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Meanwhile, the concentration of Pb,Zn and other heavy metals is rather high in the oxidation zone and decreasesdownward to levels that are unbelievably low for Pb-Zn mine tailings. Theseobservations suggest that heavy metals should be re-immobilized by secondaryminerals, rather than primary minerals, in the oxidation zone, and could be leachedout from suboxic environment due to low rate oxidative dissolution which preventsthe precipitation of secondary minerals in significant amount. Thus, cover scenarioswhich establish a suboxic environment beneath the cover layer might not always beeffective in preventing heavy metal release from mine tailings.Sequential extraction studies indicate that, in addition to heavy metal leaching,oxidation of the mine tailings increased the mobility of residual Zn, and Cu, while Pb remains immobile due to the formation of anglesite (PbSO4). Using the seven-step extraction technique developed by Dold (J. Geochem. Explor., 2003, 80: 55-68), galena dissolves in significant amount at step 2 most probably due to the strong complexing of Pb2+ by acetate, while other metal sulfides dissolve at step 6, which suggest that this extraction technique could not be used to evaluate the mobility of lead in natural environment

重金属含量均低于新鲜尾矿,但以硬化层中的含量最高(Pb、Zn含量分别为0.47%和0.93%),往下大幅度降低,表明尾矿风化过程中形成的次生矿物对Pb、Zn等重金属元素有较强的固定作用,而次氧化带的淋溶作用造成了金属元素的大量流失;(4)与新鲜尾矿相比,硬化层中铅的可迁移性大大降低,硬化层之下尾矿样品中铅的可迁移性也不同程度降低,这是由于硫化物氧化产生的硫酸根与尾矿中的铅反应形成铅矾(PbSO_4)的缘故;(5)氧化作用使尾矿中的zn、Cu等重金属的可迁移性不同程度地增大,其中对锌的可迁移性影响最大,铜的可迁移性与铁比较相似,铅则容易与硫化物氧化形成的SO_4~(2-)反应形成铅矾(PbSO_4);(6)为了减少尾矿污染和修复矿山环境,人们提出了各种不同的尾矿覆盖方案,本文的研究结果表明,这些方法不一定能够有效地阻滞污染元素的迁移。

The results show that the perfect strength can be obtained under oxygen partial pressure about 20% O2, overhigh or low oxygen partial pressure is unfavorable for recrystallization of Fe2O3, which causes a decrease of pellet strength. The original hematite will be transformed into magnetite on reduction firstly when carbon-burdened hematite pellet is roasted in oxidizing atmosphere, and then the magnetite will be oxidized to secondary hematite, which is more active than original hematite, therefore, the induration strength of pellet is able to be enhanced.

研究结果表明:内配碳赤铁矿氧化球团在接近空气配比(氧含量约20%,体积分数)的氧化性气氛中焙烧强度最大,氧含量过高或过低都会影响Fe2O3的再结晶,使球团强度降低;在氧化性气氛中焙烧含碳赤铁矿球团时,原生赤铁矿先还原为磁铁矿,磁铁矿再氧化成活性较高的次生赤铁矿,提高了赤铁矿焙烧固结性能和球团强度。

The test results showed that under low ambient temperature and aphotic storage conditions jet fuel exhibited good color stability.Oxidation reactions,such as photo-catalyzed oxidation and radical oxidation,were the main reaction mechanism of color degradation,and copper played an important role in catalyzing the oxidation reactions.Under static thermal stability testing condi...

试验结果表明,喷气燃料在较低温度、无光储存条件下具有很好的颜色安定性;氧化反应是导致喷气燃料颜色变深的主要反应机理;静态热安定性试验条件下,喷气燃料的颜色随氧化时间呈相对稳定的加深趋势;氧化铝吸附脱除了喷气燃料中的一些原有氧化抑制剂,使喷气燃料在较高温度、有氧条件下易于发生氧化反应;铜在喷气燃料氧化变色反应过程中具有明显的催化作用。

The analysis of thermal behavior and chemical structure show that the three main reactions do not initiate simultaneously. Dehydrogenization and cyclization reactions begin at the initial stage of stabilization, while oxidation reaction takes place on the precondition of cyclization reaction. Cyclization reaction has induction period that is influenced by temperature and heating rate.

热分析和化学结构分析的结果表明,预氧化过程中的三大主要反应并非同时进行,脱氢反应和环化反应从预氧化初期开始,而氧化反应需要以环化反应为前提条件,随后进行;环化反应具有一定的诱导期;在氧化性气氛中,首先发生脱氢反应,氧对环化反应起到了阻碍作用,使整个过程顺利可控。

The results show that the density of glass, glass transition temperature and thermal expansion coefficient increase with the increase of yttria content, and the chemical durability decreases with the increase of yttria content. The bend strength of glass increases from 53.52 MPa to 109.65 MPa when 1.80% Y2O3 is added into glass. However, with the content of yttria further increases to 6.84%, the bend strength is suspended about 110 MPa. Y2O3 acting as network modifies in the structure and makes the island-shape network unit repolymerization by the bonding of Ge-O-Y because of the decrease of non-bridge oxygens and strengthening of glass network structure.

结果表明:该系统玻璃的密度、玻璃转变温度和热膨胀系数随氧化钇含量的增加而升高,玻璃的化学稳定性随氧化钇含量的增加而下降;在玻璃中加入1.80%氧化钇后,玻璃的抗弯强度值由53.52 MPa增至109.65 MPa;继续增大氧化钇的含量至6.84%时,玻璃的抗弯强度维持在110 MPa左右;氧化钇的加入减少玻璃网络结构中非桥氧数量,使孤立的岛状网络单元重新聚合,增强玻璃的网络结构。

In order to explain the phenomenon, the process of activation sulfurization of LaCoO 3 in the presence of oxygen was studied by XPS, XRD and TEM methods.

