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低聚糖

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CA-CTSs including N,O-carboxymethyl chitosan,N,O-1-carboxyethyl chitosan (N,O-1-CEC),N,O-2-carboxyethyl chltosan(N,O-2-CEC),N-carboxymethyl chitosan and N-1-carboxyethyl chitosan(N-1-CEC) are quaternized using active quaternary salts prepared in laboratory.5 series including 25 kinds amphoteric chitosans characterized with polymeric ampholyte,in which 24 kinds are synthesized firstly,are obtained, 2-Hydroxypropyl dimethylbenzyl ammonium N,O-(1-carboxyethyl) chitosan chloride (GDMBA-N,O-1-CEC) is hydrolyzed into serial low molecular weight GDMBA-N, O-1-CEC with acid as catalyst and microwave as assistant instrumentality innovately.

以合成的活性季铵盐改性了N,O-羧甲基壳聚糖、N,O-1-羧乙基壳聚糖(N,O-1-CEC)、N,O-2-羧乙基壳聚糖(N,O-2-CEC)、N-羧甲基壳聚糖和N-1-羧乙基壳聚糖(N-1-CEC)等羧烷基壳聚糖,得到5个系列25种具有两性高分子电解质特征的新季铵化羧烷基壳聚糖,其中24种为首次合成;创新提出以微波辅助酸催化的方法催化2-羟丙基二甲基苄基-N,O-(1-羧乙基)壳聚糖氯化铵(GDMBA-N,O-1-CEC)水解,得到了低分子量的GDMBA-N,O-1-CEC。

The compositions and FTIR spectral characteristics of hydrolysis product were studied using GC and FTIR. The results indicated that ASP3 is a kind of pectic polysaccharide which contained the main part of homogalacturonan fragments as "smooth regions" with galacturonic acid and rhaminose, and rhamnogalacturonan segments as "hairy regions" backbone. Galactose, arabinose, mannose and glucose were linked as arabinogalactan, galactan and arabinan, which were the mainly constitution of the branch.

实验结果表明,ASP3是一种果胶多糖,主要由光滑区和毛发区(富含中性糖侧链的鼠李半乳糖醛酸聚糖)两部分组成:GalA和Rha位于多糖分子的主链,由于Rha含量较低,大部分GalA相连形成半乳糖醛酸聚糖光滑区;Gal、Ara、Man及Glc位于多糖分子的支链,其中Gal以较高的聚合度与主链相连,Ara以还原性末端或低聚寡糖的形式与主链相连或与半乳聚糖末端相连形成阿拉伯半乳聚糖。

The results show that a little amount of heteropolymolybdovanadophosphate can remarkably speed the degradation, the best conditions of the oxidative degradation of chitosan with hydrogen peroxide catalized by heteropolymolybdovanadophosphate in homogeneous condition are as follows: the ratio of catalyst and chitosan is 1 to 10, concentration of hydrogen peroxide is 0.15%, the temperature is 80℃, reaction time is 2h. 0.2g chitosan was degraded under the best condition and the molecular weight by viscometry was degraded from 1460000 to 7812. then water-soluble chitosan was obtained by this method; The heterogeneous method is a high efficient way, the best condition of this method are as follows: the ratio of catalyst and chitosan is 2 to 100, the volume of 30% hydrogen peroxide is about 3mL, the temperature is 90℃, reaction time is 5min~30min.

研究结果表明,适量磷钼钒的存在可显著加速壳聚糖的降解,磷钼钒催化过氧化氢均相氧化降解壳聚糖的适宜反应条件是:催化剂与壳聚糖的质量比为1∶10、过氧化氢百分浓度为0.15%、反应温度为80℃、反应时间为2h,在此条件下对0.2g溶解在100 mL 0.5%稀醋酸中的壳聚糖进行降解,可使壳聚糖的粘均分子量由原来的146万下降到七千多(7812),成为水溶性低分子量壳聚糖,从而达到应用的要求;在异相条件下以磷钼钒为催化剂催化过氧化氢氧化降解壳聚糖是一种高效快速的方法,此法降解壳聚糖的最佳反应条件是:催化剂与壳聚糖的质量比为2∶100;30%过氧化氢的用量为3mL左右;反应温度为90℃、反应时间为5min~30min。

Objective:To produce low-sugar and high-moisture preserved pachyrhizus; Methods:The relationship of moisture and water activity, numbers of bacterial and mildew were researched. Then water activity was reduced by chitosans with different viscosity-average molecular weights; Results:The number of mildew was a major microbial index of quality-maintaining duration of product. The lower viscosity-average molecular weights of chitosans was, the more water activity reduced; Conclusion:When 9 kD molecular weight,...

目的:为生产低糖、高水分含量番薯果脯;方法:研究果脯中水分含量与水分活度的关系及细菌总数和霉菌数在保温试验中的变化,并采用不同黏均分子量的壳聚糖降低果脯的水分活度;结果:果脯中霉菌数是影响产品保质期的主要微生物指标,壳聚糖的黏均分子量越低,降低水分活度的幅度越大;结论:通过添加0.5%、9kD黏均分子量的壳聚糖,产品水分含量为20%、总糖为26%时,番薯果脯常温放置保值期达到12个月。

By the solution self-organization, two kinds of organic-inorganic complexes of phosphotungstic acid with chitosan and chitosans degraded were prepared.

本论文提出两种降解制备水溶性壳聚糖的新方法:(1)UV-H_2O_2联合制备水溶性低聚壳聚糖:(2)在壳聚糖-水异相体系中,磷钨酸催化H_2O_2制备水溶性低聚壳聚糖。

The results showed that the different molecular weight of the complexes of Chitosan with copperor zinc, the complexes of carboxymethyl Chitosan with copper and the low-molecular-weight iii complexes of sulfation chitosan with copper had excellent inhibition on Valsa mali. The low-molecular-weight complexes of chitosan with copper had inhibition on Botyosphaeria berengeriana. All of samples had no inhibition on Fusarinm oxysporium.f.sp.vasinfectum and Alternaria Solani under this test conditions.

结果 发现,不同分子量的壳聚糖 Cu、Zn配合物、羧甲基壳聚糖 Cu配合物及低分子量的壳聚糖硫酸酯 Cu配合物对苹果腐烂病菌有明显的抑制作用;低分子量壳聚糖 Cu配合物对苹果轮纹病菌有一定的抑制效果;所有配合物在试验浓度范围内,对棉花枯萎病菌和蕃茄早疫病菌均无抑制作用。

The effect of oligosaccharide sports drink which contains 20% glucose polymer and adequate concentration of electrolytes was tested.

用保龄宝公司一种含20%糖和适量无机盐的低聚糖饮料的饮用效果在人体实验中进行了观察。

To sports drink, adding oligosaccharide can enhance sugar intakes and improve supply of sport energy.

低聚糖用于运动中补糖可提高糖的摄入量,改善运动能量供应。

In October 2002 adopted the first soy protein isolate, soybean oligosaccharide export food hygiene Register; in February 2003 passed the ISO9001: 2000 international quality management system certification.

公司在2002年10月就率先通过了大豆分离蛋白、大豆低聚糖产品的出口食品卫生注册;于2003年2月通过了ISO9001:2000国际质量管理体系认证。

In addition, xylooligosaccharides could be determined by HPLC on Aminex HPX42A column exc...

研究表明,采用AminexHPX-42A糖柱是测定低聚糖的简便快速的好方法。

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