使溴化

Take for the amount of test materials, precision that set, place beaker, unless otherwise specified, may be added 40ml of water and hydrochloric acid solution (1-2) 15ml, and then set on a magnetic stirrer, stirring allows the dissolved, together with potassium bromide 2g insert platinum - platinum electrode, it will insert the solution of the following buret tip is about 2 / 3, using sodium nitrite titration solution (0.1mol / L, or 0.05mol / L) rapid titration, side drops while stirring, to near point, Burette tip surface will be presented with a small amount of water leaching cutting-edge, lotion, and solution and continue titration slowly until the sudden deflection of galvanometer pointer, namely, titration end point.

取供试品适量，精密称定，放置烧杯中，除另有规定外，可加水40ml与盐酸溶液（1-2）15ml，而后置电磁搅拌器上，搅拌使溶解，再加溴化钾2g，插入铂-铂电极后，将滴定管的尖端插入溶液下面约2/3处，用亚硝酸钠滴定液（0.1mol/L或0.05mol/L）迅速滴定，边滴边搅拌，至近点时，将滴定管的尖端提出液面，用少量水淋洗尖端，洗液并溶液中，继续缓缓滴定，至电流计指针突然偏转，即为滴定终点。

The influence of each condition on the reaction speed and yield was studied, and the optimal conditions were: the ratio of the amount of substance of aromatic amine and heptafluoro-isopropyl iodine was 1:1.1~1.5, the amount of substance of sodium dithionite, sodium bicarbonate, aniline compounds were respectively 1.1~1.3, the amount of substance of phase transfer catalyst TBAB and aniline compounds was 0.05~0.1, the concentration of aniline compound was 0.5~1.0 mol/L, reaction temperature was 10~20 ℃, and the solvent was aether.

最佳结果为：芳胺与七氟异丙基碘的物质的量比1：1.1~1.5，连二亚硫酸钠、碳酸氢钠与苯胺的物质的量分别为1.1~1.3，相转移催化剂四丁基溴化铵与苯胺的物质的量比在0.05~0.1，溶剂总用量使苯胺浓度在0.5~1.0 mol/L；反应温度10~20℃；溶剂采用乙醚。取代基供电子性越强，反应时间越短，产率越高；氨基的对位优先反应，氨基的邻位较难发生反应；且七氟异丙基总是优先取代在芳环电子云密度较高的位置上。

Potassium bromide crystal s were effectively colored electrolytically with a lab-made electrolytic apparatus at 693 K by a DC 1 200 V voltage.

用自行研制的电注入装置，在693K温度下施加DC1200V电压、对溴化钾晶体进行电注入并使之有效着色。

Potassium chloride and potassium bromide crystals were effectively colored with 36 keV xenon ions.

用36keV氙离子注入，有效地使氯化钾和溴化钾晶体着色。

The invention discloses a dielectric hole-microhole composite material and synthesizing method in the inorganic porous material, adsorbing material and catalytic material technical domain, which comprises the following steps: adopting zeolite molecular sieve as raw material; reacting with sodium bisilicate solution under 30-60 deg.c for 10-300 min; disintegrating particle part of zeolite molecular sieve into piece with microhole structure; adding cetyl trimethyl ammonium bromide as molder; adjusting pH value of mother liquid to 10-12; aging 1-8h; adding in the high-pressure autoclave to do water heat synthesizing reaction at 80-130 deg.c for 24-72h; separating solid; washing; drying; sintering under 500-600 deg.c for 5-10h; obtaining the Si-Al porous material with dielectric hole and microhole composite structure.

本发明属于无机多孔材料、吸附材料和催化材料技术领域，涉及具有介孔-微孔复合材料及其合成方法。其特征是以沸石分子筛为原料，用偏硅酸钠的水溶液在30～60℃反应10～300分钟，使沸石分子筛的颗粒部分解离形成具有微孔结构的碎片，加入模板剂十六烷基三甲基溴化铵，然后调节母液pH值为10～12，老化1～8小时，然后加入高压釜于80～130℃进行水热合成反应。反应24～72小时后，分离出固体，水洗、干燥，然后于500～600℃焙烧5～10小时，得到具有介孔和微孔复合结构的硅铝多孔材料。本发明的效果和益处是所发明的合成方法可用于合成多种沸石结构和介孔结构的复合材料，所合成的材料经过质子交换可以具有较强的酸性，在吸附和催化领域具有广泛应用前景。

It is characterized by that firstly, preparing silver bromiodide flake microcrstalline emulsion, then utilizing silver halide solution to corrode core of silver bromide to prepare the invented hollow silver bromiodide flake microcrystal whose form is triangle or hexagon and whose surface possesses small holes and pits, and the core of the microcrystal is silver bromide and its external layer is silve bromidiode, its iodine content is 1-10 mol%, and the light sensitivity of the emulsion is greatly raised.

