交酯

The area ratios of 980/1022, 980/1047,(980+1047)/1022 and 980/(1022+1047) cm^(-1) were decreased as the degree of acetification increased which indicated that acetification induced a decrease of crystallinity of starch. And the crystal structure changed from A-type to V-type. For the cross-linking of POCl3, the area ratios of 980/1022, 980/1047,(980+1047)/1022 and 980/(1022+1047) cm^(-1) were also decreased as the degree of cross-linking but the decrease was little compared to that of acetification. The result indicated that cross-linking of POCl3 had little effect on the starch crystal structure.

随着醋酸酯化取代度的增大，980/1022、980/1047、(980+1047)/1022和980/(1022+1047)的相对峰面积的比值均呈现下降趋势，表明醋酸酯化改性会导致淀粉结晶程度降低，结晶形态从A型转变为V型；随着交联度的增大，980/1022、980/1047、(980+1047)/1022和980/(1022+1047)的相对峰面积比值均呈现下降趋势，但下降程度较小，表明三氯氧磷交联对淀粉结晶结构影响不明显。

This experiment with dilute alkali swelling on collagen extraction and separation, then purified by gel from collagen, and then glutaraldehyde, carbodiimide, has three types of di-isocyanate cross-linking agent on the plastic recombinant protein molecules cross-linked, the final test of infrared spectroscopy analysis of the results of their cross-linking to determine the extent of the effectiveness of cross-linking cross-linking agent to have an initial understanding.

本实验用稀碱溶胀法对胶原蛋白进行提取与分离，接下来用凝胶层析纯化所得胶原蛋白，然后用戊二醛、碳化二亚胺、己二异氰酸酯三种交联剂对胶原蛋白分子进行重组交联，最后通过对红外光谱测试结果的分析，对其交联程度进行判断，对交联剂的交联功效有一个初步的了解。，谢谢。

Results showed that the monomer conversion increased slightly in the presence of the crosslinking agents The size of particles decreased slowh as the amount of cmsslinking agent increased.and the size distribution of the particles broadened at a higher amount of cmsslinking agent Divinyl benzene was more effective than ethyl glycol dimethyl methacrylate to make polymer crosslinked.During alkali treatment process,void latex particles can be obtained when no DVB or less than 0.5 wt％ of EGDMA was used,while muhihollow structure was generated when DVB or more than 1.0 wt％ of EGDMA was introduced.The volume expansion of the particles decreased with increasing the amount of emsslinkirlg agents.

结果表明，体系中加入交联剂后，单体转化率都有不同程度的提高；随交联剂用量的增加，乳胶粒粒径略有减小，交联剂用量较高时，乳胶粒粒径分布加宽；二乙烯基苯的交联效率稍高于双甲基丙烯酸乙二醇酯；不加入交联剂及EGDMA用量低于0.5%时，处理后乳胶粒呈空腔结构，加入DVB及EGDMA用量高于1.0%时，处理后乳胶粒呈多孔结构，并且乳胶粒体积增量随交联剂用量的增加而减小。

The effect of kind of crosslinking agents, the glyoxal dosage, the crosslinking reaction temperature and the crosslinking reaction time on films properties were discussed.

制备了低酯化度玉米淀粉醋酸酯(DS.2)/聚乙烯醇可降解复合膜，重点讨论了交联剂的种类、用量、交联反应温度及时间片复合膜力学性能和耐水性的影响。

Adding sugar to the three raw starch and their low cross-linkedsuccinylated starch,the viscosity and thermal paste viscosity were rised eventually; addingcitric acid, lactic acid and sodium chlorid to the three raw starch and their low cross-linkedsuccinylated starch, the final viscosity and thermal paste viscosity showed varying degreesof decline.

