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Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80~100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100~300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能,且合金内的V元素会向表面富集,因此,钛合金真空热处理和表面涂层的烧结温度不能过高,即应低于其相转变点;通过对生物活性梯度涂层的组成和结构的设计,分析和计算了梯度涂层内的应力大小和分布,结果表明:对于本研究,当成分分布系数n=1.5时,可以获得较合理的涂层力学性能,即在沉积开始时,采用富含BG颗粒的悬浮液,以便在钛合金侧获得同底层BG有良好过渡的富BG涂层;梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定,改变成分分布系数,只能改变涂层内应力变化的趋势;涂层的厚薄不影响涂层内的应力分布规律,但涂层越薄,涂层内的应力变化越快,但这并不意味着涂层越厚越好,因为涂层越厚,涂层允许的变形越小,对于应用于弯曲受力部位的涂层而言,涂层应薄一点为好(50μm);而对于仅纯受剪切应力的部位,如牙根种植体,涂层可适当加厚(80~100μm);通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现,它们在水溶液体系中很难发生电沉积;在无水乙醇溶液中,HA颗粒带正电,可在阴极钛合金片上发生均匀的电泳沉积,而BG颗粒则带负电荷;利用复分解反应法,可以制得100~300nm的HA,通过诱导HA在BG颗粒表面结晶,可对BG颗粒进行表面包覆,获得了被HA包覆的BG颗粒,改变了BG颗粒表面的带电特性,使BG和HA颗粒在无水乙醇中均带上正电荷,从而实现了HA和BG颗粒在阴极上的共沉积。

Also the phase transition temperature from hexagonal ZnTiO_3 phase to cubic Zn_2TiO_4 was lowed by adding V_2O_5. It was noticed that V enriched in the boundary of the exaggerated grains, while not be detected in the inner of exaggerated grains or in the boundary of small grains. At sintering temperature 50℃, orthotitanate phase Zn_2TiO_4 in zinc titanate ceramics with ≤1.00wt% WO_3 additions became major phase, while zinc metatitanate ZnTiO_3 became major phase with ≤1.00wt% WO_3 additions.

结果表明:单独掺杂V_2O_5和WO_3有效降低了陶瓷烧结温度,900℃烧结的掺杂0.75wt%V_2O_5钛酸锌陶瓷密度可达理论密度的96.1%,930℃烧结的掺杂3.00wt%WO_3钛酸锌陶瓷的密度达理论密度的95.2%;V_2O_5的添加使六方相ZnTiO_3的分解温度从900℃降到了850℃以下,V_2O_5富积于陶瓷体的晶界处,在V_2O_5富积区附近产生了异常长大的晶粒。

In the present communication, a modification of the combustion method for the microdetermination of carbon and hydrogen was described, in which the sample was covered with the thermal decomposition product of AgMnO_4 and the combustion tube was filled with the same reagent.

用高錳酸銀热分解产物复盖在試样上进行灼烧和用同一試剂作固定填充剂并采用較高的氧气流速能使有机物在三分钟內氧化完全。为闡明燃烧过程,故比較本法、Krbl法和套管热分解法所产生的二氧化碳热导曲线。

In the mean time, it benefits microorganism decompose organic matter, aged algae, uneaten food and other hazardous substances; transfer them to new nutrient elements then re-promote the sustained and steady growth of monoplast algae; supply fish, prawn seedling sufficient natural live food; improve survival ratio and growth rate of fish and prawn seedling, cut down the cost of cultivation etc.

该产品为浮游单细胞藻类提供均衡且全面的营养元素,使单细胞藻类快速生长;同时,有益微生物分解有机质、老化的藻类及残饵等有害物质,转化成新的营养元素循环提供单细胞藻类持续稳定的生长;为鱼、虾幼苗提供充足的天然活饵料,从而提高鱼、虾苗的成活率及生长速度,降低养殖成本等。

Six bacteria and five mildews have been separated from 119 strains, wliich grew well on the culture media contained lignin. The result of taxonomic identification is that XI, X2 and X3 belong to Pseudomonas, X4 and X5 belong to Xanihomonas, X6 belongs to Mycoplana. A preliminary study has been carried out on the capacity of lignin degradation of the 6strains of bacteria, and strains X2 and X4 were chose to carry out the experiments. The most favorable temperature for the 2 strains is 30癈, and the pH is 7; After being treated by ultraviolet rays, activity of all the three kinds of lignin-degrading enzyme produced by the strains can be increased greatly, the bacteria increasing rate is remarkably improved.

