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The common building block of them was synthesized by firstly glycosylation of an appropriately protected glucose with diosgenin, then introduction of a rhamnosyl residue to the 2-OH at Glu, finally freeing the 4-OH at Glu by selectively benzoylation of 6-OH.

我们先将适当保护的葡萄糖接在薯蓣甙元上,然后选择性地保护葡萄糖的 3 羟基,在 2 上引入一个鼠李糖,接下来选择性地保护葡萄糖的 6 羟基,得到了上面三个皂甙的共同合成子。

The common building block of them was synthesized by firstly glycosylationof an appropriately protected glucose with diosgenin, then introduction of a rhamnosyl residue to the 2-OH at Glu, finally freeing the 4-OH at Glu by selectively benzoylation of 6-OH.

我们先将适当保护的葡萄糖接在薯蓣甙元上,然后选择性地保护葡萄糖的3羟基,在2上引入一个鼠李糖,接下来选择性地保护葡萄糖的6羟基,得到了上面三个皂甙的共同合成子。

The novel complex (1) in which both benzylic nitrogens and heteroaromatic ones to the same metal ion with the rigid ligand imposed by the large heteroaromatic moiety first time was synthesized; a 2: 1 (ligand: metal ions) type complex which has steric resistance and strong thermochemical driving force was obtained. The crystal structures of characteristic ligand (LA4) and complexes (4, 7, 10), in which one cell includes two moieties: there exist minute difference in coordinated bonds and angles despite the same metal ions with the same ligand, were obtained. It shows that several stable conformation in one complex cell.

首次合成了含邻菲罗啉的具有较大刚性的四氮配体中四个氮原子全部与同一金属离子配的配合物的晶体结构;得到了一个在空间上存在阻作用的配体与金属离子2:1结构的晶体;解析了具有特色的一个配体(LA4)和三个配合物(4、7和10)的晶体结构,其中的配体与金属离子的配作用显示出细微的差异,表明在同一金属配合物的晶胞中,可以同时存在着多个稳定的构象。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62),1,3-二-(2,6-二甲苯基)-4,5-二氢咪唑基1-苯亚甲基-(2,4-二甲基吡啶)-二氯合钌(63)中,邻取代的吡啶作为解离配体,通过邻基团的空间效应削弱钌-氮配键,使配体更易解离,提高了催化剂的初活性。

Boden said four of the five reviews were glowing and one really attacked the study.

Boden博士说到,五评议员中四正在讨论而一实际上批判了研究。

Boden said four of the fie reiews were glowing and one really attacked the study.

Boden博士说到,五评议员中四正在讨论而一实际上批判了研究。

Result: There were 29 eyes from 29 cataractous patients, 15 males and 14 females.

结果:29病人,15为男性,14为女性。

Complications included 8 patients with port-A system dysfunction, one with anterior spinal artery syndrome, and one case of cauda equine syndrome.

并发症包括8患者的port-A系统机能障碍,一有前脊髓动脉症候群、一马尾症候群。

RFA was undertaken percutaneously on an outpatient basis in 13 patients (25 lesions). The remaining patients underwent RFA via laparoscopy (21 patients; 58 lesions) or celiotomy (16 patients; 49 lesions); mean hospital stay was 1 and 5 days, respectively.

13病人(25个病灶)的采用经皮下植入的射频治疗,其他病人包括21病人(58个病灶)采用了腹腔镜下的射频消融手术和16病人(49个病灶)开腹手术治疗;平均住院时间分别为1和5天。

If a Savgha of bhikkhus comprising a chapter of even one less than twenty should reinstate that bhikkhu is not reinstated and those bhikkhus are censurable.

即使只差一个而不足二十的比丘僧团为这比丘出罪的话,这比丘未出罪,而且这些比丘应该被呵责。

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