催化作用

Firstly, 3-ethylthiobutanal was prepared from crotonaldehyde reacting with ethanehiol in triethylamine with high yield. Secondly, methyl acetoacetate was converted to 6-ethylthiohept-3-en-2-one by three steps via hydrolysis, condensation with 3-ethyltio-butanal and dehydration, then 6-ethylthiohept-3-en-2-one was cycloco ndensed with dimethyl malonate by Michael addition and Claisen condensation, followed by saponification and decarboxylation to give the intermediate of 5-(2-ethylthiopropyl)-cyclohexane-1,3-dione.

首先，以巴豆醛与乙硫醇为原料，在三乙胺的催化作用下高收率制得3-乙硫基丁醛；然后从乙酰乙酸甲酯出发，通过碱水解、与3-乙硫基丁醛缩合、脱水三步反应合成6-乙硫基-3-烯-2-庚酮，接着6-乙硫基-3-烯-2-庚酮与丙二酸二甲酯通过Michael加成和Claisen缩合成环，再通过皂化和脱羧反应生成中间体5-[2-丙基]-1，3-环己二酮；再与丙酸酐反应丙酰化，最后与0-3-氯-2-丙烯基羟胺肟化，得到目标化合物烯草酮。

The catalytic action of various kinds of functional coordination compound and metallomicelles which are made from the complex and micelle, as mimic hydrolase or peroxidase, have been studied respectively in catalyzing the carboxylic ester and phosphatic diester hydrolysis, and the phenolic derivant oxidation in this paper. Some novel results of academic significance have been obtained.

本文以不同类型的功能配合物及其与表面活性剂形成的金属胶束作为水解酶和过氧化物酶的模拟酶模型，分别研究它们对羧酸酯、磷酸二酯水解反应和酚类氧化反应的催化作用，取得了新的有学术意义的成果。

ABSTRACT Objective To research the electrocatalytic action of poly film modifing electrode for determination of ciprofloxacin hydrochloride, an electroanalytic method of content determination CPLX was set up.

目的 研究聚中性红薄膜修饰电极对盐酸环丙沙星的电催化作用，建立一种定量检测CPLX的电化学分析方法。

Electrocatalysis of carbon atom wire modified electrode to the electrochemical reaction of uric acid was investigated by using cyclic voltammetry and differential pulse voltammetry.

通过循环伏安法和差分脉冲伏安法研究了碳原子线修饰电极对尿酸电化学反应的催化作用。

Under the same conditions, the electrocatalytic ability of the electrode was higher than that of the pure Pt electrode.

结果表明Pt-Ru微粒电极对甲醇的电氧化显示出催化作用， Ru的加入提高了电极的抗中毒能力。

The direct electroreduction of nitrite requires large overpotential on most electrode surfaces, however, various transition-metal complexes were proved to be good catalysts for nitrite reduction.

NO〓〓的直接电还原需要很高的过电位，但各种各样的金属配合物被证明是NO〓〓电还原的良好催化剂，而我们在实验中惊奇地发现一系列饱和未取代的和稀土取代的杂多化合物对NO〓〓还原产生良好的催化作用。

It's found that th e activation of alloy was improved with increasing the concentration,temperature and immersing time of alkaline solution,the reason is that the Zr-rich surface of alloy was conversed to Nirich surface because of the strong erodent action of alkaline solution,this catalyzes ...

实验发现：储氢合金电极的活化性能随碱液浓度增大、温度升高以及浸泡时间的延长得到改善，主要由于KOH的强腐蚀性使合金表面由富Zr层转化为富Ni层，为氢的吸附离解起到催化作用，总结出最佳KOH处理液的实验参数：6mol/L、80℃、浸泡 2 4h ，在此条件下合金电极循环两周即达最大放电容量。

With the addition amount of rare earth oxide increasing,the two exothermal peaks of AP came closer and finally merge into one strong peak with a great increase of decomposition heat.

不同稀土氧化物种类对高氯酸铵热分解的催化作用有一定的差异，轻稀土镨和钕的氧化物使分解峰表现为前弱后强的两个相连的峰，中稀土钐和钆的氧化物表现为单一的强峰，而重稀土铒和镱的氧化物表现为前强后弱的两个分立的放热峰。

The results showed that the shape selective effect of the faujasite is obvious, and the thermodynamic balance exists between 2,6 DTBN and 2,7 DTBN.

结果表明，八面沸石对该反应过程有较好的择形催化作用，两种异构化产物(2 ，6 二叔丁基萘和 2 ，7 二叔丁基萘)之间存在着热力学平衡，即两种异构化产物可在酸性中心位上相互转化。

Our earlier experimental results show that trace Fe has obvious catalytic role in the transformation of ferric hydroxide.

前期研究表明微量Fe对Fe_3凝胶的相转化过程有显著的催化作用。

She gently rebuff ed him, but agreed that they could be friends

她婉言拒绝了，但同意作为朋友相处。

If in the penal farm, you were sure to be criticized.

要是在劳改农场，你等着挨绳子吧！