition of methylenecyclopropanes, vinylidenecyclopropanes, and methylenecyclobutane with phthalhydrazine.

本论文主要研究了亚甲基环丙烷类化合物的一些化学反应性能，共由以下六部分组成：1、亚甲基环丙烷类化合物与苯硫氯、苯硒氯及二苯基二硒的反应；2、亚甲基环丙烷类化合物开环产物的偶联反应；3、单芳基取代的亚甲基环丙烷类化合物在钯催化剂作用下的扩环反应；4、金化合物催化磺酰胺对亚甲基环丙烷类化合物的串联开环关环氨氢化反应；5、路易斯酸催化亚甲基环丙烷类化合物与丙酮二羧酸二乙酯在有水存在下的反应；6、醋酸碘苯促进的亚甲基环丙烷类化合物、亚乙烯基环丙烷类化合物及亚甲基环丁烷类化合物与邻苯二甲酰肼的新型1，3-偶极环加成反应。

A process for preparingp-fluo-2-(2-methyl-3-propionyl)-4-oxy-N,3-diphenyl-phenylbutylamide includes such steps as Friedle-Craft acylating of newly prepared phenylacetyl chloride and fluorobenzene under catalysis of AlCl3 to obtain 4-fluoro-phenylbenzyl ketone, brominating at carbonyl alpha position under catalysis of less AlCl3 to obtain alpha-bromo-4-fluo-phenylbenzyl ketone, and condensing with isobutyryl acetanilide under action of sodium ethoxide.

本发明涉及一种制备对氟－2－(2－甲基－3－氧丙基)－4－氧－N，3－二苯基－苯丁酰胺(1)的方法，其包括以下步骤：新制的苯乙酰氯与氟苯在AlCl3催化下进行Friedle－Craft酰化反应，得到对4－氟－苯基苄基酮(4)；化合物(4)在少量AlCl3催化下进行羰基α位溴化，得到α－溴－4－氟－苯基苄基酮(5)；然后(3)异丁酰乙酰苯胺在乙醇钠作用下与化合物(5)进行缩合。

Two reasons can be explained the improvements of catalytic activities after the addition of Ce. One is the increase of the thermal stability of Ni-B and Ni-P nanoamorphous alloys, which retards the nanocrystalline Ni to aggregate during the exothermal reaction of benzene hydrogenation. The other is to make their grain sizes smaller, thus it increases the number of activity center in unit mass.

说明加入Ce提高催化活性的主要作用有两方面，一是提高Ni-B和Ni-P纳米非晶态合金的热稳定性，抑制催化苯加氢反应时大量放热促使纳米晶Ni的聚集长大；二是使生成的Ni-B和Ni-P纳米非晶态合金颗粒更为细小，从而增加单位质量样品的活性中心数量。

The nanocrystalline film was composed of a three-diminsional network of interconnected particles.Reodx behavior and electrocatalytic activities of the Ti/nano-TiO2 electrode were investigated by cyclic voltammetry from oxalic acid and nitrobenzene to glyoxalic acid and p-aminionphenol. The Ti/Ti redox system,as a medium,shows highly electrocatalytic activities and stable characteristic to indirect electroreduction of organic compounds(e.g.:oxalic acid and nitrobenzene).

循环伏安法研究了纳米TiO2膜电极对草酸还原为乙醛酸、硝基苯还原为对氨基苯酚反应的电催化活性，结果发现纳米膜中的Ti/Ti氧化还原电对起一种中介作用，可使有机物如草酸和硝基苯间接电还原，且电极催化活性高，性能稳定。

The hybrid composite PW11Co/PAMAM was characterized by FT-IR, UV-Vis diffuse reflectance spectra, XPS, XRD and TG/DTA, indicating that the PW11Co was chemically anchored to PAMAM. The morphologies of the title composite were characterized by scanning electron microscopy and transmission electron microscopy. The catalytic activity was evaluated by oxidation of isobutyraldehyde to isobutyric acid in MeCN under mild conditions (20 ℃, ambient pressure), showing that the title compound is a more effective and recoverable catalyst than corresponding PW11Co.

通过FT-IR、DR-UV-Vis、XRD、TEM、SEM、TG/DTA等手段对其进行了表征，并考察了其对异丁醛转化异丁酸的催化活性，实验结果表明，多金属氧酸盐通过配位键与聚酰胺-胺作用形成的无机-有机复合物可望成为一种催化活性高且易于分离和重复使用的多相催化剂。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！