首先制备溴碘化银薄片微晶乳剂，再利用卤化银溶剂使溴化银内核腐蚀，制备成的中空溴碘化银薄片微晶呈三角形或六边形，表面上有小孔和凹坑，微晶的内核为溴化银，外层为溴碘化银，其碘含量为1―10mol％；无论从色盲乳剂，还是经光谱增感乳剂的感光度都有大幅度的提高。

The chemical structure of the product was characterized by means of the melting point and IR. The results show that tetraethylammonium bromide which was used as a phase transfer catalyst in this reaction had optimization effect on the interfacial diffusive reaction of BTC and PNP. Higher concentration of sodium hydroxide, lower temperature and a higher dosage of BTC produced a small amount of 4-nitrophenyl chloroformate, while lower concentration of sodium hydroxide and a lower dosage of BTC made reaction incomplete, which affected the yield.

结果表明，在碳酸二（4-硝基苯基）酯合成中使用的相转移催化剂四乙基溴化铵对受界面扩散控制的BTC气与对硝基酚钠反应有良好的相转移催化效果；氢氧化钠质量分数较低时，酚钠盐向溶有BTC的油相扩散速度较小，较高时会产生氯甲酸对硝基苯酯；温度较低、BTC量较高时，会产生少量氯甲酸对硝基苯酯，BTC用量较低会使反应不完全，这些都影响着收率。

Experts'research on the stability of water-based ink and process has been a preliminary study. Femandez and other matozoa of the discovery of water-based ink by electrostatic repulsion stability and space steric 's. Aromtics and gecol, and so on the surface of the plastic film studies indicate that water-based inks, join different types of surfactants can be effective removal of water-based inks, and Canadians zephiramine hexadecyl alkyltrimethylammonium can make the surface charge of carbon black particles.

国际学者差火性油墨的稳不退性和脱除工艺已举行了开端查究。femandez等发掘火性油墨的胶体稳不退性是由静电排不引力和不满答位阻效应成群不决的。gecol等差脱除塑料薄膜暗不天的火性油墨查究后暗示，参加差别种类暗不天活性剂均可灵验去除火性油墨，而且加人阳离子暗不天活性剂十六烷基不一甲基溴化铵可以使炭暗粒子暗不天电荷逆转。

The PEI grafted on the surface of nylon was modified by the alkyl halide such as bromohexane and iodomethane,to give high-molecular-weight antimicrobial quaternary ammonium salts.

尼龙6用4-溴丁酰氯活化，再与高分子聚乙烯亚胺在有机溶剂中进行反应，使PEI共价接枝在载体上，然后用卤代烷对接枝在尼龙6上的PEI进行烷基化反应，使其形成具有杀菌功能的高分子季铵盐，制备出尼龙树脂固定化的高分子抗菌杀生剂。

The nylon was activated with organic functional groups,and after that reacted with high-molecular-weight polyethyleniminein the organic soleent. PEI was grafted covalently on the surface of nylon. The PEI grafted on the surface of nylon was modified by the alkyl halide such as bromohexane and iodomethane,to give high-molecular-weight antimicrobial quaternary ammonium salts.

摘 要：尼龙6用4-溴丁酰氯活化，再与高分子聚乙烯亚胺在有机溶剂中进行反应，使PEI共价接枝在载体上，然后用卤代烷对接枝在尼龙6上的PEI进行烷基化反应，使其形成具有杀菌功能的高分子季铵盐，制备出尼龙树脂固定化的高分子抗菌杀生剂。

And discuss some key point of integrated management system design, include hazard identification and risk assessment and risk control in the occupational health and safety management, the measure of satisfaction target of customer, the flawlessness of law system, the integration of the integrated management system and enterprise standardization system, unify lead institution and work orgnization, integreted internal audit and integrated management review.

同时，论述了一体化管理体系构建中的几个主要问题，包括职业健康安全管理中的危险源辨识、风险评价和风险控制、顾客满意度的科学监测、法律、法规体系的完善、一体化管理体系与企业标准化体系的有机结合、统一的领导机构和工作机构、一体化的内部审核和管理评审。

Deepwater Taranaki is investigated for its petroleum potential, using all available seismic data tied to shallow-water wells.

运用与浅水井相关的现有全部震波探测数据考察了深海区塔拉纳基盆地的油藏前景。