从119个菌株中分离筛选出了6株细菌和5株霉菌,它们可以在含有木质素的培养基上良好生长:细菌分类学鉴定结果为X1、X2和X3:假单胞菌属,X4和X5:黄单胞杆菌属,X6:枝动杆菌属;对6株细菌降解木质素性能进行了初步的研究,选定X2和X4为实验用菌种,两株菌适宜的生长温度为30℃,最适初始pH值为7;经紫外线照射诱变法处理,可使它们产生的三种木素分解酶活性均有明显的提高,细菌增长速率比诱变前明显提高。

On the basis of composite solid propellants combustion model, we have modifiedthe surface structure factor of nitroamine propellants and a new function have be used tomodified the decomposition products of nitroamine according to predecessors researchfindings in combustion mechanism of nitroamine propellants, these work make originalmodel is indicated for a wide range of pressure and particle size.

2在原有的复合推进剂燃烧模型基础上,根据前人在硝胺推进剂及燃烧机理方面研究成果对硝胺推进剂表面结构因子f_进行修正,并引入ξ函数对硝胺的分解产物中的氧化性气体含量进行修正,使原有的燃速预估模型能适用于更宽的粒度及压力范围。

Through temperature、paracresol sodium salt concentration and the amount of BTC such as the study.

结果表明:酚钠盐浓度、温度以及BTC用量过高或过低,都会降低收率,其中温度较高会加速BTC的分解,而BTC用量较低会使反应不完全。

A new desulfurization apprach for pulverized coal combustion is introduced in this paper; pulverized coal is first burn in a precombustion furnace under oxygen deficient condition (about 30% air needed in boiler is provided for precombustion), in precombustion moust of sulfur in coal is decomposed and oxidized, and evolved, the sulfur evolved is trapped in a desulfurizing fluidized bed by calsuim, and then the char and gas are introduced to the boiler furnace for complete combustion.

本文提出了一种煤粉燃烧脱硫新方案,利用煤中硫优先氧化分解释出的原理,用少量的空气(大略为锅炉实际空气用量的30%),在一前置燃烧室中,使煤粉中硫的绝大部分被分解氧化,释放出来,释放出来的硫在脱硫流化床中被石灰脱硫剂脱除,未燃烧的炭粒与烟气再吹进锅炉膛中完全燃烧。

Results Results of security experiments and deodorization experiments confirmed that the compound fluid had strong abilities of oxidation and decomposition, which can oxidate or decompose the unpleasant substances with pungent taste, putrefactive odor, and stink, etc, even some materials harmful to human health. Results of deodorization was satisfactory.

结果 经安全性实验、消臭效果实验证实,复方松针消臭液具有很强的氧化能力,它可使具有刺激性、腐臭味、腥臭味等令人不愉快气味的物质,甚至是对人体健康有害的物质进行氧化分解,显示令人满意的除臭能力。

For the first time we synthesized nanoscale metal hydrides of lanthanum, neodymium, samarium, dysprosium, and ytterbium with high efficiency under mild condition by complexometric catalysis instead of traditional preparation at high temperature and high pressure. It is for the first time that we synthesized lanthanide organic compounds with catalysts or initiating agents at atmosphere and ambient temperature,and some of them are new compounds. Nanometric lanthanide metal powders are prepared by thermal decomposition of the compounds in vacuum. Differently from the traditional method, size of the products prepared by our method is less than 40nm, and the activity of the reaction is very high. They are pyrophoric at atmosphere. They can make some reactions without activity or low activity show extremely high activity .We investigated influent regulations of methods, conditions to scale and special surface.

我们首次成功地用络合催化等方法取代需在高温高压下进行的传统方法,在温和条件下高效率地合成出纳米尺寸镧、钕、钐、镝、镱的金属氢化物;首次在常压常温的条件下,通过催化、引发等方法合成镧系金属有机化合物,再将其真空热分解成功地制备了纳米尺寸的镧、钕、钐、镝、镱等金属粉末;与传统方法不同,这些方法得到的产品基本颗粒尺寸小于 40 nm,遇到空气燃烧,具有极高的化学反应活性,使原来活性很低甚至观察不到活性的反应大幅度提高反应速率和产率;考察了制备方法、制备条件等因素对晶粒尺寸、比表面积大小等的影响规律。

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