使成碳

The results indicate that the carbon and the oxygen in the —COOH group,and the nitron in —2—NH group come into formation of different large π bonds with the benzene rings,and there is a dihedral angle of 63.2° because of place blocking and conjugate effect.

结果显示，该分子羧基的碳氧原子、磺酰胺基的氮原子与苯环形成不同的离域大π键，空间位阻效应和共轭效应使两个苯环不在同一平面，二面角为63.2°。

By use of the Fischer-Tropsch reaction in a C-H-O system, we discussed the relationships between inorganic CO〓 and some physical chemistry conditions, such as Oxygen flee degree , temperature, pressure, other objects consistency and catalyzer. a when T=200K～2000K, if f〓＞0, the reaction of generating CO〓 will be dominant, CH〓 hardily exists; b when T＞1000K, CH〓 is not propitious to exist, carbon in system almost exists in form of CO〓; c the more pressure, the more CO〓 is propitious to exist; d the more consistency of CO, O〓 and H〓O, the more CO〓 is propitious to exist, the more consistency of H〓, the more CH〓 is propitious to exist.

依据C-H-O体系费托反应的简化模型，讨论了氧逸度、温度、压强、其它物质浓度、催化剂等物理化学条件对无机成因CO〓生成的影响，从理论上讨论了在地质环境中，无机成因CO〓存在的物理化学条件：1在T＝200K～2000K的温度范围内，体系中一旦氧逸度＞0，生成CO〓的反应将占绝对优势，CH〓几乎不可能存在；2T＞1000K时，不利于CH〓形成，使体系中的碳主要以CO〓的形式存在；3体系压强越大，越有利于CO〓的形成；4反应物CO、O〓、H〓O的浓度越高，越有利与CO〓的存在，H〓的浓度高有利于CH〓的形成。5地质成藏作用可以经历很长的地质年代，这足以补偿矿物岩石中的Ni、Mo、Fe、Co、Ru等催化性能的降低及其它动力学条件的不足，使得费托反应可能发生，从而生成无机成因的CO〓和烃类。

The Diels-Alder cycloadditions of [60] fullerene for preparation of optical limitingmaterials are discussed in chapter 3 and 6. Soluble cycloaddition derivatives of 〓aresynthesized by the reaction of 〓 with indene,1,1'-biindene andcyclopentadiene derivatives.〓Particular, the Diels-Alder cycloaddition of 〓 with1,1'-biindene under controlled conditions affords the stable monoadduct 〓〓of novel structure, which was confirmed by HPLC, FTIR, FD-MS,〓NMR,〓 NMR, HMQC and HMBC spectra, Its two bridgehead cage carbons resonate at70.91ppm, The 〓 NMR spectra showed 38 lines consistent with the 〓 symmetryassociated with [6,6] addition. The 〓 shows similar optical limitingproperties to that of 〓 in toluene for 8ns laser at wave length 532nm. Moreover, thehigh solubility of this adduct in polar solvents such as THF, acetone enables itsincorporation into sol-gel glass matrix. The thin films prepared via the sol-gel methodshow improved OL behaviour compared to those of 〓. The langmuir-Blodgett filmformation and uv-visible absorption of 〓 are also investigated. LBmonolayer of this compound is prepared on the air-water interface at 〓 mol/l. In chapter 4, three water-soluble derivatives of [60] fullerene: fullerol(1), theaddition product (2)of fullerol (1)with polyvinylpyrrolidone and fumaric acidderivative of 〓(3) are synthesized and characterized.

