使氧化

The main object of this research is to investigate synthesis of Cu23Cl Cu and CuO nanoparticles through electrospinning and heat-treated method The research is mainly focused on preparative parameter and the change of heat-treated temperature to form the nanoparticles inlaid in silicon fibers the shape and color change are dicussed First of all to prepare the Polyvinyl butyral and silica dioxide complex nanofiber by electrospinning and then to investigate different heat-treated temperature and reactive time to being an influence on the products The results detected by SEM XRD TEM EDS FTIR combined sol-gel process and electrospinning can prepare Polyvinyl butyral and silica complex nanofiber The experimental result is found when heat-treated temperature is 100~4750C it can produce Cu23Cl nanoparticles; Above 4750C~ 4900C it can produce Cu nanoparticles; Above 450~7000C it can produce CuO nanoparticles And the viscosity is lain between 20~40cp and the sol-gel process time is 3hr it can produce the thinner fibers The average diameter of the fibers are 107 88±21 01nm;Due to the nanoparticles inlaid in the silica fibers the thinner fibers can be inlaid the smaller nanoparticles so this is the result that the experiment is expected To calcine the complex fibers is to produce surface silica fibers contain Cu23Cl Cu and CuO nanoparticles due to surface plasma resonance it make the color of the fibers become yellowish green from light white green turn into the red nuclear finally As the experimental result to utilize sol-gel process combine electrospinning can produce porous silica fibers contain Cu23Cl Cu and CuO nanoparticles

本研究旨在探讨「利用放电纺丝和热处理法来合成Cu23Cl、Cu和CuO奈米粒」之研究，实验著重在制备参数与热处理温度变化对所形成的奈米粒镶嵌在二氧化矽纤维中的形态与颜色变化探讨。首先，利用放电纺丝法制备出聚乙烯醇缩丁醛及二氧化矽之奈米纤维，比较不同的热处理温度与反应时间的改变对产物生成产生影响，进而研究不同热处理温度和时间对生成奈米粒的影响。产物经由SEM、XRD、TEM、EDS和FTIR等仪器分析结果显示，结合溶胶-凝胶法(sol-gel process)和放电纺丝法可产生聚乙烯醇缩丁醛及二氧化矽复合奈米纤维。实验结果发现，若热处理温度在100~4750C下可得到Cu23Cl奈米粒，475~4900C 可得Cu奈米粒，450~7000C以上可得 CuO奈米粒。而黏度介於20~40cp间和溶胶-凝胶时间为3hr时，可产生直径比较细的纤维，纤维直径为107 88±21 01nm；且由於奈米金属颗粒镶嵌在二氧化矽纤维中，直径比较细的纤维，可以得到比较小的奈米金属颗粒，这与实验预期相符。而锻烧此复合物产生多孔的二氧化矽纤维并包含Cu23Cl、Cu和CuO奈米微粒时，由於表面电浆子共震关系，而使纤维颜色由淡白黄绿色变成黄绿色，再变红褐色。由实验结果得知，利用溶胶-凝胶法(sol-gel process)结合放电纺丝法和不同热处理温度，可产生Cu23Cl、Cu和CuO奈米粒镶嵌在二氧化矽纤维。

On the NiO/SiO〓 catalyst prepared by IM, the main hydrogenation product of MA was SA, the activity and selectivity were almost no relation with the nickel content and nickel species 3. Summarizing the characterization and activity evaluation of the catalysts, we concluded: On nickel based catalyst, when NiO was crystallite, and the Ni〓 that was prepared by reducing, hydrogenation of the MA could lead to SA but not to γ-BL; when NiO was cluster and had a properly interaction with the support, the Ni〓 prepared by reducing, could hydrogenate MA to SA then to γ-BL. When NiO cluster and crystallite were both existed on the catalyst, the hydrogenation products were mixture of SA and γ-BL, and the amounts of SA and γ-BL were related with the ratio of cluster and crystallite.

综合催化剂的表征和活性评价得出：当镍基催化剂上氧化镍以结晶态存在，经氢还原后的零价镍可使顺丁烯二酸酐加氢得到丁二酸酐，丁二酸酐难以进一步加氢为γ-丁内酯；当镍基催化剂上氧化镍以簇团形式存在，与载体之间有适当的相互作用时，经氢还原后的零价镍可使顺丁烯二酸酐加氢得到的丁二酸酐进一步加氢为γ-丁内酯；若催化剂上氧化镍既有结晶态又有簇团形式时，随二者含量比例不同而得到丁二酸酐和γ-丁内酯的混合物。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

Oxidative bleaching by oxidation of its own to make a strong oxidation of colored substances were destroyed, so as to achieve the purpose of bleaching; food mainly used to restore the bleaching agent, mostly belonging to sulfurous acid and its salts, they are generated through the reduction of the role of sulfur dioxide can fruits and vegetables fade, it is widely used in food products such as bleaching and preservation.

