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亚胺

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The selectivity of cyclization of carbodiimide 2 with primary amine was studied and the result showed that the anomalous product being cyclized from arylamino group was formed preferencially.

研究了碳二亚胺2与伯胺成环反应的选择性,结果表明优先生成反常的芳氨基成环产物,利用中间体可能的构型解释了实验结果。

Bis-(4-bromobenzoyl) benzene as the monomer of poly was synthesized by Friedel-Crafts benzoylation reaction. Poly-Ⅱ synthesized via palladium-catalyzed aryl amination reaction using 1, 4-bis-(4-bromo-benzoyl) benzene and 4, 4'-diaminodiphenyl ether as monomers.

通过傅-克酰基化反应合成了1,4-双-(4'-溴苯酰基)苯,以1,4-双-(4'-溴苯酰基)苯和4'4-二氨基二苯醚为单体,通过钯催化的胺基化缩聚反应合成了高性能聚合物-聚亚胺酮-Ⅱ。

Study on an efficient process for the preparation of trifloxystrobin starting from 2-methylacetophenone bypartial oxidation,esterification,reaction with methoxyamine,bromization and condensation with 3'- acetophenone oxime.

以邻甲基苯乙酮为原料,经过高锰酸钾的碱性氧化,甲醇酯化,再与甲氧基胺盐酸盐肟化后,用N-溴丁二酰亚胺溴化,最后和间三氟甲基苯乙酮肟缩合得到目标产物肟菌酯。

A novel planar chiral diferrocenylimine-diols 6 was synthesized by the condensation of R, S(subscript p-1-(2-diphenyl hydroxyl methyl) ferrocenylethylamine [R, S(subscript p-4] with phthaldehyde in anhydrous ethanol, and was crystallographically characterized.

通过R,S(下标 p-1-(2-二苯基羟甲基)二茂铁乙胺[R,S(下标 p-4]和对苯二甲醛在无水乙醇中的缩合反应合成了一种新型平面手性双二茂铁亚胺二醇化合物6,并经X-射线衍射分析它的晶体结构。

Was synthesized from cyanoacetic acid and diethylamine via DCC coupling under mild conditions.

中间体5 的制备由氰基乙酸在二环己基碳二亚胺作用下经酰胺化一步制得,条件温和,收率较高,避免使用剧毒的氰化钠。

In this Ph. D. dissertation, reverse microemulsion method was fully used infabricating and modifying polyacrylamide with functional and high-relative moleculeweight. The copolymerization of 2-acrylamide-2-methylpxopanesulfonic acid, fluorescent monomer 4-methoxy-N-(2-N\', N\'-dimethylamino ethyl)naphthalimide alkyl chloride quaternary ammonium salt, fluorescentmonomer 4-(N\'-methyl-1-piperazinylallyl)-N-butyl-naphthalimide chloride quaternaryammonium salt, Cationic monomer dimethylethylammonium bromide and hydrophobical monomer octadecylacrylate with acrylamide and properties of the copolymers werestudied. The interaction between five polymers and Al_2O_3(012) crystal surface have beensimulated by Materials Studio 3.0 program package, binding energies and non-bondinteraction energies and deformation energies have also been acquired.

本文以制备具有较高相对分子质量和功能型PAM为研究目的,将反相微乳液法运用到其制备及改性的有关环节,通过反相微乳液聚合工艺,将几种改性功能单体2-丙烯酰胺基-2-甲基-丙磺酸、荧光单体2-(4-甲氧基-1,8-萘二甲酰亚胺基)-乙基二甲基烯丙基氯化铵、荧光单体4-(N'-甲基-1-哌嗪基)-N-丁基-1,8-萘烯丙氯季铵盐、阳离子单体丙烯酰氧乙基-二甲基-乙基溴化铵和疏水单体丙烯酸十八酯与AM共聚,制备AMPS改性PAM、荧光示踪型PAM、阳离子单体DMB改性PAM和OA改性PAM等四类不同功能单体改性PAM,并研究其应用性能。

Examples of monomers which have on average not less than 3 cross-linking groups per molecule include for example tri, tetra, penta and hexa functional isocyanates, alcohols, amines, epoxys,acrylates, siloxanes and imines.

其中的单体平均不超过3交叉连接不到每分子团体有例子包括,例如三,四,五溴和六功能异氰酸酯,醇,胺,epoxys,丙烯酸酯,硅氧烷和亚胺

Based on this monomer, several novel polyimides bearing side chain s composed of cyano-biphenyl mesogenic end groups and hexylene spacer were prepared.

合成了一种含氰基联苯氧基侧链的二元胺单体,然后通过两步法热酰亚胺化工艺制备了新型的含氰基联苯基团侧链的聚酰亚胺

However,they are generally insoluble and infusible in their fully imidized form,which would lead to processing difficulties;and this process of polyintermediate has several inherent problems such as emission of volatile byproducts(e.g.,H_2O)and storage instability etc.

然而,完全亚胺化的芳香族聚酰亚胺通常不溶不熔,难于加工,而采用聚酰胺酸中间体加工时,又存在储存稳定性差,加工过程中会产生可挥发小分子副产物(如;H_2O)等问题。

The reaction of chiral isocyanide with N-sulfonylimine catalyzed byRh complex gave 2-imidazoline in 68 - 82% diastereoselectivity.

本论文由五部分组成·在没有任何酸,碱和催化剂存在下, N-磺酰亚胺与异氰乙酰胺反应,以60-94%的产率生成1,3-恶唑。1,3-恶唑的结构由X-ray分析测定。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力