使重氮化

The paper discloses a process for diazotization fluorination of aromatic primary amines utilizing sodium nitrite and anhydrous hydrofluoride to produce the corresponding diazonium fluoride which is decomposed, usually by heat, to make the desired fluoroaromatics .

本文通过重氮化工艺路线的改进，在液态氟化氢中进行重氮化和重氮盐的热分解，提高了芳香族氟化物的收率，并且使重氮化反应工艺能应用于工业化生产。

According to Griess reaction, diazonium-salts formed from aromatic amines such as sulfonamides etc., react with NaNO_2 in acid medium and may be coupled with α-naphthylamine or diphenylamine to produce red colored compounds.

一按Griess反应芳香族胺类的重氮化鹽，如对氨基苯磺醯胺类药物等，在酸性溶液中皆能与α-萘胺或二苯胺分别偶合成偶氮色素而显紅色，过多之亞硝酸可与氮色素再作用使紅色消失而呈棕黄色。

The complexation of SCnA also results in a bathochromic shift and a decrease in optic intensity of the absorption spectrum of DS.

在水溶液中磺化杯芳烃可与二苯胺重氮盐形成包结物，导致DS的化学位移向高场移动，同时使其吸收光谱红移，强度下降。

The photodegradation rate of M-PPV 1 was constrained by DABCO that quenches the triplet state of M-PPV; 2increased when the solvent changed from benzene to deuterated benzene in whichthe lifetime of triplet state is longer than that in benzene; 3 was improveddramatically with high concentration of M-PPV triplet state was generated by energytrasfer from biacetyl.

发现：1能猝灭M-PPV的三重态的1，4-二氮二环[2.2.2]辛烷也能有效地抑制光氧化反应的进行；2能提高M-PPV三重态寿命的氘代溶剂也能使M-PPV光氧化降解速率加快，3丁二酮和M-PPV间的能量传递能够提高M-PPV三重态的浓度，这和丁二酮作三重态敏化剂敏化光氧化M-PPV时，M-PPV的光降解速率大大增加也是一致的。

Compounds 3a-3d, 4a-4d, 5a-5d, 6a-6e and 7a-7e were prepared with a new efficient method, in which the aromatic amines were diazotized with isoamyl nitrite in EtONa/EtOH under refluxing condition, and mono -, bis -and tetrakis -substituted calix [4] arenes were obtained respectively as main product by diazo-coupling in different molar ratio to calix [4] arene.

一，提出了一个有效的新方法合成含有芳香偶氮基团的杯[4]芳烃衍生物3a-3d；4a-4d；5a-5d；6a-6e和7a-7e：即在非水溶剂乙醇中用亚硝酸异戊酯，在强碱乙醇钠存在下对芳香胺进行重氮化，得到芳香重氮酸盐沉淀，过滤，然后加入杯[4]芳烃的四氢呋喃溶液，通入CO〓气体调节溶液的pH值为7-9，使其发生偶联反应。

Add 100-150g of finely crushed ice and stir until the m-nitroaniline has been converted into the sulphate and a homogeneous paste results. Cool to 0-5°C by immersion of the beaker in a freezing mixture, stir mechanically and add a cold solution of 18g(0.26mol) of sodium nitrite in 40 ml of water over a period of 10 minutes until a permanent colour is immediately given to potassium iodide-starch paper: do not allow the temperature to rise above 5-7°C during the diazotisation.

加入100-150g碎冰，搅拌至m-硝基苯胺成硫酸盐，把烧杯浸入到冷冻液中冷却到0-5°C，机械搅拌下于 10 min内加亚硝酸钠冷溶液（由18g(0.26mol)亚硝酸钠和40 ml 水组成），直到用淀粉-碘化钾试纸测试时，能使该试纸立即显色且不褪色：在重氮化反应时不允许温度超过5-7°C。

I can not make it blossom and suits me

我不能让树为我开花

When temperatures are above approximately 80 °C discolouration of the raceways or rolling elements is a frequent feature.

当温度高于 80 °C 左右时，滚道或滚动元件褪色是很常见的特征。