氧化漂白是通过其本身强烈的氧化作用使着色物质被氧化破坏，从而达到漂白的目的；食品中主要使用还原漂白剂，大都属于亚硫酸及其盐类，它们通过产生的二氧化硫的还原作用可使果蔬褪色，因此广泛应用于食品的漂白与保藏等。

The present invention discloses a polycarboxylic acid copolymer which is obtained by copolymerization of monomer components comprising a polyalkyleneimine unsaturated monomer (A2) and an unsaturated carboxylic acid monomer, the polyalkylene glycol unsaturated monomer (A2) having an oxyalkylene group bonded to a polyhydric alcohol residue, and the monomer component containing an unsaturated monocarboxylic acid monomer.

公开了一种多元羧酸共聚物，它是通过单体组分共聚制得的，所述单体组分包括聚二醇不饱和单体(A2)和不饱和一元羧酸单体，所述聚二醇不饱和单体(A2)具有使氧化烯基结合到多元醇残基上的结构，所述多元醇残基平均每个分子具有不少于3个羟基。

Besides, the Tyr710Arg mutant produced two monocyclic products, achilleol A and camelliol C, and only the Tyr710Pro mutant lost the cyclase activity.

此外，在Tyr710Arg的突变株中也产生了两个单环的产物， achilleol A和camelliol C。而所有突变点中只有Tyr710Pro使氧化鲨烯环化酵素失去活性，且没有任何产物产生。

The lower oxidising power and reducing power of the of the available electrons and holes once transferred to the iron oxide phase, as suggested by Litter and Navio [9], can also be translated into lower photoactivity.

比较低的使氧化力量而且减少力量那可得的电子和洞一次转移到氧化铁状态，当做建议被垃圾和 Navio[9]，也能被转变为比较低的 photoactivity。

NM taurocholic acid at pH 5.5. The LES activity became sustained increase in basal tone withcaotic response after continuous perfusion of 20 nM taurocholic acid longer than1 hour, andfinally loss of response.

动脉注射substance P 抑制剂，可小幅减低下食道括约肌收缩。4nM 和20 nM 的taurocholic acid at pH 5.5 胆酸灌注会使氧化自由基产生些微增加。20 nM taurocholic acid at pH 5.5 约一小时后，基础食道压力上升且型态混乱不规则，对刺激反应呈疲乏。

The incorporating of heterogeneous atoms such as P and V or noncrystal materials results in structure changes of lithium cobalt oxide,therefore its reversibility during discharge and charge is improved.

引入杂原子磷、钒或别的非晶物，使氧化钴锂的结构发生变化，从而导致充放电过程中结构变化的可逆性提高。

POMs and deys are still maintained integrallty.AFM exhibits the films is even.The thickness of each layer is about 1.25nm. The AFM images reflect that there are some protuberances on the outer surface layer of the film, which due to the aggregates of spherical structure PMo12. Cyclic Voltammograms reflects the redox potentials of dye in multilayer shifts towards more positive values than pure dye multiplayer which may be explained by charge transfer from dye to POM. Fluorescence spectra show that polyoxometalates caused the fluorescence decay of dyes, which maybe used as fluorescence sensors.

UV-VIS说明复合膜均匀生长； IR 光谱、XPS能谱研究结果表明，紫外光照前后，膜中多酸/染料分子间没有发生显著的光化学反应，各组分的结构仍然保持；原子力显微镜显示，膜的外表面是均匀的，每一个双层厚度大约是1.25nm，膜表面的隆起，可能是多酸阴离子簇堆积所引起；循环伏安测定结果表明，由于多酸阴离子的影响，有机染料的氧化还电位发生了正的偏移，反映出复合膜中染料分子与多酸阴离子间发生了荷移相互作用，导致染料分子失去部分电子而使氧化性略强；荧光光谱研究结果表明，多酸阴离子可以有效地引发荧光染料的荧光淬灭，这为多酸在荧光传感器方面的应用提供了有价值的信息。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。