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亚萘基

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The result of the experiment showed that the qualitative medium - speed filter paper can be used as the material of the nitrite - detecting paper: color developing reagent A containing 4 - aminobenzene sulfonamide and N - 1 naphthyl ethylenediamine hydrochloride, and mixtures of 1 : 1 naphthylamine solution and sulfanilic acid solution as color developing reagent.

实验结果表明:定性中速滤纸可以作为亚硝酸根试纸的材料;含有4-氨基苯磺酰胺和N-1-萘基乙二胺盐酸盐的显色剂A及含有1:1的α-萘胺溶液和对氨基苯磺酸溶液的显色剂B,按1:1混合后可以作为显色剂;通过应用实验表明,亚硝酸根试纸具有体积小、便于携带、检测方便、成本低廉等特点。

Based on theoretical calculation of electronegativity of groups offlotation-reagent and method of infra-red adsorption spectroscopy, the collection andadsorption of α-nitroso-β-naphthol in hematite flotation have been studied. The chemicaladsorption seems to be predominant owing to formation of pentacyclic nitrosyl chelate com-pound by atoms of nitrosyl bond in α-nitroso-β-naphthol together with Fe~(3+) on hematitesurface.

研究了α-亚硝基β-萘酚对赤铁矿的捕收性能及吸附规律,导出了吸附方程和吸附速率方程用药剂基团电负性理论计算以及红外吸收光谱法论述了其作用机理α-亚硝基β—萘酚主要是以N O键合原子与赤铁矿表面的Fe形成N O五元环螯合物而化学吸附。

N-Methyl-3,3-dimethyl spiroindoline-2,3'[3H] naphthaline [2,1-b] [1,4] oxazine was synthesized by 1,3,3-trimethyl-2-methylene indoline and 1-nitroso-2-naphthol, its UV and IR spectra and elemental analysis were carried out, and the photochromism and main influencing factors such as temperature, solvent and pH were studied.

以1,3,3-三甲基-2-亚甲基吲哚啉和1-亚硝基-2-萘酚为原料合成了N-甲基-3,3-二甲基螺吲哚啉-2,3'[3H]萘并[2,1-b][1,4]恶嗪,对其进行了紫外和红外光谱以及元素分析,并对其光致变色性质以及主要影响因素温度、溶剂和pH进行了研究。

They are 4-(2- hydroxy-3-butynlenoxy) benzoic acid (1, WA), 5-chloro-7, 8-dihydroxy-7-methyl- 6-oxo-3- [ -3, 4-dihydroxy-3, 5-dimethyl-l-heptylene] -1H-8, 8a-dihydrobenzo [2, 3-c] pyran (2, WB),-2-(2-methyl-2-dibutene diamido)-2-butenoic acid (3, B5262), 3, 4-dihydro-9, 10-dihydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3- c] pyran-1-one (4, A73 semi-Vioxanthin), 8, 8'-bis (6, 9-dioxo-3,4-dihydro-10- hydroxy-7-methoxy-3-methyl-1H-naphtho [2, 3-c] pyran-1-one)(5, A122 Xanthomegnin), 2, 5-dioxo-3a-hydroxymethyl-3, 3a, 6, 6a-tetrahydro-furo [2, 3-b] furan (6, 1003-2), 7-acety1-5-chloro-6, 8-dioxo-7-methyl-3- [ -3, 5-dimethyl-1, 3- diheptylene] -4aH-benzo [2, 3-c] pyran (7, M2-2 sclerotiorin), respectively.

它们分别被命名为4-(2-羟基-3-丁炔氧基)苯甲酸(1,WA)、5-氯-7,8-二羟基-7-甲基-6-氧代-3-[-3,4-二羟基-3,5-二甲基-1-庚烯基]-1H-8,8a-二氢苯并[2,3-c]吡喃(2,WB)、-2-(2-甲基-2-丁烯二酰亚胺基)-2-丁烯酸(3,B5262)、3,4-氢-9,10-二羟基-7-甲氧基-3-甲基-1H-萘并[2,3-c]吡喃-1-酮(semi-Vioxanthin,4,A73)、8,8'-双(6,9-二氧代-3,4-二氢-10-羟基-7-甲氧基-3-甲基-1H-萘并[2,3-c]吡喃-1-酮)(Xanthomegnin,5,A122)、2,5-二氧代-3a-羟甲基-3,3a,6,6a-四氢-呋喃并[2,3-b]呋喃(6,1003-2),7-乙酰基-5-氯-6,8-二氧代-7-甲基-3-[-3,5-二甲基-1,3-庚二烯基]-4aH-苯并2,3-c]吡喃(Sclerotiorin,7,M2-2)。

