使碳化

The method will involve a sequence of ammonification of glass surface, functionalization of carbon nanotube surface, and bonding between the nanotubes.

将奈米碳管与其它材料以一定的比例复合而制备，进而形成一种具有奈米碳管之复合吸附材料所组成之固相萃取柱介质，其合成步骤包括：奈米碳管表面改质官能化，玻璃粒体之载体氨化及最后将两者经缩合剂作用而产生化学键结使奈米碳管批覆在玻璃粒体之载体上。

The method involves exposing the cells to a compound having the formula I in which: w is a nucleic acid x is a non-amino acid or non-peptide nucleic acid binding group y is a spacer having a chain length equivalent to 1-30 carbon-carbon single covalent bonds or is absent R4 is H or halogen or CH2O-R3; and R1, R2 and R3 are the same or different and are either hydrogen, methyl, ethyl, alkyl, alkenyl, hydroxylated alkyl, hydroxylated alkenyl groups or ether containing alkyl, alkenyl, hydroxylated alkyl or hydroxylated alkenyl groups optionally being an acyl group having a carbon chain length equivalent to 3-24 carbon atoms saturated or unsaturated, with the proviso that at least one of R1, R2 or R3 includes a group having a carbon chain of 3-24 carbon atoms saturated or unsaturated, or to a compound having the formula II in which: w is a nucleic acid x is a non-amino acid or non-peptide nucleic acid binding group y is a space having a chain length equivalent to 1-30 carbon-carbon single covalent bonds or is absent, R5 is alkyl, alkenyl, hydroxylated alkyl, hydroxylated alkenyl group or ether containing alkyl, alkenyl, hydroxylated alkyl or hydroxylated alkenyl group optionally being an acyl group having a carbon chain length equivalent to 3-24 carbon atoms saturated or unsaturated, with the proviso that R5 includes a group having a carbon chain of 3-24 carbon atoms saturated or unsaturated.

该方法包括使细胞暴露于具有式的化合物，在式中：w是核酸，x是非氨基酸或者非肽核酸结合基团，y是具有等于1―30个碳―碳单共价键的链长的间隔基或者不存在，R4是H或者卤素或者CH2O－R3；R1、R2和R3是相同的或者不同的并且是氢、甲基、乙基、烷基、链烯基、羟基化烷基、羟基化链烯基或者包含烷基、链烯基、羟基化烷基或羟基化链烯基的醚，任选地是来源于具有等于3―24个碳原子的碳链长的饱和或不饱和脂肪酸的酰基，其条件是R1、R2或者R3的至少一个包括具有3―24个碳原子的饱和或不饱和碳链的基团，或者使细胞暴露于具有式的化合物，在式中：w是核酸，x是非氨基酸或者非肽核酸结合基团，y是具有等于1―30个碳―碳单共价键的链长的间隔基或者不存在，R5是烷基、链烯基、羟基化烷基、羟基化链烯基或者包含烷基、链烯基、羟基化烷基或羟基化链烯基的醚，任选地是具有等于3―24个碳原子的饱和或不饱和碳链的链长的酰基，其条件是R5包括具有3―24个碳原子的饱和或不饱和碳链的基团。

Straw application, whether straw mulch or incorporated straw with soil, increased the content of soil labile organic carbon and incorporated straw with soil as more beneficial to the increase of the contents of hot water-extractable carbon, potentially mineralizable carbon acid-extractable carbon, readily oxidizable carbon, particulate organic carbon, and light fraction organic carbon.

表施秸秆和混施秸秆均能使土壤活性有机碳含量增加或显著增加，混施秸秆较表施秸秆更有利于热水提取态碳、可矿化碳、酸提取态碳、易氧化态碳、颗粒有机碳和轻组有机碳含量增加，而可溶性有机碳和微生物生物量碳的变化与秸秆施用方式关系不大。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

For TRO there are a little surfacatants whose effect are not good.In this paper,content of sulfonates and composition of alkyl are decided through right design ;under control reaction conditions different alkylbenzene sulfonates are synthesized;Polyreaction catalyst is developed .non-straight high carbon olefine are made through C9-C12 Polyreaction technolgy;clear composition alkylkenzene is sulfanated in falling-film reactor by SO,product can be adjusted,recipe of the surfacate can be used for super-low interfacialtension with Daqing oil -10-3-10-4mN/m,and stablity is good too.According to method issued by Daqing Develop and Explore Research institute,EOR is over 20% in natural core .

