低聚反应

In this dissertation, two series of rare earth initiators: rare earth tri (2, 6-di-tert-butyl4-methylphenolate) and rare earth calixarene complex have been developed to ring-opening polymerize 2, 2-dimethyltrimethylene carbonate, trimethylene carbonate and ε-caprolactone at mild conditions. Both the polymerization features and mechanisms are discussed in details.

本论文为环碳酸酯、内酯的开环聚合开发了两类新型低毒性稀土催化剂：三(2，6-二叔丁基-4-甲基苯氧基)稀土配合物和对叔丁基杯芳烃稀土配合物，都可以在温和的反应条件下单组分引发2，2-二甲基三亚甲基环碳酸酯、三亚甲基环碳酸酯和ε-己内酯聚合，合成各种分子量的均聚和共聚材料，考察了催化剂结构、聚合条件等对聚合的影响，深入研究了聚合机理。

The grafting effect and mechanism was charac- terized by FTIR,The heat stability of unvulcanized and dynamical mechanical proper- ty of vulc- lcanizates of SBR and SBR-g- were tested by TG and DMA respectively. medium-resistance properties of SBR and SBR-g- vulcan- izates were also investigated.The results showed that addition of St accelerated GMA grafting onto SBR and control the decomposition of SBR. When the conditions were GMA/St/DCP was 8/4/0.3 and grafting temperature was 160℃.

结果表明，St对提高接枝率、抑制SBR的降解起到了积极的作用；SBR中聚丁二烯的α－H和双键共同参与了GMA/St熔融接枝反应；当SBR/GMA/St/DCP=100/8/4/0.3、接枝温度为160℃时，SBR的接枝率较高（23.78%），SBR–g–硫化胶的拉伸强度和撕裂强度比SBR硫化胶的分别提高了119%和27.4%；SBR–（GMA--co-St）未硫化胶的Tg比SBR未硫化胶的高，而耐热分解性能优于SBR未硫化胶；SBR–g–硫化胶在低温条件下的刚性增大、弹性降低、具有较低的内耗，在常温下的阻尼性能较高，但弹性性能保持较好；SBR–g–硫化胶的耐热稳定性以及耐非极性有机溶剂的性能优于SBR硫化胶。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

E The fractal and spherical particles exist favorably in the coarse fraction, while in the fine mode (0μm) are floccules formed by flocking fine particles together, containing crustal elements and mainly being silicates and aluminosilicates. f The content of Al, Si, Fe in TSP samples is higher than in PM〓, indicating an enrichment of these elements in coarse mode. g Compared with non-dust particles, the dust particles are more homogeneous in terms of morphology, particle size and composition. h Particles with irregular shape and well-distributed size dominate in dust samples, containing crustal elements such as Mg, Al, Si, Ca, Fe et al.

细粒中除小圆球外，大多为细小颗粒聚结在一起的不规则块状颗粒，主要含地壳元素，可能是硅酸盐和铝硅酸盐。fMg、Al、Si、Fe在PM〓中的含量较相应的TSP中的低，可见这些元素主要存在于较粗颗粒中。g沙尘期气溶胶粒子的形貌较非沙尘期单一、均匀，非沙尘气溶胶粒子的形貌、组分较沙尘期复杂。h沙尘期样品中，粒径均匀、形状不规则的颗粒最多，这些颗粒主要含地壳元素Mg、Al、Si、Ca和Fe等，是典型的由源区传输过来的沙尘粒子，但其高硫含量表明在青岛特殊的地理环境下，在粒子表面发生了硫的均相和非均相反应。

Low molecular weight liquid polyethylene glycols as a novel green solvent for organic reactions have been attracting great attention.

低分子量的液态聚乙二醇作为一种新型的绿色有机反应溶剂正受到人们的极大关注。

I plant Agent M-80 resin is a-methyl styrene as raw materials response received low-molecular-weight linear homopolymer.

我厂代理的M-80树脂是以a-甲基苯乙烯为原料反应所得到的低分子量线性均聚物。

The labia have now been sutured together almost completely.The drains and the Foley catheter come out at the top.

此刻阴唇已经几乎完全的缝在一起了，排除多余淤血体液的管子和Foley导管从顶端冒出来。

To get the business done, I suggest we split the difference in price.

为了做成这笔生意，我建议我们在价格上大家各让一半。