通过Diels-Alder环加成反应，用茚〓和1，1'-联茚〓及取代茂合成了一系列可溶性的〓环加成衍生物，发现可控制反应条件，使1，1'-联茚与〓反应，并高产率地得到具有新颖结构的单加成物，用HPLC、FTIR、FD-MS 及〓、HMQC、HMBC等多种波谱技术对其结构进行表征，测得它的两个〓杂化的桥头碳的化学位移为〓ppm，证明生成的衍生物为6∶6闭式环加成，〓NMR谱中共给出38个信号，表明〓联茚衍生物分子具有〓对称性；在波长532nm，脉冲宽度8ns的激光下，〓联茚衍生物的甲苯溶液的光限幅性能与〓的甲苯溶液相近，由于〓联茚单加成衍生物熱稳定性好，在四氢呋喃，丙酮等极性溶剂中溶解性好，能分别均匀地掺入溶胶-凝胶中，已发现它的溶胶(so1)光限幅性能优于纯〓的光限幅性能；使用Langmuir-Blodgett技术将〓联茚衍生物在空气和水的界面进行了LB单层膜和多层膜实验以及UV-Vis吸收谱研究，通过等温压缩曲线测试，证明浓度为〓〓时，〓联茚衍生物能够形成单层膜。

We have asked that all of the air hoses be switched from polycarbonate to polyurethane. This is because polycarbonates outgas hydro carbons, which contaminate the air mixture reducing power, and can also produce H20 which can damage the optics.

我们已经要求将所有空气软管从聚碳酸酯换成聚亚安酯，因为聚碳酸酯会和混合气体中的碳原子产品反应，这们会使混合气体所产品的激光功率下降，同时会生成H20原子损坏聚焦镜。

The results show that the perfect strength can be obtained under oxygen partial pressure about 20% O2, overhigh or low oxygen partial pressure is unfavorable for recrystallization of Fe2O3, which causes a decrease of pellet strength. The original hematite will be transformed into magnetite on reduction firstly when carbon-burdened hematite pellet is roasted in oxidizing atmosphere, and then the magnetite will be oxidized to secondary hematite, which is more active than original hematite, therefore, the induration strength of pellet is able to be enhanced.

研究结果表明：内配碳赤铁矿氧化球团在接近空气配比(氧含量约20%，体积分数)的氧化性气氛中焙烧强度最大，氧含量过高或过低都会影响Fe2O3的再结晶，使球团强度降低；在氧化性气氛中焙烧含碳赤铁矿球团时，原生赤铁矿先还原为磁铁矿，磁铁矿再氧化成活性较高的次生赤铁矿，提高了赤铁矿焙烧固结性能和球团强度。

Amino-2-methylpropanol was utilized as a chemical modifying reagent to modify carboxyl groups in unsaturated fatty acids into nitrogen-containing heterocycles, which effectively suppressed the migration of double bonds of the alkenyl within the electron impact source and led to regular informative mass spectra indicative of the position of the olefinic bonds in the chain.

以2-氨基－2-甲基丙醇为脂肪酸的化学修饰试剂，将不饱和脂肪酸羧基化学修饰试剂，将不饱合脂肪酸羧基化学修饰成含氮杂环，从而避免了链烯基中碳碳双键在EI源中的移动，并使质谱呈现显示双键位置的规范信息。

Zeta potential was -44.23 millivolt. Viscosity was 1.83 mpa. All of which were coincided with physical desire. In addition, the tests of PHGF liposomes including irritation, hemolysis, pyrogen, anomaly toxicity and hypersensibility, proved that the preparation reached the standard of intravenous injection entirely. Taking glutamic pyruvic transaminase and malondialdehyde in mice as index, studies on pharmacodynamics after hepatic injure caused by tetrachloromethane in mice indicated that GPT level (P.001) and MDA yieldment P

以小鼠CCli急性中毒性肝损伤为模型，以动物血清中谷丙转氨酶（GP水平与肝脏中丙二醛p A烨成量为指标，进行PHGF脂质体的药效学试验，结果表明P＊＊F脂质体能显著降低GP T水平o＜0刀01）与MD A 生成量厌＜o.05）；大鼠组织形态的观察表明高剂量＊＊＊F脂质体能使肝脏 0 内皮细胞增生活跃，提高肝细胞的免疫功能，对受损肝细胞具有修复作用；同样小鼠碳廓清试验也显示PHGF脂质体较市售粉针具有更好的机体免 p 疫作用o功刀01），达到制剂设计目的，获得较好的结果。