在氧化气氛下预处理会产生更多的阳离子空位,从而使其CO高温氧化活性明显升高;在还原气氛下预处理会产生更多的氧离子缺陷,从而使其CO低温氧化活性明显升高[1] 。

The product has green-yellow fluorescence at excitation wavelength of 355 nm and emission wavelength of 478 nm, and the fluorescence intensity could be enhanced in the presence of acetone.

三、流动注射在线氧化荧光法测定氯普噻吨的的研究利用在硫酸介质中二氧化铅可使无天然荧光的氯普噻吨氧化而转变为在最大激发波长和最大发射波长分别为393nm和452nm的强荧光物质,而且丙酮对该荧光体系有强烈增敏作用的现象,建立了以醋酸纤维素固定化的二氧化铅作为固相反应器的流动注射在线氧化荧光法测定氯普噻吨的新方法。

First firing of raw materials are usually basic glaze frit, in the process of production need to add metal oxides, metal ions is also a special color of the enamel glaze color, or as a gel, or suspension-like particles of the dispersion or absorption of light and color, for example, cobalt oxide blue or purple, blue green copper oxide, cobalt oxide copper oxide mixture is significant blue, red cuprous oxide, nickel oxide in the potassium content of the glaze was red, in the sodium yellow glaze of green, if used alone was brown iron oxide, cobalt oxide and manganese dioxide are combined black or dark brown.

通常是先将原料烧成基本釉的熔块,在制作的过程中再加入需要的金属氧化物,也就是以金属离子特具的颜色而使珐琅釉呈色,或成为胶状,或悬浮状的粒子对光线的色散或吸收而呈色,例如氧化钴呈蓝或紫色、氧化铜呈蓝绿色、氧化铜混和氧化钴则显青色、氧化亚铜呈红色、氧化镍在含钾之釉中呈红色、在含钠之釉中呈黄绿色,又如氧化铁单独使用呈褐色,与氧化钴及二氧化锰合用则呈黑色或黑褐色。

By means of magnetically controlled reaction and sputtering process, metal tin is oxidized, and tin oxide film in nano level is formed on silicon chip and further oxidized and annealed to form the nano crystal particle tin oxide film. The nano crystal particle tin oxide film has the features of great specific surface area, homogeneous thickness, high surface smoothness, high sensitivity, high stability and others.

本发明采用磁控反应溅射方法使金属锡氧化,在硅片上生成锡的纳米量级氧化物薄膜,再进一步氧化、退火,即可制造出纳米晶粒氧化锡薄膜,该氧化锡纳米敏感薄膜具有氧化锡颗粒度小,比表面积大,厚度均匀等特点,且表面平整度高,在100倍显微镜下观察没有裂痕,有利于提高气敏传感器的灵敏度和稳定性,通过溅射时间严格地控制膜厚,可重复性高,适合于批量生产。

A method for the analysis of zinc oxide phase content in sulfide ore was studied. On the basis of the characteristics of each phase component, the sulfide ore sample was leached twice with NaOH and acetic acid-ascorbic acid, respectively, so that the oxide mineral and zinc oxide were dissolved completely. The leaching rate of zinc oxide phase was up to 98 Vo. Moreover, the dissolution of zinc sulfide phase was effectively inhibited, solving the problems of selective leaching and determination for zinc oxide.

研究了硫化矿中氧化锌相含量的分析方法,根据硫化矿中各物相组分特点,提出了用氢氧化钠溶液和乙酸-抗坏血酸溶液二次浸取硫化矿,使锌氧化矿、氧化锌充分溶解,氧化锌相的浸取率达到98%以上,同时有效地抑制了硫化锌相的溶解,较好地解决了氧化锌相选择溶解测定的问题。

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Fancy gold-plated dangling earrings with facetted White Opal crystals.

花式镀金悬垂耳环与facetted白欧泊水晶。

This essay chooses the study aim from biology teachers in middle school in Shi Jiazhuang which tells us that most of the middle school biology teachers in Shi Jiazhuang have the"burnout", lower successfulness, individualize.

本文选取石家庄市初中生物教师作为研究对象,运用问卷调查的方法对石家庄市初中生物教师职业倦怠的现状进行调查,调查结果发现,石家庄市初中生物教师这一群体普遍存在职业倦怠,情感枯竭程度偏高,成就感偏低,去个性化程度最为严重。

In measurements of a day,generallyspeaking,the photosynthesis of birch in mesophytic habitat is better than that in xerophytichabitat(peak values are 12.8,10.33μmolCO2m-2s-1 respectively);that of sexual birch inmesophytic habitat is better than that of clone birch(peak values are 9.87,6.71μmolCO2m-2s-1respectively);that of young tree is better than that of seedling(peak values are12.37,10.05μmolCO2m-2s-1 respectively).

在一天中的各个时刻,总体说来,中生生境生长的白桦光合作用超过旱生生境生长的白桦光合作用(净光合速率峰值分别为12.8、10.33μmolCO2m-2s-1);白桦幼树的光合作用超过白桦幼苗(净光合速率峰值分别为12.37、10.05μmolCO2m-2s-1);中生生境有性白桦的光合作用超过无性白桦的光合作用(净光合速率峰值分别为9.87μmolCO2m-2s-1、6.71μmolCO2m-2s-1)。