作用中心
- 与 作用中心 相关的网络例句 [注:此内容来源于网络,仅供参考]
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The fourth chapter analyzed into the internal relationships between the central town construction and the urbanization, the main content including the background analysis of the birth of central town, the role and function of central town in unbanization, the value and measures of developing suburb cental town and so on.
第4章分析了中心镇建设与城市化发展的内在联系,主要内容包括中心镇产生的背景分析、中心镇的特征与功能、中心镇在城市化中的地位与作用、发展广州市市郊中心镇的重要意义及方式等。
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The effect of tribology factors on bearing vibration is studied experimentally. AR model and WPT are used to processing the normal arid abnormal signals. The results are as follows:1. The vibration of ball bearings is caused by the tribology action of contact pairs of ball and ring races and has the essential of tribo-dynamics. Any factors affecting the tribology characteristics of contact pairs will affect vibration and noise of bearings consequently.2. Vibration characteristics of bearing keep almostly unchanged with the increasing of axial load expecting the increasing of nature frequencies. When radial load increasing with axial load unchanged, nature frequencies keep unchanged but some new vibration peaks appears in the spectrum.3. Vibration amplitudes are damped and nature frequency are enhanced with sufficient lubrication. Vibration and noise of bearings increase obviously and roar can happen and the contact surfaces scratch slightly under insufficient and unclean lubrication state. Bearing will be disabled in a few minutes without any lubrication.4. Bearing vibration is unstable under low speed. With the speed increasing, the vibration become stable and natural frequencies increase slightly but the amplitudes increase apparently.5. Bearing vibration can be excited only by some harmonics ofwaviness without lubrication and by all harmonics with lubrication based on the theoretical analysis.6. The nature frequencies of ball bearings decrease with the increasing sizes. When international clearance increasing, nature frequencies decrease in radial and increase in axial and angular and the amplitudes increase in radial and decrease in axial and angular. When the number of balls increasing, nature frequencies increase and amplitudes decrease. When the pitch diameter increasing, axial nature frequency increase and others nearly keep no change. When outer race groove curvature radius increasing, nature frequencies increase in radial and decrease in axial and angular and amplitudes keep no change in radial and increase in axial and angular. When inner race groove curvature radius increasing, nature frequencies decrease and amplitudes increase.7. The distortion in amplitude and frequency components of bearing vibration signals picked up by the present probe measurement method is founded and right conclusions cannot be achieved by the signals. When accelerometer is rigidly screwed with steel stud onto a flat outer surface of a ball bearing, vibration signal can be got without distortion and the reliability of research on bearing vibration is assured.8. AR model is suitable for large samples of bearing vibration signals, square root of length of samples can be used as the upper limitation of order determination and the FPE order selection criterion is effective. Many advantages of AR spectrum are founded over the classical based on FFT.9. Time-Frequency analysis is necessary for abnormal noise of ball bearings. WPT overcomes the principle shortcomings of STFT and proved to be a best tool to process the abnormal signals.
