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Vinyl acetate was copolymerized with triallyl isocyanurate which was then saponified, activated, and DNA was immobilized on to the adsorbent.

本文以异氰尿酸三烯丙酯 TAIC为交联剂,醋酸乙烯酯为单体合成的共聚物,经皂化和活化后,固载上DNA,即得含DNA配体的VT吸附剂。

In the present work, the synthesis of phytosterol laurate was studied, which was esterified directly by using sodium dodecyl sulfate as catalyst. And the optimal conditions were obtained by single-factor and orthogonal experiment.

研究使用十二烷基硫酸钠为催化剂,通过羧酸直接酯化,合成植物甾醇月桂酸酯的工艺,利用单因素试验和正交试验确定最佳工艺条件。

In this paper,the monomers including St and BA with strong waterproof property were employed to modify the traditional PVAc emulsion,and meanwhile draw into DAAM functional monomer in the copolymer system,will prepare out cross linking copolymer emulsion for ADH to improve the waterproof,oilproof and dry/wet mechanical property of fuel oil filter paper.

采用具有较强抗水性的苯乙烯、丙烯酸丁酯等单体对传统聚醋酸乙烯酯乳液进行共聚改性,并在共聚体系中引入双丙酮丙烯酰胺功能单体,制备出可通过外加己二酸二酰肼交联的外交联醋丙共聚乳液,以期提高燃油滤纸的耐水、耐油性和干湿态的力学性能。

The first step in the degradation is most probably the classical ester scission reaction to give a carboxylic acid and olefinic end groups. Further ester scission on the adjacent ester groups of carboxylic acid and olefinic molecular chains can then lead to the formation of lower weight pyrolytic products, such as: CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH and HOOCPhCOOH, and they can pyrolyze continually to produce substrate pyrolytic compounds, such as: HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓 and CO、CO〓. At the same time, a corsslinking cyclization reaction occurred of the formation of the gas products during the degradation of PET.

断裂大分子链端邻近羰基和乙烯基的酯键持续断裂,不断地形成小分子裂解产物,如:CH〓=CHOCOPhCOOCH=CH〓、CH〓=CHOCOPhCOOH以及HOOCPhCOOH,这些产物还会进一步裂解成分子量更低的小分子裂解产物,如:HOOCPhCOCH〓、PhCOOH、PhH、PhCOCH〓以及CO、CO〓等,与此同时,一部分乙烯基酯端基的大分子链碎片会发生支化而相互连接,再经&链脱离&和环化反应形成难燃的交联产物。

Aging mechanism of wood-plastic composite was: light and heat break down the long molecular chains of wood flour and plastic; the free radicals reacted with the oxygen, which generated carbonyl groups, hydroperoxides and so on; the free radicals also had cross linking reaction, which generated alkoxy; Water destroyed the interface of wood flour and plastic, hydrolyzed ester additives, extracted the small molecule additives and degradation products; Microorganism degraded cellulose, semicellulose, lignin and ester additives; degradation product from different component accelerated the aging, which could be exampled by the fact that HCl from degradation of PVC accelerated the hydrolyzation of cellulose and semicellulose.

木塑复合材料的老化机理为:光和热引发木塑复合材料中木质组分和塑料组分大分子链断裂,产生的自由基与氧气作用,发生链支化反应生成羰基、氢过氧化物等,发生交联反应生成烷氧基等;水分破坏木-塑界面、水解酯类添加剂、抽提小分子添加剂和降解产物;微生物分解纤维素、半纤维素、木素和酯类添加剂;木塑复合材料中各组分的降解产物相互促进老化,PVC降解产生的HCl溶于水,促进了纤维素和半纤维素的水解。

The encapsulated TiO〓 particles by polymer were obtained with soapless emulsion polymerization of methyl methacrylate in water in the presence of the pretreated TiO〓 particles.

一种是用偶联剂钛酸丁酯对亲水性TiO〓粒子进行预处理,钛酸丁酯与TiO〓表面羟基反应,交联到TiO〓粒子表面,使TiO〓粒子表面由亲水性转变为憎水性,改善无机粉体与有机单体的亲合性,再进行TiO〓存在下甲基丙烯酸甲酯的无皂乳液聚合,即可得到TiO〓-PMMA复合粒子:另一种方法是用表面活性剂对TiO〓进行预处理,再进行TiO〓粒子存在下甲基丙烯酸甲酯的无皂乳液聚合,TiO〓粒子表面可形成一层均匀的聚合物膜,提出了包覆机理,指出单体在无机粉体表面发生聚合的关键是预先在粒子表面形成聚合场所,即吸附一层表面活性剂。

A micro-monolithic column was prepared by in-situ free radical polymerization of stearyl methacrylate with ethylene glycol dimethacrylate in the presence of the initiator AIBN and a mixture of porogens including iso-amyl alcohol and 1,4-butanediol.

以甲基丙烯酸碳酰十八酯为单体,乙叉二甲基丙烯酸酯为交联剂,异戊醇和1,4-丁二醇为二元致孔剂,偶氮二异丁腈为引发剂,原位制备了具有强疏水性的SMA整体微柱,并利用此整体微柱在普通高效液相色谱仪上测定滴眼液中氧氟沙星的含量。

4The proving of security of PEPS and SPEPS for using in food had been carried out.

4对低交联马铃薯淀粉磷酸酯和甘薯淀粉磷酸酯进行了食品安全性毒理验证。

The orthogonal experimental design was applied to investigate the effects of zirconia source Zr(NO34·5H2O, ZrOCl2·8H2O,precipitants and sulfating agent (sulfuric acid, ammonium sulfate) on the catalytic performance of the catalysts unde the most superior condition .The catalytic activity was tested in esterification of acetic acid with butanol .

在最优的条件下用正交设计法考察锆源(Zr(NO3)4·5H2O,ZrOCl2·8H2O)、沉淀剂和硫酸化试剂对催化剂性能的影响,并通过乙酸和正丁醇的酯化反应的酯化率检测所制备的SO4/ZrO2催化剂的催化效果。

In order to improve the conditions of synthesis, the effects of kinds of catalysts, mole ratio of alcohol and acid, reaction time were investigated by the variance analysis.

利用正交设计法,通过极差分析,探讨了催化剂种类、醇酸摩尔配比和酯化时间及它们之问的交互作用对酯的收率的影响。

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