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使芳香

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Birch Reduction, one of the most powerful synthetic methodologies available to organic chemists, provides a bridge between aromatic and aliphatic compounds and makes a huge arsenal of aromatic derivatives readily available for construction of alicyclic molecules, which are possibly converted into various natural products.

Birch还原是联接芳香族和脂肪族化合物的桥梁,它使许多芳香族衍生物成为合成脂肪族化合物,尤其六元脂环天然产物的起始原料,因此Birch还原是有机合成中很有用的方法。

Suggestive of ambrosia; fragrant or delicious .

美味佳肴的;芳香的,美味的使人想到神仙食品的;芳香或美味的

This is mainly due to that pyrene ligand has better planar and aromatic character than anthracene.

这主要是由于配体芘比蒽具有更好的芳香性和平面型,可以使探针Ru-2更好的与DNA结合,使荧光增强。

Therapeutics of certain and complementary sex, massage therapeutics and balmy therapeutics for instance, renascent to human body extensive force is very significant also, they can make the body is loosened adequately not only, and can make our physical ability times add, be inspired with enthusiasm.

某些互补性疗法,比如按摩疗法和芳香疗法,对人体恢复活力也极为有效,它们不仅能使身体充分放松,而且能使我们体能倍增、精神振奋。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明,在TBHP或O_2/TEMPO存在下,各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮,其中,配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛,而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差;在TBHP存在下,配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮,但对各类其它伯醇选择氧化的性能相对较差。

American Dupont NOMEX fragrant gathers the amide paper, it is (chromatographic analysis textile fiber and short fiber) is composed of two kind of shape aromatic polyamide polymer, uses the special papermaking or the system board method, agglutinates Cheng Jibo the fibrous reticulum, undergoes high temperature high pressure processing, carries on the densification and the calendering causes them reliable to fix lowly in the same place, becomes not penetrable, electrical and mechanicalness energy level high whole.

美国杜邦NOMEX芳香聚酰胺纸,它是是由两种形态的芳香族聚酰胺的聚合物组成,使用特殊的造纸或制板方法,粘合成极薄的纤维网,经过高温高压处理,进行密化和轧光使它们牢固低固定在一起,成为不可渗透的,电气和机械性能极高的整体。

Compounds 3a-3d, 4a-4d, 5a-5d, 6a-6e and 7a-7e were prepared with a new efficient method, in which the aromatic amines were diazotized with isoamyl nitrite in EtONa/EtOH under refluxing condition, and mono -, bis -and tetrakis -substituted calix [4] arenes were obtained respectively as main product by diazo-coupling in different molar ratio to calix [4] arene.

一,提出了一个有效的新方法合成含有芳香偶氮基团的杯[4]芳烃衍生物3a-3d;4a-4d;5a-5d;6a-6e和7a-7e:即在非水溶剂乙醇中用亚硝酸异戊酯,在强碱乙醇钠存在下对芳香胺进行重氮化,得到芳香重氮酸盐沉淀,过滤,然后加入杯[4]芳烃的四氢呋喃溶液,通入CO〓气体调节溶液的pH值为7-9,使其发生偶联反应。

It was found that both aliphatic and aromatic thiols promoted th photooxygenation process, leading to obvious decrease in an induction period of polymerization.

实验结果指出,芳香族和脂肪族的硫醇都能加速体系中的光氧化反应,使聚合反应诱导期缩短,芳香族硫醇对聚合反应的加速作?

The results indicate the mutual effect exists between the single coals, which could increase the maximum of thermal weight loss obviously and has a small effect on the temperature extent of the weight loss. The main pyrolysis production of coal is coke, but the main production of waste plastics is tar; the yield of water became decrease and the gas became increase by adding the waste plastics. And the CRI and CSR decreased with the ratio of waste plastics in coal. The main ingredients of tar from blend coal are aromatic hydrocarbon and alkane, while those of waste plastics are alkane and alkene. The result of co-coking with coal and waste plastics make the light tar and the aromatic hydrocarbon increase obviously. The combustible ingredient(CO、H2、CH4) of gas from co-coking with coal increase at different ratio; Co-coking with coal and waste plastics could increase the combustible ingredient and thermal value of gas.

结果表明,废塑料与煤混合物在煤的塑性温度区间内存在明显的相互作用,使最大热解失重峰迁移,热解速率变大,且随着废塑料配比的增加呈现规律性的变化;煤热解产物固体焦炭为主,而废塑料的热解产物以焦油为主,废塑料的添加使得总体焦炭和水产率下降,焦炉煤气和焦油的产率增加,即共焦化呈现出明显的&增油减水&效应;随着塑料添加量的增加,焦炭热强度呈现劣化趋势;废塑料代替瘦煤配煤炼焦可使其比例提高到3%而不影响焦炭的质量;纯煤焦化所得焦油以芳香烃类和烷烃类为主,而废塑料热解焦油以烷烃和烯烃为主;废塑料配煤炼焦,可使得的焦油呈现&环构化&和&轻质化&趋势;废塑料的添加可使煤气中的可燃组分(CO、H2、CH4)的含量均有不同程度的增加;废塑料配煤炼焦可以优化焦炉煤气的组成,增加煤气中的可燃组分,提高焦炉煤气的热值。

The results show that the torsion energy and van der Waals interaction energy are the main types of energy and the substitution group has a great effect on the total energy of molecular. The aliphatic substitution would lead to the increase of total energy, while the aromatic substitution would lead to the decrease of total energy. The calculated results of bond length show that the bond length of aliphatic C—C is longer than that of aromatic C—C, which indicates that the rupture of aliphatic C—C is easier than that of aromatic C—C on heating.

研究结果表明,扭转能和范德华能是分子中的主要作用力,取代基对体系能量有明显影响,烷基取代基使体系能量增加,而苯基取代基使体系能量降低;脂肪C—C键长比芳香C—C键长长,说明脂肪C—C在受热过程中比芳香C—C更容易断裂分解。

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