理论分析和试验研究表明: 1球轴承振动是钢球—滚道接触副中的各种摩擦学作用引起的,具有摩擦动力学的本质,任何对接触副的摩擦学特性有影响的因素都将对球轴承的振动和噪声特性产生影响; 2中心轴向载荷作用下,载荷增大使球轴承的固有振动频率升高,载荷越大同样的载荷增幅引起的频率升幅减小,足够大的中心轴向载荷作用下载荷的变化对球轴承振动的频率特性不会产生明显的影响; 3轴向和径向联合载荷作用下,径向载荷不大时球轴承振动的固有频率基本不变,但是可能引起变刚度激励的非线性振动,出现新的频峰,过大的径向载荷将使部分钢球脱离接触,使球轴承的振动和噪声呈现不稳定状态; 4润滑对球轴承的振动和噪声特性有重要的影响,良好的润滑对振动有明显的抑制作用,润滑不充分时,振动和噪声的水平会有明显增高,一定条件下还会激发接触副中的谐振,发出啸声,造成接触表面的伤害,无润滑干接触时,短时的运转就会损伤接触副表面,使振动和噪声迅速增大,并随时可能引发严重的磨损和卡滞失效;接触副润滑良好时,油膜的"刚化效应"使球轴承振动的固有频率有所提高,润滑剂中含有弥散性污浊时,振动的幅度总体升高,但弥散性污浊不会改变球轴承振动的频率特性;浙江大学博士学位论文:球轴承振动的研究 5低速时,球轴承振动的基本特征呈现不稳定状态,随着转速的提高,球轴承振动的频率特性趋于稳定,固有频率频峰升高; 6理论分析表明,干接触时钢球和滚道表面波纹度的某些谐波分量能激励球轴承的振动,振动的幅值与谐波幅值成正比,实际球轴承中钢球的分布不可能完全均匀,波纹度的激励作用会随时发生;润滑接触的分析表明,波纹度的任意谐波分量均能激励球轴承的振动; 7球轴承的几何和结构参数分析表明,球轴承尺寸越大,径向、轴向和角振动的固有频率越低;钢球中心圆直径增大,球轴承的径向和轴向振动的固有频率基本不变,角振动的固有频率有所上升,振动的幅频特性基本不变;径向游隙加大使球轴承的径向振动固有频率降低,轴向和角振动的固有频率有所升高,径向振动幅频特性的幅值升高,而轴向和角向降低;钢球的数量增多使球轴承振动的固有频率上升,幅频特性的幅值下降,径向振动的幅值下降最为明显;外圈沟曲率半径系数增大使球轴承径向振动的固有频率升高,轴向和角振动的固有频率降低,径向幅频特性基本不变,轴向和角向幅频特性幅值升高;内圈沟曲率半径系数增大使径向、轴向和角振动固有频率均下降,振动幅频特性的幅值均有升高; 8试验对比表明,传感器采用探针式安装时,由于探针接触副接触特性的影响,钡(量得到的球轴承振动信号有失真,采用专门设计和制作的试验球轴承,以固定式安装加速度计,首次测量得到了球轴承振动的真实信号,通过对振动信号的分析,验证了球轴承振动的理论模型; 9)基于时间序列分析的AR模型适用于大样本球轴承振动信号的分析,以样本长度的均方根值作定阶上界,FPE做判阶准则,给出的AR谱光滑,频率分辨率高,是球轴承振动分析的简便而可靠的手段; 10以时频域分析的小波包变换分析球轴承异音信号能够比较好地定位和聚焦异音发生的时间,时间间隔,频率范围,同样是球轴承振动分析的可靠的手段,可用作球轴承故障诊断技术。
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And the perfect Q-vector was applied to diagnose a heary rain process for August 3~5, 1996. The results showed that there were more advantageous using the perfect Q-vector, and suggested that the perfect Q-vector could clearly reveal the system development of the heary rain; the divergence center or line, the divergence field and the frontogenesis function field of the perfect Q-vector could be used to locate the heary rain area; the center magnitudes of the perfect Q-vector divergence field and the frontogenesis function field could be signified the intensity of the heary rain.
结果表明,完全Q矢量能较清楚地揭示暴雨天气系统的演变;考虑了湿过程的完全Q矢量在暴雨的诊断过程中显示了其更大的优越性;定性而言,完全Q矢量散度的辐合中心或辐合线、散度场和锋生函数场有助于确定暴雨的落区,暴雨区正好落在低层完全Q矢量散度场辐合中心和锋生函数场正值中心之间;定量而言,低层完全Q矢量散度场辐合中心和锋生函数场正值中心大小对暴雨强度有显著的指示作用。
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It is included that 4-5 types of active sites exist in the catalytic system and the active site produced polymer with low molecular weight is easy to be activiated while TEA is used as the cocatalyst. While TIBA, the active site produced polymer with high molecular weight and seldom active site produced polymer with low one is prone to be activiated. MAO tends to activiate the active site produced polymer with middle-level molecular weight. In TEA-TIBA catalytic system, TEA and TIBA activiate the corresponding active site and the weight of every active site gradationally varied with the change of the ratio of the two cocatalysts. And the activity of the active site produced polymer with high molecular weight is proportion to the concentration of TIBA.
发现:TEA作为助催化剂时产生低分子量产物的活性中心易于活化,且体系中具有活性的活性中心有4~5种;TIBA易于活化产生高分子量的活性中心,基本上不能活化产生低分子量产物的活性中心;MAO对产生中等分子量产物的活性中心活化能力较强;在TEA-TIBA混合物体系中,TEA和TIBA各自对活性中心的作用表现为明显的互补现象,各活性中心的相对强度随着两种助催化剂之间的比例改变呈现渐次变化,其中产生高分子量产物的活性中心的相对活性(来源:c5AB3fC论文网www.abclunwen.com)与TIBA的浓度有明显的正相关性。
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And then studies on the relevant theories of distribution centers to let everyone know comprehensively, including the concept of logistics and distribution, the concept and development process of distribution center, the classification and function of distribution center, as well as its role. Lately it gives detailed description on the relevant theories of location selection, including the principle and influencing factors of location selection, as well as the steps and general methods of location selection. Finally the paper sums up several methods commonly used at present.
更多配送的概念、配送中心的概念及发展过程、配送中心的分类、功能及其作用;然后研究了配送中心选址的相关理论,包括配送中心的选址原则、影响因素、选址步骤以及配送中心选址的一般方法等部分;最后总结了目前几种常用的选址方法,并在这些理论的基础上,建立了非线性混合0-1规划类型的多配送中心选址模型。
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The structural and photocatalytic properties of TiO〓 as well as surface acidity were greatly improved by sulfation. SO〓〓/TiO〓 solid superacid with Hammett constant Ho less than -12.14 was prepared by treating the TiO〓 with 1.0mol. L〓 sulfuric acid solution and then calcining at 450℃ for 3h. When compared to unmodified TiO〓, the SO〓〓/TiO〓 superacid catalyst exhibited higher anatase content, smaller crystal size, higher specific surface area, centralized pore size distribution, and the blue-shifted band edge of uv-vis adsorption spectra. Furthermore, the SO〓〓/TiO〓 superacid also showed excellent reaction activity and stability for CH〓Br photocatalytic decomposition even under the moist reaction conditions. The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.