加入蔗糖使的三种原料淀粉及其低交联酯化淀粉的热糊粘度与最终粘度有所上升；加入柠檬酸、乳酸、氯化钠后使得三种原料淀粉及其低交联酯化淀粉的热糊粘度和最终粘度呈现不同程度的下降。

Two series of polyurethane acrylate grafted acrylic resins (Acr-g-TPU-PETA and Acr-gPPU-PETA) self-emulsifying systems are obtained by grafting -NCO group modified polyurethane acrylates with acrylic copolymer prepared from n-butyl acrylate, styrene,βhydroxyethyl methacrylate and acrylic acid The self-emulsifying systems showed Newtonian fluidity with viscosity closed to that of water, the solid contents were around 30% The T〓 of 15～4℃ for dried film before photocuring favored film formation at room temperature DSC and DMA results showed that PU-PETA is compatible with acrylic resin in the grafted resin The TG and dTG curves for Acr-g-PU-PETA samples were substantially different from the corresponding blends, and the brodened dTG peaks for photocured grafted resin suggest that there might be multiple interactions among chain segments The photocued film of the grafted resins self-emulsifying system exhibited good overall properties with polyurethane acrylate grafts ranging from 30% to 50%, and Acr-g-TPU-PETA series showed better properties than Acr-gPPU-PETA series The adhesion of the photocured film was 1～2 grade, impact strength was 50kg-cm and flexibility was 1mm The Shore hardness and the adhesion of the film decreased markedly if PETA was replaced by HEMA as photoactive group due to the lower C=C double bond content in the grafted resin The polyhydroxy amine-linked thioxanthones photoinitiators can be evenly dispersed in self-emulsifying system without color spot appearing in the dried film The films photocured with IV〓～IV〓 generally exhibited higher Shore hardness, gloss and solventresistance than that cured with Irgacure 2959 and did not induce the rusting of the iron substrate Pigmenting with titanium oxide had no effect on the photocuring The polyhydroxy amine-linked thioxanthone IV〓 and IV〓 can be new candidates for the formulation of titanium oxide pigmented photocurable water-borne coatings for their pale-yellow appearance and slight interference with the color of the coatings WB 4759 with high water-solubility coalesced and separated from the dried resin film, and even induced the rusting of iron substrate.

以丙烯酸丁酯，甲基丙烯酸-β-羟乙酯，丙烯酸及苯乙烯合成厂丙烯酸共聚树脂，并与含-NCO端基的聚氨酯丙烯酸酯接枝反应，经水性化后，得到两个系列（Acr-g-TPU-PETA和Acr-g-PPU-PETA）各5个不同配比的丙烯酸树脂接枝聚氨酯丙烯酸酯自乳化体系，粘度与水相近，为牛顿流体，固含量30％左右。光固化前干燥涂膜的玻璃化转变温度在-15℃～4℃之间，有利于室温下成膜。DSC及DMA谱表明两种树脂基本相容。Acr-g-PU-PETA的热失重行为明显不同于共混材料，接枝样dTG峰明显宽化，表明接枝样中链段之间的相互作刚有多重性，丙烯酸树脂与聚氨酯之间有一定的相容性。接枝树脂自乳化体系光固化涂层的综合性能以聚氨酯丙烯酸酯成分为50％～30％者相对较好，且以Acr-g-TPU-PETA系列更理想。光固化膜的附着力为1～2级，冲击强度为50kg·cm，柔软性多为1mm。以HEMA代替PETA作为接枝树脂的活性基团，碳—碳双键密度太低，光固化膜交联点太少，硬度和附着力均较差。多羟基胺连硫杂蒽酮光引发剂能均匀分散于树脂自乳化体系和接枝树脂干膜中，不出现色斑，光固化膜肖氏硬度一般高于以Irgacure 2959为光引发剂的光固化膜，光泽度及耐丁酮溶剂性能均有所提高，不会诱导铁基生锈，钛白着色对光固化结果几乎没有影响。本论文所合成的多羟基胺连硫杂蒽酮光引发剂IV〓与IV〓为浅黄色，对光固化涂层的颜色干扰较小，为配制钛白着色光固化水性涂料提供了新的光引发剂。水溶性太强的WB 4759在干膜中易聚结析出，且对所附着的铁基有诱导锈蚀作用。

Firstly, headspace solid-phase microextraction was established to determine AITC by orthogonal design. Extraction temperature, stir speed, extraction time, and desorption time were set at 40℃, 900r/min, 30min, and 5min, respectively. Under these optimal conditions, volatile flavor compounds in mustard oil, wasabi, and 'Chongcai'leaf mustard product were identified by SPME/GC/MS. In these three samples, 6,12,17 constituents were identified respectively; Allyl isothiocyanate was the main flavor compound, which accounted for 73.45%, 64.25%, 32.74% of total volatile compounds, respectively. Carbon disulfide, a hydrolysis product of AITC, accounted for 14.37% 25.40%, 51.67% of total volatile compounds respectively. There were some other isothiocycannates, such as butane, 1-isothiocyanato-, isobutyl isothiocyanate, 1-benzene, 4-isothiocyanato-, benzene (2-isothiocyanatoethyl)-, etc.

