产物

The azo derivatives were hydrolyzed on the condition of alky to get end products. The structures of azo derivatives of 4-ASA and intermediate products were characterized by melting point, TLC, MS, FT-IR, 1H-NMR and 13C-NMR spectra properties in details.

本课题探索了一条4-ASA偶氮化合物的多步合成工艺，得到了目标产物三个，对合成的目标产物和中间产物用熔点、薄层色谱法、MS、FT-IR、1H-NMR和13C-NMR进行了详细的表征，确定了它们的结构。

The first step in the degradation is most probably the classical ester scission reaction to give a carboxylic acid and olefinic end groups. Further ester scission on the adjacent ester groups of carboxylic acid and olefinic molecular chains can then lead to the formation of lower weight pyrolytic products, such as: CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH and HOOCPhCOOH, and they can pyrolyze continually to produce substrate pyrolytic compounds, such as: HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓 and CO、CO〓. At the same time, a corsslinking cyclization reaction occurred of the formation of the gas products during the degradation of PET.

断裂大分子链端邻近羰基和乙烯基的酯键持续断裂，不断地形成小分子裂解产物，如：CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH以及HOOCPhCOOH，这些产物还会进一步裂解成分子量更低的小分子裂解产物，如：HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓以及CO、CO〓等，与此同时，一部分乙烯基酯端基的大分子链碎片会发生支化而相互连接，再经&链脱离&和环化反应形成难燃的交联产物。

To broaden desert shrub new utilizing fields, accelerate desert shrub developing to the direction of high added-value and high benefit, the paper studied on the liquefaction of Salix, Caragana and Poplar in the presence of Phenol under sulfuric acid catalysis. The optimum processing parameters for Salix, Caragana and Poplar liquefaction and resinification were investigated. The effect of molar ratio of formaldehyde to liquefied products and NaOH to liquefied products on the character and glue strength of liquefied products resin was studied.

摘 要：为了开辟沙生灌木资源新的应用领域，促使沙生灌木资源的利用向高附加值、高效益的方向发展，本文以苯酚作液化剂，以稀硫酸作催化剂对沙柳、柠条和杨木进行液化实验，分析了反应温度、液比、催化剂用量及液化时间对液化反应的影响；并研究了沙柳、柠条和杨木液化产物树脂化合成工艺和配方，分析了不同的甲醛与液化产物摩尔比以及氢氧化钠与液化产物摩尔比对沙柳、柠条和杨木液化产物树脂的各项性能的影响。

Database of physical and chemical properties for solid wastes were constructed through investigation for single typical component and their mixture of solid wastes. The particulate trajectory model and heat transfer model were developed, based on the studies of Characteristics of solid wastes movement and heat mass transfer in rotary kiln. Pyrolysis experiments of solid wastes in lab and pilot scale rotary kiln pyrolyzers were performed. Mechanism of pyrolysis for typical solid wastes was analyzed. The characteristics of pyrolytic products, such as physical and chemical properties, composition and combustibility, etc, were investigated. A neural network model for the prediction of yields and properties of pyrolysis products was developed. Then, the potential applications of pyrolytic products and the substitution of pyrolytic fuels for corresponding commercial furls were investigated. The optimization of energy recovery and utilization for different wastes through pyrolysis was analyzed.

通过对典型固体废物组分及其混合物特性的分析，建立了固体废物的化学特性分析数据库，并据此进行了物理分类；对固体废物在回转窑内的运动和传热特性进行了研究，建立了固体物料的随机颗粒滚动理论模型和传热模型；在小型和中试回转式热解炉上进行了实验；对各种典型固体废物在回转窑内的热解机理和主要热解产物的性质进行了研究；利用神经网络等方法建立了各典型固体废物的热解产物的产率及特性的数学预测模型；对固体废物热解产物的物性、成分、燃烧特性等开展了研究，分析了其与现有商业燃料匹配的可能性；对热解产物的多种应用性能进行了研究，对不同废物热解中的能源回收和利用进行了优化分析。

The polymerization of preparing PDA could be impacted by allyl chloride, allyl alcohol and allyl aldehyde. The content of allyl chloride, allyl alcohol and allyl aldehyde in the DMDAAC monomer solution varied from 0mg/kg to 1000mg/kg, their intrinsic viscosity of PDA descended from 10.3dL/g to 8.0dL/g, 6.8dL/g and 8.8dL/g respectively. The polymerization of preparing PDA could be carried out well in the case the content of NaCl, active carbon, yellow residua and low molecular polymer of DMDAAC were less than 10000mg/kg, 1000mg/kg, 1000mg/kg and 50000mg/kg respectively.

单一杂质含量变化对聚合产物PDA特征粘度影响的研究结果表明：在DMDAAC单体溶液聚合反应过程中，当Fe~(3+)、Fe~(2+)和Cu~(2+)含量分别达到7mg／kg、9mg／kg和5mg／kg时无法得到聚合产物PDA胶体；当烯丙基氯、烯丙醇、烯丙醛含量分别从0mg／kg增加到1000mg／kg时，聚合产物PDA的特征粘度从10.3dL／g分别下降到8.0dL／g，6.8dL／g和8.8dL／g；活性炭和黄色物质含量在1000mg／kg以下，低聚物含量在50000mg／kg以下以及氯化钠含量在10000mg／kg以下时产物PDA的特征粘度降低变化量不超过0.2dL／g。

This article summarises the chemical reactions in milk during heat treatment, analyzes the properties of several indicators for heat damage , such as heat-sensitive enzymes, denatured proteins, the products of Mailliard Reaction and isomerised lactose.

