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亚胺唑

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The induced supramolecular chirality was found to be dependent on the absolute configuration of lateral residues, that is, the polymers with-configurational oxazolinyl chromophores tended to form chiral aggregates with levorotatory handedness, while polymers obtained from the-monomer offered dextrogyrate one upon the addition of Cu salt. A model, in which side groups would arrange in a helix fashion, is employed for describing the unusual chirality.

由此提出了侧基在Zn/Cu协同配位作用下形成螺旋状排列的模型,即侧基螺旋模型。N-噁唑啉苯基马来酰亚胺与甲基丙烯酸甲酯共聚得到了耐热性能好(热分解温度大于296℃)的光学活性聚合物~(25D=-7.8°(来源:Af4BC论文网www.abclunwen.com)~-36.6°。

Phthalimide,anthranilic acid,2methyleneglutaronitrile bromina 1bromobutane 1,2benzisothiazole3one.

邻苯二甲酰亚胺,邻氨基苯甲酸,2亚甲基戊二脯,2溴2溴甲基戊二脯,溴代正丁烷,1.2苯并异噻唑3酮。

In addition, the reactions of the carbodiimide with alkanol and substituted phenol were studied firstly.

研究了4-酯基吡唑-5-碳二亚胺(Pyrazole-5-N=C=N-Ar)与NH_3,RNH_2,R_2NH和RNHNH_2成环反应的选择性。

This is probably due to the geometry of the intermediate. 3. The cyclization of carbodiimide 2 with 1H-1, 2, 4-triazole in presence of solid potassium carbonate was studied firstly. The interesting color change was observed during the reaction process. The condition for cyclization was researched.

首次研究了碳二亚胺2与1H-1,2,4-三唑在固体碳酸钾存在下的成环反应,结果表明该反应仅生成1-N产物,而且在反应过程中出现了有趣的颜色变化,研究了该成环反应的条件。

The cyclization of carbodiimide 2 with substituted phenol in presence of solid potassium csrtjonaic was studied TiisX'iy. Tne resuYls show that It is a new mM method fOT preparing of 2-aryloxyimidazolones.

首次研究了碳二亚胺2与酚在碱催化条件下的成环反应,结果表明这是一种温和的制备2-芳氧基咪唑啉酮的新方法。

Results Cefoperazone/Sulbactam, Imipenem, Piperacillin/Tazobactam, Cefetamet and Quinolones had strong effects to resist Chromobacterium violaceum,while resistant effects of those antibiotics were not significant, including Ampicillin, Cefazolin, Gentamicin, Tobramycin, Aztreonam, Ceftriaxono, and Ceftazidime.

结果 12种抗菌药物中舒普深、亚胺培南、特治星、马斯平及喹喏酮类抗菌药物对紫色色杆菌均有较强的抗菌作用,而氨苄西林、头孢唑啉、庆大霉素、妥布霉素、氨曲南、头孢曲松和头孢他啶等抗菌药物抗菌效果不佳。

Utilizing 6 and several kinds of diazides prepared in our lab, polys containing 1,2,3-triazolyl and perfluorocyclobutane units were synthesized by "Click chemistry". Utilizing the polycondensation reaction between 6 and several commercially available aromatic diphenol or copolymerization reaction after adding another active aromatic dichloride, fluorinated polys containing phenylphosphine oxide units were synthesized. Utilizing the polycondensation reaction between 6 and several commercially available aromatic dianhydride, fluorinated polys containing PPO units were synthesized.Secondly, structure characterization of fluorinated polys.

利用化合物6同各种自制的二叠氮化合物,通过&Click chemistry&,合成了具有1,2,3-三唑环结构单元的全氟环丁基类聚芳醚;利用化合物22同各种商业化的芳香二元酚类化合物进行缩聚反应或者再加入另外一种活性芳香二氯代物进行三元共聚反应,制备了具有苯基氧膦结构单元的含氟聚芳醚;通过化合物25同各种商业化的芳香二元酸酐类化合物进行缩聚反应,得到了具有PPO结构单元的含氟聚醚酰亚胺。

The main pathogens of VAP were Gram negative organisms (68.63%) whose predominant pathogens were Pseudomonas aeruginosa and Acinetobacter. On the other hand, 75.40% of Gram positive organisms were Staphylococcus epidermidis.Of the pathogens 20.98% were eumycetes. Compared from June 1996 to June 2001 with from July 2001 to June 2006,there was no significant difference on the incidence rate of P.aeruginosa(31.76% vs 31.58%).During the recent 10 years,the incidence of Acinetobacter rose up from 8.23% to 15.23% and the rate of oxacillin-resistant Staphylococcus epidermidis rose up from 18.75% to 71.43%. The sensitivity of P.aeruginosa and Acinetobacter isolates descended to sodium imipenem cilastatin and ceftazidime in past 10 years.

在538例VAP中,2种及2种以上致病菌感染占56.51%;革兰阴性细菌中,铜绿假单胞菌和不动杆菌属为VAP的主要致病菌(68.63%)(385/561);表皮葡萄球菌感染为VAP的主要革兰阳性致病菌(75.40%)(95/126);真菌占20.98%(183/872);铜绿假单胞菌在两个时间段所占比例无明显变化,不动杆菌属的检出率呈上升趋势(8.23%~15.23%);铜绿假单胞菌和不动杆菌属对亚胺培南、头孢他啶的敏感性明显下降,耐苯唑西林表皮葡萄球菌的检出率显著升高(18.75%~71.43%)。

Next, another novel diamine, 5-5-(4-phenyl-1,3,4-oxadiazol-2-ylbenzene-1,3-diamine, was prepared and polymerization was carried out in the same way to obtain polyimides containig triphenylamine units and 1,3,4-oxadiazole moieties in the side chain .

接下来,合成另一个新型双胺5-5-(4-phenyl-1,3,4-oxadiazol-2-ylbenzene-1,3-diamine后,以相同方法进聚缩合反应,可制得另一系列三苯胺和1,3,4-恶二唑为侧链的聚醯亚胺。

First, N'-(4-aminophenyl)-N'-4-(5-phenyl-1,3,4-oxadiazol-2-ylphenylbenzene-1,4-diamine was prepared and polymerization was carried out by direct polycondensation with a series of dianhydrides to obtain polyimides containig triphenylamine units in the main chain and 1,3,4-oxadiazole moieties as pendent group.

首先合成新型双胺N'-(4-aminophenyl)-N'-4-(5-phenyl-1,3,4-oxadiazol-2-ylphenylbenzene-1,4-diamine后,与一系的芳香族二酐进聚缩合反应,可制得一系列三苯胺为主链且1,3,4-恶二唑为侧链的聚醯亚胺。

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