首先采用正交实验设计优化固相微萃取技术的前处理条件，结果表明，以萃取温度40℃、搅拌速度900r／min、萃取时间30min、解吸时间5min为最佳条件；在此最优条件基础上，利用SPME／GC／MS联用技术分析芥末油、青芥辣、冲菜的挥发性风味成分，分别检出6、12、17种化合物，主要风味物质均为AITC，相对丰度分别为73.45％、64.25％、32.74％；AITC的水解产物二硫化碳的相对丰度分别为14.37％、25.40％、51.67％；还检测到了其它几种异硫氰酸酯，如异硫氰酸丁酯、异硫氰酸异丁酯、异硫氰酸丁烯酯、2-苯乙基异硫氰酸酯等。

Then, the hapten LBc and LBs was conjugated to bovine serum albumin with CDI method to form immuno-antigen; the haptens LBc, LBs and LBy was conjugated to ovalbumin with mixed anhydride method to form the the coating antigens.The new zealand rabbits were immunized by conjugate of LBc-BSA and LBs-BSA, and titres of anti-bifenthrin serum (5.12×10~4, 3.2×10~5) were determined by non-competitive indirect enzyme-linked assay procedure.

通过碳二亚胺法将LBc和LBs交联于牛血清蛋白作为免疫抗原，通过活泼酯法将分别LBc、LBs和LBy交联于卵清蛋白作为包被抗原，LBc-BSA和LBs为免疫原制备了联苯菊酯的兔抗血清，非竞争间接酶联免疫吸附分析方法测得其效价达5.12×10~4和3.2×10~5。

Though enantioslectivity in the epoxidation of some substrates with soluble polymer-supported tartrates is a little lower than that with solution-phase tartrates, it is higher than enantioslectivity with insoluble polystyrene resin-supported tartrates, linear poly s and corrosslinked poly s. It is obvious that soluble polymer-supported tartrates have good catalytic activity and enantioselectivity.

尽管可溶性聚合物支载的酒石酸酯在某些底物环氧化中的对映选择性比小分子酒石酸酯低一些，但明显优于文献报道的不溶性聚苯乙烯树脂支载的酒石酸酯、线形聚酒石酸酯和交联聚酒石酸酯配体，显示了良好的催化活性和对映选择性。

Objective To investigate the effect and side-effect of mifepristone in small doses comparing C53contraceptive in postcoital contraception.Methods 142women with normal menstruation were divided into two groups randomly.Observation group（n=66）were given mifepristone10mg and C53contraceptive5mg within72hours after unprotected intercourse or contraception failure.Control group（n=76）were given mifepristone with a sin-gle dose of10mg within72hours after unprotected intercourse or contraception failure.The effect side-effect and menstruation of the two group were compared.

目的 探讨低剂量米非司酮配伍双炔失碳酯应用于紧急避孕的效果方法将142例月经规律的合格妇女随机分 2组，观察组（66例）在避孕失败或无保护性性交后72h内开始服用米非司酮10mg+双炔失碳酯5mg，对照组（76例）在避孕失败或无保护性性交后72h内开始服用单剂量米非司酮10mg，观察两组避孕效果、不良反应及月经情况。

This one mode pays close attention to network credence foundation of the businessman very much.

这一模式非常关注商人的网络信用基础。

Cell morphology of bacterial ghost of Pasteurella multocida was observed by scanning electron microscopy and inactivation ratio was estimated by CFU analysi.

扫描电镜观察多杀性巴氏杆菌细菌幽灵和菌落形成单位评价遗传灭活率。