研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。
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The apparent quantum efficiency of SO〓〓/TiO〓 was 10 times of that of TiO〓 catalyst for the photocatalytic degradation of bromomethane. Therefore, the SO〓〓/TiO〓 superacid catalyst is promising for practical application in environmental remediation.It was found that both L and B acid sites exist on SO〓〓/TiO〓 photocatalyst while only L acid sites on TiO〓 photocatalyst. On the basis of experimental results, the synergistic model of superacidic centers was proposed for SO〓〓/TiO〓 photocatalyst to explain the photocatalytic behavior and the mechanism of superacidifing effects, assuming that the adjacent L and B acid sites induced by SO〓〓 comprise cooperatively the superacidic center on superacid photocatalyst. The group cooperation of the superacidic center could strengthen the surface acidity, increase surface acid sites and the adsorbtion of O〓, promote separation of photogenerated electron-hole pair, enhance the interfacial transfer of charges and reversibility of water adsorption. Consequently the excellent photocatalytic activity, reaction stability and resistibility to humidity of SO〓〓/TiO〓 superacid photocatalyst may attributed to the group cooperated effect of the superacidic center on the photocatalyst.
研究结果表明:SO〓〓与TiO〓表面的结合为螯合式双配位结构;TiO〓光催化剂表面经H〓SO〓浸渍处理后,提高了表面酸性,改善了催化剂结构和光催化性能,当H〓SO〓浸渍浓度为1.0mol.L〓、烧结温度为450℃时,可制得SO〓〓/TiO〓超强酸催化剂(H〓<-12.14),其结构和光催化活性得到明显改善,与TiO〓相比,SO〓〓/TiO〓光催化剂的锐钛矿含量高、晶粒小、BET比表面积大、孔径分布集中、光谱吸收边蓝移,具有优异的光催化氧化活性、稳定性及抗湿性能,光催化降解溴代甲烷的表观量子效率比TiO〓催化剂提高了一个数量级,是一种有实际应用前景的高效光催化剂;由此提出了SO〓〓/TiO〓超强酸催化剂表面集团协同作用的超强酸中心模型,认为在SO〓〓/TiO〓超强酸催化剂表面,由SO〓〓诱导的相邻L酸中心和B酸中心组成了集团协同作用的超强酸中心,其集团协同作用显著地增强了催化剂表面酸性、增大了表面酸量及O〓吸附量、促进了光生电子和空穴的分离及界面电荷转移,具有可逆吸附水的性能,是SO〓〓/TiO〓超强酸催化剂具有优异的光催化氧化活性、很好的活性稳定性及抗湿性能的重要原因。
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Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.
XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现;3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布;4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒;5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明:1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致;2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响;3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。
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Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.
XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现; 3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布; 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒; 5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明: 1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致; 2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响; 3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。
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Home position shear tests of slope rock, point loading tests and indoor AMD simulation action tests in XingQiao concave slope had show shearing strength and coherence between body layers of quartz sandstone decrease by 13.2%~21.3% after attacked by AMD, the angle of internal friction between layers is decreased by 5.0%~7.5%, in general, AMD affects the rocks mechanical property at range of 60~100m interior the perpendicular slop. Data analysis shows: 1 The actions to slope are major focused on zone of weakness, shearing strength of slope foot and AMD centre are reduced by 52% and 64.7% separately. 2 The explosion stress wave of long distance field has obviously increasing influence to disturbance amplitude value of slope with increasing of the slope height and distance, the response of the top of slope and fault region are obvious as well as damage effect; the foot of slope is with smallest disturbance amplitude value, the disturbance amplitude value of the step close to free face is obviously bigger than the interior of slope. 3 With the coupling effect of the AMD and explosion loading, the stress distribution inside of slope mainly presents characters of explosion stress field; the area affected by AMD becomes a weak area of shearing stress.
新桥深凹露天矿边坡岩体的原位剪切试验、点载荷试验、室内模拟AMD作用试验表明:AMD蚀化后的石英砂岩,岩体层面间的抗剪强度和粘聚力减小的幅值约为13.2%~21.3%;层面间内摩擦角减小幅值在5.0%~7.5%之间;AMD一般影响垂直边坡体内部在60~100m范围内的岩体力学性质数值分析表明:AMD对边坡体的作用主要集中在弱化区域内,边坡体的底脚和AMD作用中心区域的剪切应力减少了52.0%和64.7%;(2)随着边坡体高度和距离的增加,远场爆炸应力波对边坡扰动幅值的增加趋势明显,边坡顶部和断层部位的响应突出,损伤效应明显;边坡底脚扰动幅值最小,临空面附近台阶的扰动幅值明显大于边坡体内部;(3)AMD与爆破荷载耦合作用后,边坡体内部的应力分布主要呈现出爆炸应力场的特征,AMD影响区域形成了一个剪切应力弱区。
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