本文分析了牛乳在热加工过程中的化学变化，介绍了几种牛乳热损伤监控标识物(如热敏性酶类，蛋白质变性产物，美拉德反应产物和乳糖异构化产物)的特点，并详细论述了已有的牛乳热损伤监控技术：对变性β-乳球蛋白含量的监控，对糠氨酸和乳果糖含量综合水平的监控，对羟甲基糠醛含量的监控，以及以变性蛋白质(以色氨酸的荧光强度计，FTry)和美拉德反应荧光产物的聚集量为基础，评估牛乳热加工损伤程度的FAST方法。

Nanocrystalline copper tellurides Cu〓Te〓 and Cu〓Te〓 have been successfully prepared in ethylenediamine and ethylenediamine with hydrazine hydrate system under high-intensity ultrasonic irradiation at room temperature respectively. Nanocrystalline silver tellurides Ag〓Te and Ag〓Te〓 have been successfully prepared in ethylenediamine and ethanol system under high-intensity ultrasonic irradiation at room temperature respectively.

在制备碲化铜时，在纯乙二胺体系超声辐射所制备的最终产物为Cu〓Te〓，而在加有水合肼的乙二胺中制得的产物为Cu〓Te〓；在制备碲化银时，在乙二胺体系制备的产物为Ag〓Te，而在乙醇体系制备的产物为Ag〓Te〓。

But when Fe/D113 precursor is pyrolysed in the range of 400-700℃, the crystal structure of the iron particle is different. The products are mainly iron oxides andα-Fe as Fe/D113 precursor pyrolysed at 500℃, and as the pyrolytic temperature increases to the range of 600-700℃,α-Fe and Fe_3C are observed. Meanwhile, Al_2O_3、MgO、MgAl_2O_4 were observed in Al/C, Mg/C, Al-Mg/C which were prepared from D113 resin at 1000-1300℃.

而在同样的条件下热解载铁树脂(Fe／D113)，热解产物中铁的晶体结构与热解温度有关，400℃热解产物为铁的氧化物；500℃热解产物为体心立方结构的单质铁；600-700℃的热解产物为bcc单质铁和铁的碳化物(Fe_3C)。1000-1300℃热解含Al、Mg及Al-Mg的D113树脂制得的Al／C、Mg／C、Al-Mg／C材料中Al、Mg主要以Al_2O_3、MgO、MgAl_2O_4形式存在。

XRD and EDS analysis indicate that at static condition, the composition of the scale is CO3, while the scale changes to CO3 at dynamic conditions. The increment in flow rate increased the thickness of the scale remarkably, but had little influence on the hardness and Young's modulus of the scale. The fracture toughness of the scale exhibited the lowest value at the flow rate of 0.5 m/s whereas the adhesion strength increased with increasing the flow rate.

结果表明，静态条件下形成的腐蚀产物膜的主要成分为CO3，动态条件下的主要成分为CO3；介质的流动能够促进腐蚀产物膜的形成，但对膜的硬度以及杨氏模量影响不大；腐蚀产物膜的断裂韧性随着流速的增大先下降后上升，流动状态下内层腐蚀产物膜的致密性较好，膜与基体的结合强度较高。

A method for making Bisphenol A with a purity of more than 99.7% by reacting phenol and acetone using an acid catalyst, separating a BPA-phenol adduct by crystallisation and removing phenol from the adduct, in which involves continuous suspension crystallisation with a total dwell time of more than 4 hours in at least 3 crystallisers, by cooling first to 50-70 C in two parallel crystallisers and then to 40-50 C in a third crystalliser connected in series with the first two.; A method for the production of Bisphenol A with a purity of more than 99.7%, by reacting phenol with acetone in presence of an acid catalyst, separating a BPA-phenol adduct from the product mixture by crystallisation, filtration and washing, and removing the phenol from the adduct, in which stage involves continuous suspension crystallisation in at least three crystallisers connected in such a way that the mixture is first cooled to 50-70 C in two crystallisers in parallel and then cooled to 40-50 C in a third crystalliser in series with the first two, the total residence time of the mixture over all crystallisers being more than 4 hours.

描述用于生产纯度大于99.7％的双酚例如，双酚A(BPA的方法，这种方法包含苯酚和丙酮在有酸性催化剂参与的情况下反应形成一个包含双酚的产物混合物；通过结晶、过滤和洗涤从该产物混合物中以双酚/苯酚复合物的形式除去至少一部分双酚以提供双酚A/苯酚复合物晶体；并且从双酚/苯酚复合物晶体中除去至少一部分的苯酚以提供纯度大于99.7％的双酚；其中结晶过程包括连续的混悬液结晶，并且是在至少三个结晶装置中进行的，装置的排列使得产物混合物首先在结晶过程的第一阶段在第一个结晶装置和并联的第二个结晶装置中被冷却到50至70℃的温度，随后在结晶过程的第二阶段在与第一和第二个结晶装置下游串联的第三个结晶装置中被冷却到40至50℃的温度，并且其中产物混合物在结晶过程中的总驻留时间在4小时以上。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了