使成碳

To burn to carbon; carbonize.

将…烧成碳，使碳化

Spheroidizing is the process of producing a structure in which the cementite is in a spheroidal distribution.

球化是使渗碳体产生成类似球状分布结构的工艺。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

Organozinc reagents can react with a variety of α,β-acetylenic ketones and aldehydes in the absence of any catalyst. The one-pot reaction affords β-branched Baylis-Hillman type adducts, the multifunctionalized alkenes, in excellent yields with high stereoselectivity.

这种顺式亲核加成反应的发生是由于该类有机锌试剂既具有较强的亲核性，又具有Lewis酸的特性，使有机锌中R基团从同位进攻中心碳原子而形成新的碳碳键。

Template-confined growth is a very powerful method for obtaining aligned 1D nanomaterials with adjustable diameter, length and morphology. Porous anodic aluminum oxide templates with different channel structures have been synthesized in our lab, with which the aligned CNT arrays, Y-branching and novel dendriform CNTs have been obtained. Based on the structural characterization of the products, a space-limited and self-catalytic growth mechanism has been proposed accordingly. Roughly speaking, the catalyst particles at the bottom of template channels initiate the nucleation of carbon species, which acts as the seed for subsequent CNT growth.

本文采用近年发展起来的模板控制生长法，以多孔氧化铝模板控制CVD生长的方法调控了碳纳米管有序阵列、γ-分叉及树枝状分叉结构，在对产物进行详尽结构表征和分析的基础上阐述了氧化铝模板控制生长碳纳米管的生长机制：孔道内催化剂仅在生长初始阶段催化碳物种的成核，起&种子&作用，随后模板孔道自身的催化及限域作用使碳纳米管紧贴着孔道内壁生长。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

Although benzene is often represented with alternating single and double bonds between carbon atoms, the electrons in the bonds are shared or delocalized in such a way as to make all carbon-carbon bonds alike .

虽然往往把苯描绘成碳原子之间按单、双键交替排列，但事实上键中的电子是共享的，或者说是非定域的，其结果是使所有的碳原子都是等同的。

Although benzene is often represented with alternating single and double bonds between carbon atoms, the electron s in the bonds are shared or delocalized in such a way as to make all carbon-carbon bonds alike.

虽然往往把苯描绘成碳原子之间按单、双键交替排列，但事实上键中的电子是共享的，或者说是非定域的，其结果是使所有的碳原子都是等同的。

Although benzene is often represented with alternating single and double bonds between carbon atom s, the electrons in the bonds are shared or delocalized in such a way as to make all carbon-carbon bonds alike.

虽然往往把苯描绘成碳原子之间按单、双键交替排列，但事实上键中的电子是共享的，或者说是非定域的，其结果是使所有的碳原子都是等同的。

The enhance nient of the corrosion resistance laser dadoling of the CNTs/Ni60 coatings is due to that the reserved carbon nanotubes in the coatings segregate the corrosive medium and promote N-based alloy passivation, the formed phases of the carbide and the reserved carbon nanotubes homogenous distribution in the claddings resist die corrosion.

碳纳米管／镍基激光熔覆层耐腐蚀的原因在于熔覆层保留的碳纳米管使熔覆层更加致密，隔离了腐蚀介质，促进了镍基合金的钝化，从而提高了熔覆层的耐蚀性；同时，熔覆层中保留下来的碳纳米管和被分解的碳纳米管与金属基体形成碳化物，作为增强相均匀弥散在熔覆层中，它们的存在阻止了腐蚀坑的长大，因而蚀坑较小，耐腐蚀性得到提高。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。