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催化作用

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The isomerization reaction of propylene oxide to produce allyl alcohol catalyzed by basic lithium phosphate was studied.

研究了环氧丙烷在碱性磷酸锂催化作用下异构化生成烯丙醇反应过程,考察催化剂的制备条件,异构化温度对催化性能的影响,以及催化反应机理和动力学特性。

A new catalytic kinetic method with second derivative oscillopolarography detection for determining trace amounts of NO〓〓 has been developed. The method is based on the catalytic oxidation of Amarath by potassium bromide in the diluted H〓SO〓. The detection limit of the method is 2.8×10〓g/ml, the linear range of the determination 〓is 0.6~14ng/ml for NO〓.

首次研究了鸡冠红的示波极谱行为,并发现NO〓〓在稀硫酸介质中对KBrO〓氧化鸡冠红褪色反应具有强的催化作用,本文采用两阶导数示波极谱法作监测技术,测定了该催化体系的表观反应级数及动力学方程,建立了催化动力学伏安法测定痕量NO〓〓的新方法。

Mechanism of catalyzed oxidation of SO2 with pyrolusite suggested that the process was combined catalysis in the presence of Mn and Fe both in solution and solid.

软锰矿催化脱硫的机理分析表明,过程是液相Mn、Fe协同催化与固相催化作用相结合。

A simple and highly sensitive new kinetic catalytic fluorimetric method was proposed for the determination of trace chromium,based on the catalytic effect of trace amounts of chromium on the oxidation of Pyronine Y by hydrogen peroxide in acetic acid-sodium acetate buffer medium leading to a decrease in the fluorescence intensity.

在HAc-NaAc缓冲体系中,痕量铬对过氧化氢氧化吡咯红 Y的氧化还原反应有催化作用,使吡咯红 Y荧光减弱,据此建立了催化荧光法测定痕量铬的新方法,同时考察了该催化反应的最优条件及动力学性质。

The effect of catalyzator on yielding of coal conversion was analyzed.The results show that the formation of volatile matter is raised by using differen...

KMnO4,Fe2O3,MnO2的催化作用机理与其空价层原子轨道有关,CaO的催化作用机理与其本身的碱性特征有关。

In this field, the absorption on solid surface is the indispensable step of heterogonous catalysis, and the most widely applied catalysis is the one of gas on solid.

据统计,世界上85%的化学制品要依靠催化反应制得,而催化与吸附关系密切,其中固体表面的吸附是多相催化的必经步骤,应用的最为广泛的是气固相的催化作用

The mathematic relationship between coking coal's characters and coke reactivity index and coke strength after reaction was studied.Main effect factors were analyzed by dynamics model formed by metaplast and mesophase.Taking metamorphic degree of coal, coal maceral, caking property, ash and the content of K_2O and CaO as independent variable, forecasting model was set up by the coking tests with 25 kinds of coals used in the industries.It concludes that exinite in coal makes CRI increase and CSR...

以研究炼焦煤性质与焦炭反应性、反应后强度之间的数学关系为目的,通过胶质体和中间相形成动力学解析导出模型的主要影响因子,以煤的变质程度、煤岩组成、粘结性、灰分及K2O和CaO含量等因素为自变量,由25种工业用煤的炼焦试验,建立出预测模型,并得出壳质组使反应性增大及反应后强度降低;K2O催化作用强于CaO,且两者的催化作用均随煤的变质程度不同而不同等重要结论。

We discuss the mechanism of trimerization of nitriles catalyzed by organolithium compounds and study the catalystic characteristics. Using this new method, the yield of triazines is greatly improved.

另外,实验探讨了有机锂化物对芳香腈三聚反应的催化作用,得到了较高的产率,同时,研究了它的作用机理和催化性能。

These compounds, properly designed, can be 1~2 orders of magnitude more surface active than surfactants with a single corresponding hydrophobic and a single corresponding hydrophilic group in the molecules. In this work, selected trimeric surfactant TNP is first synthesized.

本文研究了Gemini表面活性剂GNP和GTB用于脂肪酸酯的碱性水解催化作用,测定了水解速率常数和反应活化能,从动力学机理上说明了所合成的Gemini表面活性剂对脂肪酸酯水解反应有明显的胶束催化作用

Under elec trodes, elec trochemical reaction will combin e with chemical catalysis reaction,which will lead to the elec trochemically and catalytically degradation of organic molecules.

在电极的作用下,电化学反应和化学催化作用结合,可导致有机分子的电催化降解。

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