使氧化

A simple and highly sensitive new kinetic catalytic fluorimetric method was proposed for the determination of trace chromium,based on the catalytic effect of trace amounts of chromium on the oxidation of Pyronine Y by hydrogen peroxide in acetic acid-sodium acetate buffer medium leading to a decrease in the fluorescence intensity.

在HAc-NaAc缓冲体系中，痕量铬对过氧化氢氧化吡咯红 Y的氧化还原反应有催化作用，使吡咯红 Y荧光减弱，据此建立了催化荧光法测定痕量铬的新方法，同时考察了该催化反应的最优条件及动力学性质。

The deficiency of tetrahydrobiopterin（BH4）can lead nitric oxide synthaseto uncouple,can reduce the production of nitrogen monoxidum,increase the production of active oxygen,then generate a series of changes of function and structure in cardiovascular system.

四氢生物蝶呤(BH4)缺乏导致一氧化氮合酶脱耦联，使一氧化氮生成减少，活性氧生成增多，从而产生一系列心血管系统功能和结构改变。

At the same time, the scuttle structure of ablation shaped by the reverse process lead the layer of interest exposed to the air to suffer oxidation and infiltration of urania, which is favourable to interlayer oxidation and mineralization of uranium.

同时，反转作用形成的剥蚀构造天窗，使目的层裸露于地表，接受含氧含铀水的渗入和氧化作用，为层间氧化带及其铀矿化的形成创造了有利条件。

The results show that a little amount of heteropolymolybdovanadophosphate can remarkably speed the degradation, the best conditions of the oxidative degradation of chitosan with hydrogen peroxide catalized by heteropolymolybdovanadophosphate in homogeneous condition are as follows: the ratio of catalyst and chitosan is 1 to 10, concentration of hydrogen peroxide is 0.15%, the temperature is 80℃, reaction time is 2h. 0.2g chitosan was degraded under the best condition and the molecular weight by viscometry was degraded from 1460000 to 7812. then water-soluble chitosan was obtained by this method; The heterogeneous method is a high efficient way, the best condition of this method are as follows: the ratio of catalyst and chitosan is 2 to 100, the volume of 30% hydrogen peroxide is about 3mL, the temperature is 90℃, reaction time is 5min～30min.

研究结果表明，适量磷钼钒的存在可显著加速壳聚糖的降解，磷钼钒催化过氧化氢均相氧化降解壳聚糖的适宜反应条件是：催化剂与壳聚糖的质量比为1∶10、过氧化氢百分浓度为0.15％、反应温度为80℃、反应时间为2h，在此条件下对0.2g溶解在100 mL 0.5％稀醋酸中的壳聚糖进行降解，可使壳聚糖的粘均分子量由原来的146万下降到七千多(7812)，成为水溶性低分子量壳聚糖，从而达到应用的要求；在异相条件下以磷钼钒为催化剂催化过氧化氢氧化降解壳聚糖是一种高效快速的方法，此法降解壳聚糖的最佳反应条件是：催化剂与壳聚糖的质量比为2∶100；30％过氧化氢的用量为3mL左右；反应温度为90℃、反应时间为5min～30min。

The result shows the zymosis juice can redusebrain monoamine Oxidase activity by 28.1 percent(P.01),increase liver superoxidase dis-mutase activity by 10.67 percentP.

结果表明：香菇发醇液使脑单胺氧化酶活性下降28.1％（P＜0.01）；肝脏超氧化歧化酶活性增强10.67％（P＜0.05）：心肌脂褐素含量降低29.7％（P＜0.01）。

The first one is that the diene structure in Adda side chain was attacked and cleaved, which was named as Adda degradation pathway. The second one is that the pathway of Mdha and Ala degradation, which was that the peptide bond between Mdha and Ala was attacked and cleaved. Adda degradation pathway was dominant and mainly responsible for the degradation of MC-LR by ozone.