Seven Schiff bases of N-(4-hydroxyphenylmethylene)-1-naphthylamine, N-(4-hydroxyphenylmethylene)-p-methoxyaniline, N-(4-hydroxyphenylmethylene)-benzylamine, N-(4-hydroxy-3-methoxyphenylmethylene) furfurylamine, N-(4-hydroxy-3-methoxyphenyl methylene)-p-methylaniline, N-(4-hydroxy-3-methoxyphenylmethylene)-p-methoxyaniline and N-salicylidene-4-aminoantipyrine were first synthesized by the one step solid phase reactions between aromatic aldehydes with phenolic hydroxyl and amines at room temperature without solvent.

分别以带酚羟基的芳醛与胺类反应,首次通过室温固相反应一步合成了N-(4-羟基苯基亚甲基)-1-萘胺、N-(4-羟基苯基亚甲基)-对甲氧基苯胺、N-(4-羟基苯基亚甲基)-苄胺、N-(4-羟基-3-甲氧基苯基亚甲基)糠胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲苯胺、N-(4-羟基-3-甲氧基苯基亚甲基)-对甲氧基苯胺和N-亚水杨基-4-氨基安替比林7种Schiff碱,反应15min完成,产率均超过90%。

The chiral polymer P-1 shows strong blue fluorescence due to the extended π-electronic structure between the chiral repeating unit-6,6'-di(4-trifluoromethyl-phenyl)-2,2'-bisoctoxy-1,1'-binaphthyl and the conjugated linker 2,2'-bipyridyl group via vinylene bridge.

手性高分子P-1能发射强的蓝色荧光,这是由于手性重复单元-6,6′-二(4-三氟甲基苯基)-2,2′-二正辛氧基-1,1′-联萘和单元2,2′-联吡啶通过亚乙烯基桥连形成共轭高分子结构造成的。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的,将反相微乳液法运用到其制备及改性的有关环节,通过反相微乳液聚合工艺,将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1,8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1,8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚,制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM,并研究其应用性能。

Its main products include:ZOLEDRONIC ACID, ADAPALENE, SIMDAX, VORICONAZOLE, J ACID UREA, J ACID UREA SODIUM SALT, 1,7-CLEVE'S ACID, 1,6-CLEVE'S ACID, 1,5- DINAPHTHYL ISOCYANATE, 5- INROINDOLE,----2-METHOXYIMINO-2-(FURYL-2-YL)ACETIC ACID AMMONIUM SALTand etc.

部分产品远销美国、德国、英国、印度、日本等十几个国家和地区,主要产品有:唑来磷酸、阿达帕林、左西孟旦、伏立康唑、猩红酸、猩红酸钠盐、双介酸、1,7克力夫酸1,6克力夫酸、1,5-萘二异氰酸酯、5-硝基吲哚、甲氧亚胺基呋喃乙酸铵等。

The final products were analyzed using UV-vis absorption spectrometry and GC-MS and the occurrence of nitronaphthalene and nitronaphthol will possibly deteriorate the environmental quality.

以稳态UV-vis吸收光谱及GC-MS分析了355nm光照HNO2+萘水溶液的最终产物,其中硝基萘及硝基萘酚的产生会恶化环境质量;联系瞬态研究结果,分析了所有产物的生成途径;确定了中间产物亚硝基萘对激光闪光光解实验的影响并提出了其在355nm光照下的解离机理。

Finally, N ethey[3,3 dimethyl spiralindoline naphthoxazine]was synthesized by the addition of 1 nitroso 2 naphthol also,the photochromic mechanism of the substance and its photochromic phenomenon in ethanol were studied.

报道了以苯肼和 3 甲基 2 丁酮为原料首先合成 2 ,3 ,3 三甲基吲哚,吲哚再与碘乙烷亲核取代,碱化得费舍尔碱,最后与 1 亚硝基 2 萘酚作用合成N 乙基 [3 ,3 二甲基螺吲哚啉萘并恶嗪 ]的全过程,并研究了该物质的变色机理以及在乙醇溶剂中的光致变色现

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