The biometallogenesis system of Jinya gold deposits consists of the following procedure: pre-concentration of gold and metallogenic matter in living organisms in Luodian-Danchi rift depositional basin; solution, absorption and concentration of metallogenic matter in organic matter and organic thermal fluid generated from organisms during lithogenesis; migration of gold and metallogenic matter in organic fluid from basin to Lingyun underwater carbonate platform and concentration at its boundary convex (palaeo-blind-mountain) during basin compaction ; metallization due to depth thermal fluid making organic fluid thermal degradation and forming new fluid which riches in gold and sulfur, and the fluid migrating upward and depositing in upside ore-controlling structures because of absorptions by organic carbon and atc.

通过研究金牙金矿作用的生物成矿系统内容为：在早、中三叠世罗甸—丹池裂谷盆地接受沉积时，生物对金等成矿物质就存在预富集作用；在成岩过程中，生物转化为有机质及有机热流体，对生物及沉积物中的金等成矿物质存在溶解、萃取、富集作用；在盆地压实成岩作用中，盆地中有机热流体向凌云水下碳酸盐台地运移，并在台地边缘外凸部位集中，此过程流体携带大量成矿物质，对金等成矿物质存在迁移集中作用；深部热流上侵使有机流体发生降解和释放金的热作用、形成高含金的有机热液，含金热液上移在构造通道中沉积并被有机碳再次吸附，最终形成金矿床，对金存在成矿作用。

The invention relates to a pipeline polyurea outer anticorrosive coating and the making method thereof, making heated prepolymerization reaction on dibenzo-methane diisocyanate, carbodiimide diisocyanate, polyether binary alcohol and polyether trihydric alcohol to prepare prepolymer solution A, and making end amino polyethylene oxide ether, dimethyl sulfur-based toluene diamine, diethyl diamine, iso-propyl titanate solution, polyacrylate, carbon black, titanium dioxide and lightweight calcium carbonate into solution B, and as using, respectively heating the solutions A and B to 65 deg.C and then mixing them, then quickly spraying and curing to form a coat.

本发明涉及一种管道用聚脲外防腐涂料及制造方法，由二苯基甲烷二异氰酸酯、碳化二亚胺化二异氰酸酯、聚醚二元醇和聚醚三元醇通过加热预聚反应制成预聚物的A液、由端氨基聚氧化乙烯醚、二甲硫基甲苯二胺、二乙基甲苯二胺、钛酸异丙酯溶液、聚丙烯酸酯溶液、碳黑、钛白粉和轻质碳酸钙配制而成的B液组成，使用时将A液和B液分别加热至65℃后混合，然后快速喷涂固化形成涂层。

The results showed that the addition leading to -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 7 could proceed with good diastereoselectivity and excellent yield (95%).(3) The selective N-deprotection of -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 2 without affecting the vinyl group in the substrate were untaken.(4) The Zip reaction for the transformation of -1-(3-aminopropyl)-3-methylazecan-2-one 8 to -7-Methyl-1, Sdiaza-cyclotetradecan-6-one 9 were undertaken. The results showed that, under controlled conditions, acceptable yields (43%) could be achieved and racemization can be minimized during the ring expansion reaction.

该合成路线与文献方法相比，反应条件较温和，也缩短了反应时间；(2)哌啶衍生物2与乙烯基格氏试剂进行加成反应的条件和立体选择性，取得了较好的结果（差向异构体比为80：20，产率95％左右）；(3)不饱和哌啶衍生物7在不影响碳碳双键的情况下去除苯基甘氨醇手性辅助基的条件；(4)具有羰基α位手性的氨基酰胺8在不同条件下经Zip重排反应转变为9的反应，控制反应条件，可使反应中消旋化减小到最小的程度。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。