本文研究通过烷基苯磺酸盐组成的正确设计，确定了磺酸盐的当量范围和烷基碳数组成和分布；通过对烷基化条件控制，设计合成了不同碳数的直链和支链烷基苯及烷基二甲苯，并用于制备了相应的烷基苯磺酸盐；研制出了新型的烯烃叠合络合催化剂，采用C_9、C_(12)支链烯烃叠合工艺合成了更高碳数的支链烯烃，并进一步合成出相应的烷基苯和烷基二甲苯；以SO_3为磺化剂，通过对磺化条件的选择和控制，采用已知组成的烷基苯混合物进行膜式磺化反应，使合成工艺得以简化；所得磺酸盐组成确定并且可控，最终配方可与大庆原油形成超低界面张力，达10~3～10~(-4)mN/m数量级，且稳定性良好；以合成的烷基苯磺酸盐为主体形成了三元复合驱配方，室内驱油模拟实验表明，按照大庆研究院对复合驱体系活性剂的评价方法，在天然岩芯上的驱油效率在20％以上。

The enhance nient of the corrosion resistance laser dadoling of the CNTs/Ni60 coatings is due to that the reserved carbon nanotubes in the coatings segregate the corrosive medium and promote N-based alloy passivation, the formed phases of the carbide and the reserved carbon nanotubes homogenous distribution in the claddings resist die corrosion.

碳纳米管／镍基激光熔覆层耐腐蚀的原因在于熔覆层保留的碳纳米管使熔覆层更加致密，隔离了腐蚀介质，促进了镍基合金的钝化，从而提高了熔覆层的耐蚀性；同时，熔覆层中保留下来的碳纳米管和被分解的碳纳米管与金属基体形成碳化物，作为增强相均匀弥散在熔覆层中，它们的存在阻止了腐蚀坑的长大，因而蚀坑较小，耐腐蚀性得到提高。

To improve the quality of Ta Spinnerets with high hardness and alkali-proof corrosion,HFCVD is used to deposit crystalline diamond films with different sizes of grain on carbonized Ta spinneret s.

为改善钽喷丝头的品质，提高其硬度和耐碱腐蚀能力，利用热丝CVD制备不同粒径的金刚石薄膜，并通过对钽衬底的碳化处理，成功使之沉积于纯钽喷丝头表面，对纯钽喷丝头进行表面强化。

To improve the quality of Ta Spinnerets with high hardness and alkali-proof corrosion, HFCVD is used to deposit crystalline diamond films with different sizes of grain on carbonized Ta spinnerets.

为改善钽喷丝头的品质，提高其硬度和耐碱腐蚀能力，利用热丝CVD制备不同粒径的金刚石薄膜，并通过对钽衬底的碳化处理，成功使之沉积于纯钽喷丝头表面，对纯钽喷丝头进行表面强化。

Self cleaning , durable , high speed dynamic separation device smoothers grinding media movement to provide better separation result .

动态间隙式的分离装置，使用超高硬度的碳化钨合金，耐磨性特佳，高速转动的动片使珠子不易滞留，并具有自动清洗作用，确保分离效果。

The thesis are divided into two parts. In the first part, we used 2,4,6-trichloro-1,3,5-triazine as the precursor to react with sodium which have been achieved by decomposing sodium hydrate at 623 K. At a low reaction temperature of 623 K, carbon nitride nanosphere、porous carbon nitride material and byproduct sodium chloride, would be produced.

本研究将分成两部份，第一部分是在低温下(623 K)将氢化钠粉末热裂解，生成表面积较大的熔融态金属钠，使气态的氰尿醯氯通入与熔融态金属钠在623 K反应，生成奈米氮化碳球、奈米孔洞性氮化碳材料及副产物氯化钠。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。