臭氧氧化的Adda途径是通过对MC-LR上Adda侧链的进攻，断开具有活性的Adda支链，而达到脱毒的目的；臭氧氧化的Mdha途径是通过对MCs肽环上面Mdha和Ala的断键，打开环状肽链，使藻毒素失去活性，在整个过程中Adda途径占主导地位。

The result showed that Ti02 nanowires with a diameter of 20 nm and a length up to several micron only can be synthesized in NH4F/glycol solution with a small amount of water (glycol: H20=39:1), 60V anodic voltage and 2h anodic time. The nanowires originated from the vertical splitting of anodically grown nanotubes.

结果表明，当醇水体积比为39：1时，60V电压下氧化2h，TiO2纳米管顶部的氧化层在缺陷处发生二次击穿溶解，产生自组装的孔核，场助溶解驱动力使纳米管顶部在孔核处沿管轴向垂直劈裂，形成直径20nm、长度可达几微米的TiO2纳米线。

Under supersonic condition Ce(superscript 4+) may oxidize sulfur compound such as benzothiophene in diesel fuel into sulfonea. By choosing a proper solvent to extract sulfonea, the sulfur content in diesel fuel is reduced from 554 mg/L to 25 mg/L with a desulfurization ratio of 95.5% and the sulfur content of diesel oil by oxidization is in line with the quality standard of diesel oil in World Fuel standard Ⅲ.

首次超声条件下使用Ce(上标 4+)氧化柴油中的硫化物，并把这类硫化物氧化成砜类化合物，再选用合适的溶剂将这些砜类化合物通过萃取方法除去，使柴油中的总硫含量从554mg/L降到25mg/L，达到了95.5%的高脱硫率。

Moreover,the selective oxidation of primary and secondary alcohols to corresponding carbonyl compounds with the multinuclear copper complexes Cul-Cu4 as catalysts have been conducted using TBHP and O_2/TEMPO,respectively.Among them,the copper complex Cu3 showed the best performance.On the performances of the two classes of oxidants,benzylic and heterocyclic alcohols could be effectively oxidized to carbonyl compounds.Specifically,the secondary alcohols could be effectively oxidized to ketones with excellent selectivity up to 100%in the presence of TBHP and the allylic alcohols could be effectively oxidized to aldehydes in the presence of O_2/TEMPO system.

实验结果还表明，在TBHP或O_2/TEMPO存在下，各配合物催化剂均能使各种取代芳香伯/仲醇以及杂环醇等以不同程度的转化率和选择性转化成相应的醛或酮，其中，配合物Cu3在O_2/TEMPO存在下可使苯甲醇和烯丙醇等以较高转化率和近100%的选择性转化成相应的醛，而对其它芳香醇和脂肪伯/仲醇等的催化性能则较差；在TBHP存在下，配合物Cu3则可使1-苯乙醇和其它仲醇以较高转化率和近100%的选择性转化为相应的酮，但对各类其它伯醇选择氧化的性能相对较差。

A method for eliminating the internal oxide structure in the gas-phase carbon-nitrogen osmosis of gear features that the CCL4 is added to the kensene as carburizer and then is decomposed to generate Cl2 for reducing the oxide, the ammonia gas as nitrizing agen passes through the cylinder of silica gel or granular calcium chloride for adsorbing residual water vapour and then through the cylinder of 5A molecular sieve for adsorbing residual O2, and the resistance wire is wound on igniting pipe at furnace top to prevent the NH4Cl in exhausted gas from being condensed.

本方法采用在气体渗碳剂煤油中，加入6～8％的CCl 4 ，使共渗炉内的CCl 4 分解出新生的Cl 2 ，使已形成的合金元素内氧化物还原；在渗碳剂氨气入共渗炉前，先经过硅胶瓶或桶及粒状氯化钙瓶或桶过滤，吸附掉氨气中的残留水蒸汽，再经过5A分子筛瓶或桶吸附掉氨气中的残留氧；在靠近炉顶位置的点火管周围缠绕带瓷环的电阻丝，靠电阻丝的副带加热，使排气中的NH 4 Cl不冷凝结块等措施实现内氧化组织的消除。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。