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This flocculating agent has good water solubility. Dissolving rate is quicker than traditional synthesized flocculating agent such as poly-propionamide. It overcomes flaws of slow dissolving rate and inconvenient field using of traditional poly-propionamide; because of copolymerizing with natural product Amorphophallus konjac, it has advantage of strong natural product biodegradation. After be used, it do not cause secondary pollution. It can be used in process of city domestic sewage and industrial sewage.

本发明絮凝剂具有良好的水溶性,溶解速度比传统的合成类絮凝剂如聚丙酰胺类更快,克服了传统聚丙酰胺溶解速度慢,现场使用不方便的缺点;而且由于与天然产物魔芋胶共聚,同时具有了天然产物可生物降解性强的优点,使用后不易造成二次污染,可以应用于城市生活污水和工业废水处理中。

In order to facilitate the recycling of the useful components,the heavy by-product s in benzoic acid production were decolored by adsorption and distillation processes to remove the colored impurities such as crosslinking macromolecules and carbonized compounds.

为了有效去除苯甲酸重副产物中含有的交联大分子和碳化物等有色杂质,降低有用组分资源化处理的难度,分别采用吸附和蒸馏两种方法对苯甲酸重副产物进行脱色处理。

S:Dye intermediate—Hacid could be treated effectively by Wet Air Oxidation process and Catalytic Wet Air Oxidation process,all the Hacid was decompounded in 5 minutes and some intermediate products,sueh as NH+ 4,SO 2- 4,HCOOH,CH 3COOH and so on,were formed.

湿式氧化和催化湿式氧化都能有效地处理染料中间体—— H-酸。所有的 H-酸在 5 min内均被去除和形成一些中间产物。在不同反应时间段测定了 p H值及阴、阳离子和小分子有机酸等中间产物

Comparing with the result of methyl iodide in intense laser field, some differences are observed:(1) at the same laser field intensity, the highest charged fragment ion of methyl bromide was Br(superscript 3+), lower than I(superscript 6+) of methyl iodide;(2) the dehydrogenation channel was observed in the multiphoton dissociation or Coulomb explosion of methyl bromide, but was not observed in the case of methyl iodide;(3) HBr(superscript +) was observed, but there was no similar channel in the case of methyl iodide;(4) for methyl bromide, the valid charge distance of Coulomb explosion increases with the product of p and q; while in the case of methyl iodide, the distance remained almost the same;(5) the producing channel of CH(superscript + subscript m)(m=0, 1, 2) is different from the ionization-dissociation of methyl iodide in which the stepwise dissociation of CH3(superscript +) was thought to be the main channel, CH(superscript + subscript m)(m=0, 1, 2) of methyl bromide are mainly from the products of the direct dissociation of the dehydrogenated parent ions instead of the stepwise dissociation of CH3(superscript +).

与碘甲烷在强场中的实验结果对比发现:(1)在相同的激光场强下,碘甲烷电离解离的最高价碎片离子为I(上标 6+)而溴甲烷为Br(上标 3+);(2)溴甲烷质谱中存在母体离子的脱氢产物CHBr和CHBr(上标 2+),而对于碘甲烷,没有检测到这些通道,C-I键首先断开;(3)质谱中存在H^79Br和H^81Br,而碘甲烷的电离解离中不存在HI产物;(4)溴甲烷库仑两体爆炸的有效电荷间距随着两碎片电荷乘积的增大而增大,而对于碘甲烷此间距几乎不随电荷乘积变化;(5)CH(m=0, 1, 2)的主要生成通道可能与碘甲烷不同,不是来自CH3的顺序脱氢,而是来自脱氢母体离子的直接解离。

The crystal structure of the deoxygenating reaction product 1,1-dichlorotetraphenylcyclopentadienone of phenyl mercury with tetraphenylcyclopentadienone is reported.

本文报道了二氯卡宾(由一溴二氯苯基甲基汞产生)与四苯基环戊二烯酮脱氧反应产物的晶体与分子结构,并就其结构特征讨论了反应机理和产物的关系。

The reaction can be carried out in a non-aqueous solution and 4-aminopyridine can be diazotized with this method.

这个方法表现出如下优点:1),整个重氮化与偶联反应均在非水溶剂中进行;2),改变原料不同投料比,可以分别得到含有一,二,四偶联产物为主的反应产物;3),可以合成在酸性水溶液中不易重氮化的4-氨基吡啶的偶氮化合物。

In the liquid electrolyzing method, the solution of ammonia and oxydol were used as the reactants, and copper was used as the electrodes. Polynitrogen cluster N_(20) has been detected from the products.

在液相电解法中,以铜为电极,电解氨水和双氧水的混合溶液,反应6小时后,可以检测到产物中可能含有氮原子簇N_(20)的信号。6小时后,电流明显减小,产物中已无氮原子簇的信号。

The optimized configuration and electronic structures of reactants and products were studied by molecular orbital PM3 method.The reaction enthalpies ...

用半经验的量子化学PM3方法研究了反应物和产物的电子结构,得到了产物的最优构型和电荷键序分布以及反应焓变,讨论了反应中的电子效应和空间效应。

Methods: 2ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2ethyl5nitro aniline. The product was then synthesized to 3methyl6nitro1Hindazole by using ringclosing reaction in the presence of NaNO2, and then ethylated to obtain 2,3diethyl6 nitro2Hindazole. The latter compound was then reduced by SnCl2/Hcl to get target compound 2,3diethyl6nitro2Hindazole.

以2乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2乙基5硝基苯胺,后用亚硝酸钠关环得3甲基6硝基1H吲唑,经硫酸二甲酯甲基化得2,3二甲基6硝基2H吲唑,最后用氯化亚锡将其还原得到目标产物,通过1H NMR确定结构与目标产物一致。

Methods: 2-ethyl aniline was used as starting material of the synthesis and was processed by acetic anhydride acylation, strong nitric acid nitraction at low temperature, and desacyl synthesis to produce 2-ethyl-5-nitro aniline. The product was then synthesized to 3-methyl-6-nitro-lH-indazole by using ring-closing reaction in the presence of NaNO2, and then ethylated to obtain 2, 3-diethyl-6- nitro-2H-indazole. The latter compound was then reduced by SnC12/Hcl to get target compound 2, 3-diethyl-6-nitro-2H-indazole.

以2-乙基苯胺为原料经醋酐酰化、浓硝酸低温硝化及去酰基保护合成2-乙基-5-硝基苯胺,后用亚硝酸钠关环得3-甲基-6-硝基-1H-吲唑,经硫酸二甲酯甲基化得2,3-二甲基-6-硝基-2H-吲唑,最后用氯化亚锡将其还原得到目标产物,通过1HNMR确定结构与目标产物一致。

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