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The hydrogenation of alkali metals using lanthanide trichloride and naphthalene as catalyst has been studied.

本文研究了稀土氯化物对碱金属氢化反应的催化作用

CATALYTIC ACTION OF METAL IONS IN LIQUID PHASE OXIDATION Ⅲ.

金属离子在液相氧化中的催化作用——Ⅲ。

In this thesis, 1, 5-diaryl-3-pyrazilidinones, 1, 5-diaryl-3-hydroxypyrazoles and 3-(2, 3, 4, 6-tetraacetyl-β-D-glucopyranos-1-yl)-1, 5-diaryl-1H-pyrazoles are designed and synthesized.1, 5-diaryl-3-pyrzolidinones were obtained by condensation of 3-arylpropenates and phenylhydrazine or fluorophenylhydrazine under the catalysis of sodium methylate and the yields were about 55-80%.

在本文中,设计合成了1,5-二芳基-3-吡唑烷酮化合物、1,5-二芳基-3-吡唑烷酮化合物和3-(2,3,4,6-四乙酰基-β-D-吡喃葡萄糖-1-基)-1,5-二芳基吡唑化合物。以3-芳基-2-丙烯酸酯为原料,与芳基肼在醇钠的催化作用下,反应可以生成1,5-二芳基-3-吡唑烷酮,产率在55%以上。

The results showed that the redox peak potential difference of metol on IL/CPE was smaller than that on the bare CPE, while peak current was significantly increased, which indicated that IL/CPE had electrocatalytic activity toward the redox of metol.

研究表明,米吐尔在IL/CPE上的氧化、还原峰电位差比其在裸碳糊电极上的小,而峰电流却显著增加,说明IL/CPE对米吐尔有电催化作用;共存物对苯二酚干扰米吐尔的测定,通过方波伏安法可以消除其干扰。

By researching the catalysis action of metals in hydrogen storage materials, it is found that metal activators accelerate hydriding-dehydrding velocity of hydrogen storage materials in the process of grinding, and they also reduce the dehydriding temperature, enhance the hydrogen storage capacity of materials, and hasten the formation of similar-graphite microcrystal in the process of pretreatment.

通过对储氢材料中金属催化作用的研究发现,金属催化剂促进材料球磨过程中的快速吸氢,加快材料的放氢速度,降低材料的放氢温度,提高材料的储氢密度,促进无烟煤在预处理过程中类石墨微晶结构的形成。

The catalysis of some mimetic models of natural peroxidase in the phenol and phenolic derivant oxidation was investigated.

研究了多种过氧化物酶的模拟酶对酚类氧化反应的催化作用

By comparison, multivalent transition metal halides have the best catalytic activity to the Mg-based hydrogen storage materials.

比较发现,多价态过渡族金属卤化物对镁基储氢材料具有最好的催化作用

In this solution, it also could electrocatalysis the reduction process of nitrite.

实验中发现该化合物能对亚硝酸根的还原起催化作用

In the reaction of NAE18 with nitrogen mustard aryl phosphorochloridate, 4-dimethylaminopyridine played critical catalytic action.

在合成工作中发现:在NAE18与氮芥芳基磷酰氯的反应过程中, 4-二甲氨基吡啶起着关键性的催化作用

Doping Cr into perfect TiO2 (110) surface can create the new active surface state different from that of oxygen defect surface ,AM and transition metals deposited TiO2 (110) surface. Its active surface state is the Cr 3d occupied state near EF and the value of band-gap drop from 3.13eV to 1.16eV, so photocatalysis reaction can perform in visual light area after doping Cr into perfect TiO2 (110) surface.

TiO_2(110)面掺杂Cr 可以产生不同于氧缺陷、碱金属及过渡金属负载的新表面态,其表面态为靠近E_F 的Cr3d 电子占据能带,带隙由原来的3.13ev 降至1.16eV,因此,掺Cr 后TiO_2 可在可见光区发生光催化作用

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If you have any questions, you can contact me anytime.

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